Abstract
In the recent years, 2D IR spectroscopy has evolved as a structure sensitive experimental technique to study ultrafast structural and conformational dynamics across broad fields of science. This article explains the 2D IR experimental methodology and provides a qualitative understanding of the basics principles and spectral signatures of the various dynamical processes. A comprehensive review of various 2D IR investigations provide an in-depth understanding of the applications of this spectroscopic technique in chemistry, materials, and biology. Recent technological advances are discussed to explain the future scope of 2D IR in deciphering the molecular structure-function relation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
J.D. Hybl, A.W. Albrecht, S.M.G. Faeder, D.M. Jonas, Chem. Phys. Lett. 297, 307–313 (1998)
P. Hamm, M.H. Lim, R.M. Hochstrasser, J. Phys. Chem. B 102, 6123–6138 (1998)
W. Xiong, J.E. Laaser, R.D. Mehlenbacher, M.T. Zanni, Proc. Natl. Acad. Sci. U. S. A. 108, 20902–20907 (2011)
K. Inoue, S. Nihonyanagi, P.C. Singh, S. Yamaguchi, T. Tahara, J. Chem. Phys. 142, 212431 (2015)
T.L. Courtney, Z.W. Fox, L. Estergreen, M. Khalil, J. Phys. Chem. Lett. 6, 1286–1292 (2015)
T.A.A. Oliver, N.H.C. Lewis, G.R. Fleming, Proc. Natl. Acad. Sci. U. S. A. 111, 10061–10066 (2014)
B.M. Luther, K.M. Tracy, M. Gerrity, S. Brown, A.T. Krummel, Opt. Express 24, 4117–4127 (2016)
P.M. Donaldson, G.M. Greetham, D.J. Shaw, A.W. Parker, M. Towrie, J. Phys. Chem. A 122, 780–787 (2018)
R.M. Hochstrasser, Chem. Phys. 266, 273–284 (2001)
Y.J. Yan, R.E. Gillilan, R.M. Whitnell, K.R. Wilson, S. Mukamel, J. Phys. Chem. 97, 2320–2333 (1993)
K. Lazonder, M.S. Pshenichnikov, D.A. Wiersma, Opt. Lett. 31, 3354–3356 (2006)
N. Demirdöven, M. Khalil, A. Tokmakoff, Phys. Rev. Lett. 89, 237401 (2002)
K. Kwak, D.E. Rosenfeld, M.D. Fayer, J. Chem. Phys. 128, 204505 (2008)
K. Kwak, S. Park, I.J. Finkelstein, M.D. Fayer, J. Chem. Phys. 127, 124503 (2007)
S. Bagchi, Y.S. Kim, A.K. Charnley, A.B. Smith, R.M. Hochstrasser, J. Phys. Chem. B 111, 3010–3018 (2007)
Y.S. Kim, J.P. Wang, R.M. Hochstrasser, J. Phys. Chem. B 109, 7511–7521 (2005)
P. Deb, G.Y. Jin, S.K. Singh, J. Moon, H. Kwon, A. Das, S. Bagchi, Y.S. Kim, J. Phys. Chem. Lett. 9, 5425–5429 (2018)
S.M. Kashid, G.Y. Jin, S. Bagchi, Y.S. Kim, J. Phys. Chem. B 119, 15334–15343 (2015)
S.M. Kashid, G.Y. Jin, S. Chakrabarty, Y.S. Kim, S. Bagchi, J. Phys. Chem. Lett. 8, 1604–1609 (2017)
S. Bagchi, B.T. Nebgen, R.F. Loring, M.D. Fayer, J. Am. Chem. Soc. 132, 18367–18376 (2010)
S. Bagchi, D.G. Thorpe, I.F. Thorpe, G.A. Voth, M.D. Fayer, J. Phys. Chem. B 114, 17187–17193 (2010)
O. Golonzka, A. Tokmakoff, J. Chem. Phys. 115, 297–309 (2001)
Y.S. Kim, R.M. Hochstrasser, Proc. Natl. Acad. Sci. 102, 11185–11190 (2005)
D.V. Kurochkin, S.R.G. Naraharisetty, I.V. Rubtsov, Proc. Natl. Acad. Sci. U. S. A. 104, 14209–14214 (2007)
M. Khalil, N. Demirdöven, A. Tokmakoff, J. Phys. Chem. A 107, 5258–5279 (2003)
R.M. Hochstrasser, Proc. Natl. Acad. Sci. 104, 14190–14196 (2007)
M.K. Petti, J.P. Lomont, M. Maj, M.T. Zanni, J. Phys. Chem. B 122, 1771–1780 (2018)
R.T. Mackin, B. Cohn, A. Gandman, J.D. Leger, L. Chuntonov, I.V. Rubtsov, J. Phys. Chem. C 122, 11015–11023 (2018)
M.K. Petti, J.S. Ostrander, V. Saraswat, E.R. Birdsall, K.L. Rich, J.P. Lomont, M.S. Arnold, M.T. Zanni, J. Chem. Phys. 150, 024707 (2019)
A.T. Krummel, M.T. Zanni, J. Phys. Chem. B 110, 13991–14000 (2006)
I.C. Spector, K.S. Schramke, U.R. Kortshagen, A.M. Massari, J. Phys. Chem. C 122, 8693–8698 (2018)
T.M. Porter, J. Wang, Y. Li, B. Xiang, C. Salsman, J.S. Miller, W. Xiong, C.P. Kubiak, Chem. Sci. 10, 113–117 (2019)
L. Chuntonov, I.M. Pazos, J. Ma, F. Gai, J. Phys. Chem. B 119, 4512–4520 (2015)
J. Zheng, K. Kwak, X. Chen, J.B. Asbury, M.D. Fayer, J. Am. Chem. Soc. 128, 2977–2987 (2006)
K.-H. Park, S.R. Choi, J.-H. Choi, S. Park, M. Cho, ChemPhysChem 11, 3632–3637 (2010)
J. Kübel, G. Lee, S.A. Ooi, S. Westenhoff, H. Han, M. Cho, M. Maj, J. Phys. Chem. Lett. 10, 7878–7883 (2019)
M. Ji, S. Park, K.J. Gaffney, J. Phys. Chem. Lett. 1, 1771–1775 (2010)
A.V. Cunha, E. Salamatova, R. Bloem, S.J. Roeters, S. Woutersen, M.S. Pshenichnikov, T.L.C. Jansen, J. Phys. Chem. Lett. 8, 2438–2444 (2017)
K.-K. Lee, K.-H. Park, D. Kwon, J.-H. Choi, H. Son, S. Park, M. Cho, J. Chem. Phys. 134, 064506 (2011)
S. R. Galle Kankanamge, J. Ma, R.T. Mackin, F.M. Leonik, C.M. Taylor, I.V. Rubtsov, D.G. Kuroda, Angew. Chem. Int. Ed. 59, 17012–17017 (2020).
S.M. Kashid, G.Y. Jin, S. Bagchi, Y.S. Kim, J. Phys. Chem. B 11, 15334–15343 (2015)
J.A. Dunbar, E.J. Arthur, A.M. White, K.J. Kubarych, J. Phys. Chem. B 119, 6271–6279 (2015)
M. Okuda, K. Ohta, K. Tominaga, J. Chem. Phys. 145, 114503 (2016)
F. Yang, P. Yu, J. Zhao, J. Wang, ChemPhysChem 14, 2497–2504 (2013)
J.T. King, M.R. Ross, K.J. Kubarych, Phys. Rev. Lett. 108, 157401 (2012)
S.C. Edington, C.R. Baiz, J. Phys. Chem. A 122, 6585–6592 (2018)
J.Y. Shin, S.A. Yamada, M.D. Fayer, J. Am. Chem. Soc. 139, 311–323 (2017)
Y. Cui, J.C. Rushing, S. Seifert, N.M. Bedford, D.G. Kuroda, J. Phys. Chem. B 123, 3984–3993 (2019)
Y. Cui, K.D. Fulfer, J. Ma, T.K. Weldeghiorghis, D.G. Kuroda, Phys. Chem. Chem. Phys. 18, 31471–31479 (2016)
S. Chatterjee, D. Ghosh, T. Haldar, P. Deb, S.S. Sakpal, S.H. Deshmukh, S.M. Kashid, S. Bagchi, J. Phys. Chem. B 123, 9355–9363 (2019)
Y. Cui, D.G. Kuroda, J. Phys. Chem. A 122, 1185–1193 (2018)
D.E. Moilanen, E.E. Fenn, D. Wong, M.D. Fayer, J. Chem. Phys. 131, 014704 (2009)
R. Yuan, C. Yan, J. Nishida, M.D. Fayer, J. Phys. Chem. B 121, 4530–4537 (2017)
E.E. Fenn, D.B. Wong, M.D. Fayer, Proc. Natl. Acad. Sci. 106, 15243–15248 (2009)
R. Yuan, C. Yan, A. Tamimi, M.D. Fayer, J. Phys. Chem. B 119, 13407–13415 (2015)
S.A. Yamada, S.T. Hung, W.H. Thompson, M.D. Fayer, J. Chem. Phys. 152, 154704 (2020)
C. Yan, J. Nishida, R. Yuan, M.D. Fayer, J. Am. Chem. Soc. 138, 9694–9703 (2016)
D.B. Wong, K.P. Sokolowsky, M.I. El-Barghouthi, E.E. Fenn, C.H. Giammanco, A.L. Sturlaugson, M.D. Fayer, J. Phys. Chem. B 116, 5479–5490 (2012)
Z. Zhang, L. Piatkowski, H.J. Bakker, M. Bonn, Nat. Chem. 3, 888–893 (2011)
K. Adamczyk, N. Simpson, G.M. Greetham, A. Gumiero, M.A. Walsh, M. Towrie, A.W. Parkerb, N.T. Hunt, Chem. Sci. 6, 505–516 (2015)
D.G. Osborne, J.A. Dunbar, J.G. Lapping, A.M. White, K.J. Kubarych, J. Phys. Chem. B 117, 15407–15414 (2013)
B.A. Marekha, J. Hunger, Phys. Chem. Chem. Phys. 21, 20672–20677 (2019)
R.K. Venkatraman, C.R. Baiz, Langmuir 36, 6502–6511 (2020)
J.C. Flanagan, A.E. Cardenas, C.R. Baiz, J. Phys. Chem. Lett. 11, 4093–4098 (2020)
L.A.I. Ramakers, G. Hithell, J.J. May, G.M. Greetham, P.M. Donaldson, M. Towrie, A.W. Parker, G.A. Burley, N.T. Hunt, J. Phys. Chem. B 121, 1295–1303 (2017)
R. Fritzsch, P.M. Donaldson, G.M. Greetham, M. Towrie, A.W. Parker, M.J. Baker, N.T. Hunt, Anal. Chem. 90, 2732–2740 (2018)
G. Hithell, P.M. Donaldson, G.M. Greetham, M. Towrie, A.W. Parker, G.A. Burley, N.T. Hunt, Chem. Phys. 512, 154–164 (2018)
G. Hithell, D.J. Shaw, P.M. Donaldson, G.M. Greetham, M. Towrie, G.A. Burley, A.W. Parker, N.T. Hunt, J. Phys. Chem. B 120, 4009–4018 (2016)
G. Hithell, M. González-Jiménez, G.M. Greetham, P.M. Donaldson, M. Towrie, A.W. Parker, G.A. Burley, K. Wynne, N.T. Hunt, Phys. Chem. Chem. Phys. 19, 10333–10342 (2017)
T. Siebert, B. Guchhait, Y. Liu, B.P. Fingerhut, T. Elsaesser, J. Phys. Chem. Lett. 7, 3131–3136 (2016)
P.J. Sanstead, P. Stevenson, A. Tokmakoff, J. Am. Chem. Soc. 138, 11792–11801 (2016)
B.P. Fingerhut, E.M. Bruening, J. Schauss, T. Siebert, T. Elsaesser, EPJ Web Conf. 205, 10003 (2019)
E.M. Bruening, J. Schauss, T. Siebert, B.P. Fingerhut, T. Elsaesser, J. Phys. Chem. Lett. 9, 583–587 (2018)
C. Varner, X. Zhou, Z.K. Saxman, J.D. Leger, J. Jayawickramarajah, I.V. Rubtsov, Chem. Phys. 512, 20–26 (2018)
M. Okuda, K. Ohta, K. Tominaga, J. Chem. Phys. 142, 212418 (2015)
L. Minnes, D.J. Shaw, B.P. Cossins, P.M. Donaldson, G.M. Greetham, M. Towrie, A.W. Parker, M.J. Baker, A.J. Henry, R.J. Taylor, N.T. Hunt, Anal. Chem. 89, 10898–10906 (2017)
H. Ishikawa, I.J. Finkelstein, S. Kim, K. Kwak, J.K. Chung, K. Wakasugi, A.M. Massari, M.D. Fayer, Proc. Natl. Acad. Sci. 104, 16116–16121 (2007)
M. Maj, K. Kwak, M. Cho, ChemPhysChem 16, 3468–3476 (2015)
S. Ramos, M.C. Thielges, J. Phys. Chem. B 123, 3551–3566 (2019)
S. Ramos, A.L. Le Sueur, R.E. Horness, J.T. Specker, J.A. Collins, K.E. Thibodeau, M.C. Thielges, J. Phys. Chem. B 123, 2114–2122 (2019)
S. Ramos, E.J. Basom, M.C. Thielges, Frontiers in Molecular Biosciences 5, 94 (2018)
A.L. Le Sueur, S. Ramos, J.D. Ellefsen, S. Cook, M.C. Thielges, Anal. Chem. 89, 5254–5260 (2017)
S. Ramos, K.J. Scott, R.E. Horness, A.L. Le Sueur, M.C. Thielges, Phys. Chem. Chem. Phys. 19, 10081–10086 (2017)
A.L. Le Sueur, R.N. Schaugaard, M.-H. Baik, M.C. Thielges, J. Am. Chem. Soc. 138, 7187–7193 (2016)
E.J. Basom, J.W. Spearman, M.C. Thielges, J. Phys. Chem. B 119, 6620–6627 (2015)
P. Pagano, Q. Guo, A. Kohen, C.M. Cheatum, J. Phys. Chem. Lett. 7, 2507–2511 (2016)
S. Dutta, Y.-L. Li, W. Rock, J.C.D. Houtman, A. Kohen, C.M. Cheatum, J. Phys. Chem. B 116, 542–548 (2012)
A. Ghosh, M.J. Tucker, F. Gai, J. Phys. Chem. B 118, 7799–7805 (2014)
P. Stevenson, A. Tokmakoff, J. Am. Chem. Soc. 139, 4743–4752 (2017)
S.E. Strong, N.J. Hestand, A.A. Kananenka, M.T. Zanni, J.L. Skinner, Biophys. J. 118, 254–261 (2020)
H.T. Kratochvil, J.K. Carr, K. Matulef, A.W. Annen, H. Li, M. Maj, J. Ostmeyer, A.L. Serrano, H. Raghuraman, S.D. Moran, J.L. Skinner, E. Perozo, B. Roux, F.I. Valiyaveetil, M.T. Zanni, Science 353, 1040–1044 (2016)
P.M. Donaldson, P. Hamm, Angew. Chem. Int. Ed. 52, 634–638 (2013)
J. Nishida, J.P. Breen, B. Wu, M.D. Fayer, A.C.S. Cent, Sci. 4, 1065–1073 (2018)
J.J. Hermans, L. Baij, M. Koenis, K. Keune, P.D. Iedema, S. Woutersen, Science Advances 5, eaaw3592 (2019).
J. Lim, K.-K. Lee, C. Liang, K.-H. Park, M. Kim, K. Kwak, M. Cho, J. Phys. Chem. B 123, 6651–6663 (2019)
J. Nishida, J.P. Breen, K.P. Lindquist, D. Umeyama, H.I. Karunadasa, M.D. Fayer, J. Am. Chem. Soc. 140, 9882–9890 (2018)
A.A. Bakulin, O. Selig, H.J. Bakker, Y.L.A. Rezus, C. Müller, T. Glaser, R. Lovrincic, Z. Sun, Z. Chen, A. Walsh, J.M. Frost, T.L.C. Jansen, J. Phys. Chem. Lett. 6, 3663–3669 (2015)
C.J. Huber, R.L. Butler, A.M. Massari, J. Phys. Chem. C 121, 2933–2939 (2017)
C.M. Olson, A.M. Massari, J. Phys. Chem. A 122, 1592–1599 (2018)
A.A. Eigner, T.C. Anglin, A.M. Massari, J. Phys. Chem. C 114, 12308–12315 (2010)
A.A. Eigner, B.H. Jones, B.W. Koprucki, A.M. Massari, J. Phys. Chem. B 115, 4583–4591 (2011)
C.J. Huber, A.M. Massari, J. Phys. Chem. C 118, 25567–25578 (2014)
S.A. Roget, P.L. Kramer, J.E. Thomaz, M.D. Fayer, J. Phys. Chem. B 123, 9408–9417 (2019)
D. Paleček, G. Tek, J. Lan, M. Iannuzzi, P. Hamm, J. Phys. Chem. Lett. 9, 1254–1259 (2018)
G.M. Greetham, I.P. Clark, D. Weidmann, M.N.R. Ashfold, A.J. Orr-Ewing, M. Towrie, Opt. Lett. 38, 3596–3599 (2013)
J.v. Cosel, J. Cerezo, D. Kern-Michler, C. Neumann, L.J.G.W.v. Wilderen, J. Bredenbeck, F. Santoro, I. Burghardt, J. Chem. Phys. 147, 164116 (2017)
H.J.B. Marroux, A.J. Orr-Ewing, J. Phys. Chem. B 120, 4125–4130 (2016)
H. Chen, H. Bian, J. Li, X. Wen, J. Zheng, Int. Rev. Phys. Chem. 31, 469–565 (2012)
P.B. Petersen, A. Tokmakoff, Opt. Lett. 35, 1962–1964 (2010)
J.P. Kraack, P. Hamm, Chem. Rev. 117, 10623–10664 (2017)
D. Lotti, P. Hamm, J.P. Kraack, J. Phys. Chem. C 120, 2883–2892 (2016)
J. Bredenbeck, J. Helbing, R. Behrendt, C. Renner, L. Moroder, J. Wachtveitl, P. Hamm, J. Phys. Chem. B 107, 8654–8660 (2003)
P.L. Kramer, J. Nishida, M.D. Fayer, J. Chem. Phys. 143, 124505 (2015)
D.J. Hoffman, M.D. Fayer, J. Phys. Chem. A 124, 5979–5992 (2020)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Ghosh, D. et al. (2021). Two Dimensional Infrared Spectroscopy: A Structure Sensitive Technique with Ultrafast Time Resolution. In: Singh, D.K., Pradhan, M., Materny, A. (eds) Modern Techniques of Spectroscopy. Progress in Optical Science and Photonics, vol 13. Springer, Singapore. https://doi.org/10.1007/978-981-33-6084-6_2
Download citation
DOI: https://doi.org/10.1007/978-981-33-6084-6_2
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-33-6083-9
Online ISBN: 978-981-33-6084-6
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)