Introduction
Transition metal-catalyzed carbonylation reactions, making use of gaseous carbon monoxide as a C1 source, provide an atom economical route for the synthesis of aldehydes, ketones, carboxylic acid derivatives, and heterocyclic moieties. Aryl halides, alkenes, alkynes, and even alkanes are feedstock for carbonylation reactions [1]. This catalytic methodology thus paves way for the synthesis of important bulk and fine chemicals (Scheme 1). Although predominantly, homogeneous catalytic protocols drive the carbonylative synthesis of various chemicals, due to the drawbacks associated with homogeneous catalysis, heterogeneous catalytic protocols also hold importance now.
Transition metal-catalyzed carbonylative transformations
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Gautam, P., Shah, J.A., Bhanage, B.M. (2022). Palladium-Catalyzed Carbonylation Reactions in Ionic Liquids. In: Zhang, S. (eds) Encyclopedia of Ionic Liquids. Springer, Singapore. https://doi.org/10.1007/978-981-33-4221-7_32
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