Abstract
Developing high-efficiency and strong stability hydrogen evolution reaction (HER) electrocatalysts is the critical and promising part of reducing the catalytic energy barrier and improving the efficiency of hydrogen production. For designing prominent HER electrocatalysts, challenges remain in creating large number of effective catalytic sites for HER while maintaining their robustness at high output volumes. Therefore, the development of effective anchoring of catalytic active sites on low-cost, highly conductive carbon carriers to effectively promote metal catalytic performance through strong metal-support interactions (SMSI) is a well-established strategy that has been widely investigated. Carbon-based nanomaterials have attracted extensive attention as a promising class of HER catalysts for green sustainable energy conversion and beyond, due to their low-cost, diverse forms and highly tunable electronic structures. Herein, a summary of the advanced research progress of various types of carbon-based catalysts has been discussed, mainly including the metal-free carbon-based nanomaterials, atomically dispersed metal carbon-based materials, metal nanoparticles supported carbon-based materials, and metal nanoparticles encapsulated carbon-based materials. Finally, some notable challenges and prospects that are instructive for the design and development of next-generation high-performance carbon-based electrocatalysts have been discussed.
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References
P.W. Menezes, S. Yao, R. Beltrán-Suito, J.N. Hausmann, P.V. Menezes, M. Driess, Facile access to an active γ-NiOOH electrocatalyst for durable water oxidation derived from an intermetallic nickel germanide precursor. Angew. Chem. Int. Ed. 60, 4640–4647 (2021). https://doi.org/10.1002/anie.202014331
W. Yang, S. Chen, Recent progress in electrode fabrication for electrocatalytic hydrogen evolution reaction: A mini review. Chem. Eng. J. 393, 124726 (2020). https://doi.org/10.1016/j.cej.2020.124726
J. Theerthagiri, S.J. Lee, A.P. Murthy, J. Madhavan, M.Y. Choi, Fundamental aspects and recent advances in transition metal nitrides as electrocatalysts for hydrogen evolution reaction: A review. Curr. Opin. Solid State Mater. Sci. 24, 100805 (2020). https://doi.org/10.1016/j.cossms.2020.100805
A. Ali, P.K. Shen, Nonprecious metal’s graphene-supported electrocatalysts for hydrogen evolution reaction: Fundamentals to applications. Carbon Energy 2, 99–121 (2020). https://doi.org/10.1002/cey2.26
Y. Pan, C. Zhang, Y. Lin, Z. Liu, M. Wang, C. Chen, Electrocatalyst engineering and structure-activity relationship in hydrogen evolution reaction: From nanostructures to single atoms. Sci. China Mater. 63, 921–948 (2020). https://doi.org/10.1007/s40843-019-1242-1
W. Hua, H.-H. Sun, F. Xu, J.-G. Wang, A review and perspective on molybdenum-based electrocatalysts for hydrogen evolution reaction. Rare Met. 39, 335–351 (2020). https://doi.org/10.1007/s12598-020-01384-7
Y. Wang, B. Kong, D. Zhao, H. Wang, C. Selomulya, Strategies for developing transition metal phosphides as heterogeneous electrocatalysts for water splitting. Nano Today 15, 26–55 (2017). https://doi.org/10.1016/j.nantod.2017.06.006
S.-S. Lu, L.-M. Zhang, Y.-W. Dong, J.-Q. Zhang, X.-T. Yan, D.-F. Sun, X. Shang, J.-Q. Chi, Y.-M. Chai, B. Dong, Tungsten-doped Ni–Co phosphides with multiple catalytic sites as efficient electrocatalysts for overall water splitting. J. Mater. Chem. A 7, 16859–16866 (2019). https://doi.org/10.1039/C9TA03944A
X. Xiao, L. Tao, M. Li, X. Lv, D. Huang, X. Jiang, H. Pan, M. Wang, Y. Shen, Electronic modulation of transition metal phosphide via doping as efficient and pH-universal electrocatalysts for hydrogen evolution reaction. Chem. Sci. 9, 1970–1975 (2018). https://doi.org/10.1039/C7SC04849A
D. Chen, Z. Pu, R. Lu, P. Ji, P. Wang, J. Zhu, C. Lin, H.-W. Li, X. Zhou, Z. Hu, F. Xia, J. Wu, S. Mu, Ultralow Ru loading transition metal phosphides as high-efficient bifunctional electrocatalyst for a solar-to-hydrogen generation system. Adv. Energy Mater. 10, 2000814 (2020). https://doi.org/10.1002/aenm.202000814
Z. Wu, Y. Zhao, H. Wu, Y. Gao, Z. Chen, W. Jin, J. Wang, T. Ma, L. Wang, Corrosion engineering on iron foam toward efficiently electrocatalytic overall water splitting powered by sustainable energy. Adv. Func. Mater. 31, 2010437 (2021). https://doi.org/10.1002/adfm.202010437
L. Yan, H. Wang, J. Shen, J. Ning, Y. Zhong, Y. Hu, Formation of mesoporous Co/CoS/Metal–N–C@S, N-codoped hairy carbon polyhedrons as an efficient trifunctional electrocatalyst for Zn-air batteries and water splitting. Chem. Eng. J. 403, 126385 (2021). https://doi.org/10.1016/j.cej.2020.126385
Y. Shi, B. Zhang, Recent advances in transition metal phosphide nanomaterials: Synthesis and applications in hydrogen evolution reaction. Chem. Soc. Rev. 45, 1529–1541 (2016). https://doi.org/10.1039/C5CS00434A
D. Khalafallah, M. Zhi, Z. Hong, Recent trends in synthesis and investigation of nickel phosphide compound/hybrid-based electrocatalysts towards hydrogen generation from water electrocatalysis. Top. Curr. Chem. 377, 29 (2019). https://doi.org/10.1007/s41061-019-0254-3
Z. Chen, X. Duan, W. Wei, S. Wang, B.-J. Ni, Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution. J. Mater. Chem. A 7, 14971–15005 (2019). https://doi.org/10.1039/C9TA03220G
Y. Pei, Y. Cheng, J. Chen, W. Smith, P. Dong, P.M. Ajayan, M. Ye, J. Shen, Recent developments of transition metal phosphides as catalysts in the energy conversion field. J. Mater. Chem. A 6, 23220–23243 (2018). https://doi.org/10.1039/C8TA09454C
M. Kuang, Q. Wang, P. Han, G. Zheng, Cu, Co-embedded N-enriched mesoporous carbon for efficient oxygen reduction and hydrogen evolution reactions. Adv. Energy Mater. 7, 1700193 (2017). https://doi.org/10.1002/aenm.201700193
Q. Lu, Y. Yu, Q. Ma, B. Chen, H. Zhang, 2D transition-metal-dichalcogenide-nanosheet-based composites for photocatalytic and electrocatalytic hydrogen evolution reactions. Adv. Mater. 28, 1917–1933 (2016). https://doi.org/10.1002/adma.201503270
W. Zhou, J. Jia, J. Lu, L. Yang, D. Hou, G. Li, S. Chen, Recent developments of carbon-based electrocatalysts for hydrogen evolution reaction. Nano Energy 28, 29–43 (2016). https://doi.org/10.1016/j.nanoen.2016.08.027
Y. Zheng, Y. Jiao, L.H. Li, T. Xing, Y. Chen, M. Jaroniec, S.Z. Qiao, Toward design of synergistically active carbon-based catalysts for electrocatalytic hydrogen evolution. ACS Nano 8, 5290–5296 (2014). https://doi.org/10.1021/nn501434a
J. Wang, F. Xu, H. Jin, Y. Chen, Y. Wang, Non-noble metal-based carbon composites in hydrogen evolution reaction: Fundamentals to applications. Adv. Mater. 29, 1605838 (2017). https://doi.org/10.1002/adma.201605838
Z. Shi, W. Yang, Y. Gu, T. Liao, Z. Sun, Metal-nitrogen-doped carbon materials as highly efficient catalysts: Progress and rational design. Adv. Sci. 7, 2001069 (2020). https://doi.org/10.1002/advs.202001069
C. Gao, F. Lyu, Y. Yin, Encapsulated metal nanoparticles for catalysis. Chem. Rev. 121, 834–881 (2021). https://doi.org/10.1021/acs.chemrev.0c00237
Y. Yang, Z. Lun, G. Xia, F. Zheng, M. He, Q. Chen, Non-precious alloy encapsulated in nitrogen-doped graphene layers derived from MOFs as an active and durable hydrogen evolution reaction catalyst. Energy Environ. Sci. 8, 3563–3571 (2015). https://doi.org/10.1039/C5EE02460A
K. Gong, F. Du, Z. Xia, M. Durstock, L. Dai, Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 323, 760 (2009). https://doi.org/10.1126/science.1168049
L. Tao, Y. Wang, Y. Zou, N. Zhang, Y. Zhang, Y. Wu, Y. Wang, R. Chen, S. Wang, Charge transfer modulated activity of carbon-based electrocatalysts. Adv. Energy Mater. 10, 1901227 (2020). https://doi.org/10.1002/aenm.201901227
B. Qiao, A. Wang, X. Yang, L.F. Allard, Z. Jiang, Y. Cui, J. Liu, J. Li, T. Zhang, Single-atom catalysis of CO oxidation using Pt1/FeOx. Nat. Chem. 3, 634–641 (2011). https://doi.org/10.1038/nchem.1095
X. Wang, A. Vasileff, Y. Jiao, Y. Zheng, S.-Z. Qiao, Electronic and structural engineering of carbon-based metal-free electrocatalysts for water splitting. Adv. Mater. 31, 1803625 (2019). https://doi.org/10.1002/adma.201803625
S. Zhao, D.-W. Wang, R. Amal, L. Dai, Carbon-based metal-free catalysts for key reactions involved in energy conversion and storage. Adv. Mater. 31, 1801526 (2019). https://doi.org/10.1002/adma.201801526
R. Paul, L. Zhu, H. Chen, J. Qu, L. Dai, Recent advances in carbon-based metal-free electrocatalysts. Adv. Mater. 31, 1806403 (2019). https://doi.org/10.1002/adma.201806403
Y. Jia, L. Zhang, A. Du, G. Gao, J. Chen, X. Yan, C.L. Brown, X. Yao, Defect graphene as a trifunctional catalyst for electrochemical reactions. Adv. Mater. 28, 9532–9538 (2016). https://doi.org/10.1002/adma.201602912
Q. Han, Z. Cheng, J. Gao, Y. Zhao, Z. Zhang, L. Dai, L. Qu, Mesh-on-mesh graphitic-C3N4@graphene for highly efficient hydrogen evolution. Adv. Func. Mater. 27, 1606352 (2017). https://doi.org/10.1002/adfm.201606352
Z. Pei, J. Gu, Y. Wang, Z. Tang, Z. Liu, Y. Huang, Y. Huang, J. Zhao, Z. Chen, C. Zhi, Component matters: Paving the roadmap toward enhanced electrocatalytic performance of graphitic C3N4-based catalysts via atomic tuning. ACS Nano 11, 6004–6014 (2017). https://doi.org/10.1021/acsnano.7b01908
H. Huang, M. Yan, C. Yang, H. He, Q. Jiang, L. Yang, Z. Lu, Z. Sun, X. Xu, Y. Bando, Y. Yamauchi, Graphene nanoarchitectonics: Recent advances in graphene-based electrocatalysts for hydrogen evolution reaction. Adv. Mater. 31, 1903415 (2019). https://doi.org/10.1002/adma.201903415
X. Gui, Z. Zeng, Y. Zhu, H. Li, Z. Lin, Q. Gan, R. Xiang, A. Cao, Z. Tang, Three-dimensional carbon nanotube sponge-array architectures with high energy dissipation. Adv. Mater. 26, 1248–1253 (2014). https://doi.org/10.1002/adma.201304493
D. Yan, Y. Li, J. Huo, R. Chen, L. Dai, S. Wang, Defect chemistry of nonprecious-metal electrocatalysts for oxygen reactions. Adv. Mater. 29, 1606459 (2017). https://doi.org/10.1002/adma.201606459
C. Tang, H.-F. Wang, Q. Zhang, Multiscale principles to boost reactivity in gas-involving energy electrocatalysis. Acc. Chem. Res. 51, 881–889 (2018). https://doi.org/10.1021/acs.accounts.7b00616
Z. Pei, J. Zhao, Y. Huang, Y. Huang, M. Zhu, Z. Wang, Z. Chen, C. Zhi, Toward enhanced activity of a graphitic carbon nitride-based electrocatalyst in oxygen reduction and hydrogen evolution reactions via atomic sulfur doping. J. Mater. Chem. A 4, 12205–12211 (2016). https://doi.org/10.1039/C6TA03588D
P. Zhai, M. Xia, Y. Wu, G. Zhang, J. Gao, B. Zhang, S. Cao, Y. Zhang, Z. Li, Z. Fan, C. Wang, X. Zhang, J.T. Miller, L. Sun, J. Hou, Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting. Nat. Commun. 12, 4587 (2021). https://doi.org/10.1038/s41467-021-24828-9
Y. Peng, B. Lu, S. Chen, Carbon-supported single atom catalysts for electrochemical energy conversion and storage. Adv. Mater. 30, 1801995 (2018). https://doi.org/10.1002/adma.201801995
Y.-N. Chen, X. Zhang, Z. Zhou, Carbon-based substrates for highly dispersed nanoparticle and even single-atom electrocatalysts. Small Methods 3, 1900050 (2019). https://doi.org/10.1002/smtd.201900050
D. Liu, X. Li, S. Chen, H. Yan, C. Wang, C. Wu, Y.A. Haleem, S. Duan, J. Lu, B. Ge, P.M. Ajayan, Y. Luo, J. Jiang, L. Song, Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution. Nat. Energy 4, 512–518 (2019). https://doi.org/10.1038/s41560-019-0402-6
M.B. Gawande, P. Fornasiero, R. Zbořil, Carbon-based single-atom catalysts for advanced applications. ACS Catal. 10, 2231–2259 (2020). https://doi.org/10.1021/acscatal.9b04217
Z. Pu, I.S. Amiinu, R. Cheng, P. Wang, C. Zhang, S. Mu, W. Zhao, F. Su, G. Zhang, S. Liao, S. Sun, Single-atom catalysts for electrochemical hydrogen evolution reaction: Recent advances and future perspectives. Nano-Micro Letters 12, 21 (2020). https://doi.org/10.1007/s40820-019-0349-y
M. Fan, J. Cui, J. Wu, R. Vajtai, D. Sun, P.M. Ajayan, Improving the catalytic activity of carbon-supported single atom catalysts by polynary metal or heteroatom doping. Small 16, 1906782 (2020). https://doi.org/10.1002/smll.201906782
K. Gao, B. Wang, L. Tao, B.V. Cunning, Z. Zhang, S. Wang, R.S. Ruoff, L. Qu, Efficient metal-free electrocatalysts from N-doped carbon nanomaterials: Mono-doping and Co-doping. Adv. Mater. 31, 1805121 (2019). https://doi.org/10.1002/adma.201805121
F. Schedin, A.K. Geim, S.V. Morozov, E.W. Hill, P. Blake, M.I. Katsnelson, K.S. Novoselov, Detection of individual gas molecules adsorbed on graphene. Nat. Mater. 6, 652–655 (2007). https://doi.org/10.1038/nmat1967
Y. Chen, S. Ji, Y. Wang, J. Dong, W. Chen, Z. Li, R. Shen, L. Zheng, Z. Zhuang, D. Wang, Y. Li, Isolated single iron atoms anchored on N-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction. Angew. Chem. Int. Ed. 56, 6937–6941 (2017). https://doi.org/10.1002/anie.201702473
P. Su, W. Pei, X. Wang, Y. Ma, Q. Jiang, J. Liang, S. Zhou, J. Zhao, J. Liu, G.Q. Lu, Exceptional electrochemical HER performance with enhanced electron transfer between Ru nanoparticles and single atoms dispersed on a carbon substrate. Angew. Chem. Int. Ed. 60, 16044–16050 (2021). https://doi.org/10.1002/anie.202103557
Y. Zheng, Y. Jiao, Y. Zhu, L.H. Li, Y. Han, Y. Chen, A. Du, M. Jaroniec, S.Z. Qiao, Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 5, 3783 (2014). https://doi.org/10.1038/ncomms4783
Y. Liang, Y. Li, H. Wang, H. Dai, Strongly coupled inorganic/nanocarbon hybrid materials for advanced electrocatalysis. J. Am. Chem. Soc. 135, 2013–2036 (2013). https://doi.org/10.1021/ja3089923
Y. Zhang, L. Guo, L. Tao, Y. Lu, S. Wang, Defect-based single-atom electrocatalysts. Small Methods 3, 1800406 (2019). https://doi.org/10.1002/smtd.201800406
H. Wang, Y. Liang, M. Gong, Y. Li, W. Chang, T. Mefford, J. Zhou, J. Wang, T. Regier, F. Wei, H. Dai, An ultrafast nickel–iron battery from strongly coupled inorganic nanoparticle/nanocarbon hybrid materials. Nat. Commun. 3, 917 (2012). https://doi.org/10.1038/ncomms1921
K. Khan, T. Liu, M. Arif, X. Yan, M.D. Hossain, F. Rehman, S. Zhou, J. Yang, C. Sun, S.-H. Bae, J. Kim, K. Amine, X. Pan, Z. Luo, Laser-irradiated holey graphene-supported single-atom catalyst towards hydrogen evolution and oxygen reduction. Adv. Energy Mater. 11, 2101619 (2021). https://doi.org/10.1002/aenm.202101619
R. Liu, Z. Gong, J. Liu, J. Dong, J. Liao, H. Liu, H. Huang, J. Liu, M. Yan, K. Huang, H. Gong, J. Zhu, C. Cui, G. Ye, H. Fei, Design of aligned porous carbon films with single-atom Co–N–C sites for high-current-density hydrogen generation. Adv. Mater. 33, 2103533 (2021). https://doi.org/10.1002/adma.202103533
J. Yang, W. Liu, M. Xu, X. Liu, H. Qi, L. Zhang, X. Yang, S. Niu, D. Zhou, Y. Liu, Y. Su, J.-F. Li, Z.-Q. Tian, W. Zhou, A. Wang, T. Zhang, Dynamic behavior of single-atom catalysts in electrocatalysis: Identification of Cu-N3 as an active site for the oxygen reduction reaction. J. Am. Chem. Soc. 143, 14530–14539 (2021). https://doi.org/10.1021/jacs.1c03788
G. Yang, J. Zhu, P. Yuan, Y. Hu, G. Qu, B.-A. Lu, X. Xue, H. Yin, W. Cheng, J. Cheng, W. Xu, J. Li, J. Hu, S. Mu, J.-N. Zhang, Regulating Fe-spin state by atomically dispersed Mn–N in Fe–N–C catalysts with high oxygen reduction activity. Nat. Commun. 12, 1734 (2021). https://doi.org/10.1038/s41467-021-21919-5
L. Cao, Q. Luo, W. Liu, Y. Lin, X. Liu, Y. Cao, W. Zhang, Y. Wu, J. Yang, T. Yao, S. Wei, Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution. Nat. Catal. 2, 134–141 (2019). https://doi.org/10.1038/s41929-018-0203-5
D. Voiry, H.S. Shin, K.P. Loh, M. Chhowalla, Low-dimensional catalysts for hydrogen evolution and CO2 reduction. Nat. Rev. Chem. 2, 0105 (2018). https://doi.org/10.1038/s41570-017-0105
M. Ming, Y. Zhang, C. He, L. Zhao, S. Niu, G. Fan, J.-S. Hu, Room-temperature sustainable synthesis of selected platinum group metal (PGM = Ir, Rh, and Ru) nanocatalysts well-dispersed on porous carbon for efficient hydrogen evolution and oxidation. Small 15, 1903057 (2019). https://doi.org/10.1002/smll.201903057
T. Liu, S. Wang, Q. Zhang, L. Chen, W. Hu, C.M. Li, Ultrasmall Ru2P nanoparticles on graphene: A highly efficient hydrogen evolution reaction electrocatalyst in both acidic and alkaline media. Chem. Commun. 54, 3343–3346 (2018). https://doi.org/10.1039/C8CC01166D
L. Wang, Y. Li, M. Xia, Z. Li, Z. Chen, Z. Ma, X. Qin, G. Shao, Ni nanoparticles supported on graphene layers: An excellent 3D electrode for hydrogen evolution reaction in alkaline solution. J. Power Sour. 347, 220–228 (2017). https://doi.org/10.1016/j.jpowsour.2017.02.017
Y. Jiang, X. Li, S. Yu, L. Jia, X. Zhao, C. Wang, Reduced graphene oxide-modified carbon nanotube/polyimide film supported MoS2 nanoparticles for electrocatalytic hydrogen evolution. Adv. Func. Mater. 25, 2693–2700 (2015). https://doi.org/10.1002/adfm.201500194
L. He, F. Weniger, H. Neumann, M. Beller, Synthesis, characterization, and application of metal nanoparticles supported on nitrogen-doped carbon: Catalysis beyond electrochemistry. Angew. Chem. Int. Ed. 55, 12582–12594 (2016). https://doi.org/10.1002/anie.201603198
T.-W. Lin, C.-J. Liu, J.-Y. Lin, Facile synthesis of MoS3/carbon nanotube nanocomposite with high catalytic activity toward hydrogen evolution reaction. Appl. Catal. B 134–135, 75–82 (2013). https://doi.org/10.1016/j.apcatb.2013.01.004
X. Sun, N. Habibul, H. Du, Co0.85Se magnetic nanoparticles supported on carbon nanotubes as catalyst for hydrogen evolution reaction. Chin. J. Catal. 42, 235–243 (2021). https://doi.org/10.1016/S1872-2067(20)63632-4
T.-W. Lin, C.-J. Liu, C.-S. Dai, Ni3S2/carbon nanotube nanocomposite as electrode material for hydrogen evolution reaction in alkaline electrolyte and enzyme-free glucose detection. Appl. Catal. B 154–155, 213–220 (2014). https://doi.org/10.1016/j.apcatb.2014.02.017
D.H. Kweon, M.S. Okyay, S.-J. Kim, J.-P. Jeon, H.-J. Noh, N. Park, J. Mahmood, J.-B. Baek, Ruthenium anchored on carbon nanotube electrocatalyst for hydrogen production with enhanced Faradaic efficiency. Nat. Commun. 11, 1278 (2020). https://doi.org/10.1038/s41467-020-15069-3
X. Wu, Z. Wang, D. Zhang, Y. Qin, M. Wang, Y. Han, T. Zhan, B. Yang, S. Li, J. Lai, L. Wang, Solvent-free microwave synthesis of ultra-small Ru-Mo2C@CNT with strong metal-support interaction for industrial hydrogen evolution. Nat. Commun. 12, 4018 (2021). https://doi.org/10.1038/s41467-021-24322-2
H. Tabassum, R. Zou, A. Mahmood, Z. Liang, S. Guo, A catalyst-free synthesis of B, N co-doped graphene nanostructures with tunable dimensions as highly efficient metal free dual electrocatalysts. J. Mater. Chem. A 4, 16469–16475 (2016). https://doi.org/10.1039/C6TA07214C
T. Sun, Q. Wu, Y. Jiang, Z. Zhang, L. Du, L. Yang, X. Wang, Z. Hu, Sulfur and nitrogen codoped carbon tubes as bifunctional metal-free electrocatalysts for oxygen reduction and hydrogen evolution in acidic media. Chem. Eur. J. 22, 10326–10329 (2016). https://doi.org/10.1002/chem.201601535
X. Wu, B. Feng, W. Li, Y. Niu, Y. Yu, S. Lu, C. Zhong, P. Liu, Z. Tian, L. Chen, W. Hu, C.M. Li, Metal-support interaction boosted electrocatalysis of ultrasmall iridium nanoparticles supported on nitrogen doped graphene for highly efficient water electrolysis in acidic and alkaline media. Nano Energy 62, 117–126 (2019). https://doi.org/10.1016/j.nanoen.2019.05.034
K.-C. Pham, Y.-H. Chang, D.S. McPhail, C. Mattevi, A.T.S. Wee, D.H.C. Chua, Amorphous molybdenum sulfide on graphene–carbon nanotube hybrids as highly active hydrogen evolution reaction catalysts. ACS Appl. Mater. Interfaces. 8, 5961–5971 (2016). https://doi.org/10.1021/acsami.5b09690
B. Cao, M. Hu, Y. Cheng, P. Jing, B. Liu, B. Zhou, X. Wang, R. Gao, X. Sun, Y. Du, J. Zhang, Tailoring the d-band center of N-doped carbon nanotube arrays with Co4N nanoparticles and single-atom Co for a superior hydrogen evolution reaction. NPG Asia Mater. 13, 1 (2021). https://doi.org/10.1038/s41427-020-00264-x
J. Liu, X. Wan, S. Liu, X. Liu, L. Zheng, R. Yu, J. Shui, Hydrogen passivation of M–N–C (M = Fe, Co) catalysts for storage stability and ORR activity improvements. Adv. Mater. 33, 2103600 (2021). https://doi.org/10.1002/adma.202103600
Z. Wei, Y. Liu, Z. Peng, H. Song, Z. Liu, B. Liu, B. Li, B. Yang, S. Lu, Cobalt-ruthenium nanoalloys parceled in porous nitrogen-doped graphene as highly efficient difunctional catalysts for hydrogen evolution reaction and hydrolysis of ammonia borane. ACS Sustain. Chem. Eng. 7, 7014–7023 (2019). https://doi.org/10.1021/acssuschemeng.8b06745
J.-Y. Wang, T. Ouyang, N. Li, T. Ma, Z.-Q. Liu, S, N co-doped carbon nanotube-encapsulated core-shelled CoS2@Co nanoparticles: efficient and stable bifunctional catalysts for overall water splitting. Sci. Bull. 63, 1130–1140 (2018). https://doi.org/10.1016/j.scib.2018.07.008
M. Tavakkoli, T. Kallio, O. Reynaud, A.G. Nasibulin, C. Johans, J. Sainio, H. Jiang, E.I. Kauppinen, K. Laasonen, Single-shell carbon-encapsulated iron nanoparticles: Synthesis and high electrocatalytic activity for hydrogen evolution reaction. Angew. Chem. Int. Ed. 54, 4535–4538 (2015). https://doi.org/10.1002/anie.201411450
T. Ouyang, Y.-Q. Ye, C.-Y. Wu, K. Xiao, Z.-Q. Liu, Heterostructures composed of N-doped carbon nanotubes encapsulating cobalt and β–Mo2C nanoparticles as bifunctional electrodes for water splitting. Angew. Chem. Int. Ed. 58, 4923–4928 (2019). https://doi.org/10.1002/anie.201814262
X. Wang, Y. Zheng, J. Yuan, J. Shen, L. Niu, A.-J. Wang, Controllable synthesis of caterpilliar-like molybdenum sulfide @carbon nanotube hybrids with core shell structure for hydrogen evolution. Electrochim. Acta 235, 422–428 (2017). https://doi.org/10.1016/j.electacta.2017.02.093
J. Yu, G. Li, H. Liu, L. Zeng, L. Zhao, J. Jia, M. Zhang, W. Zhou, H. Liu, Y. Hu, Electrochemical flocculation integrated hydrogen evolution reaction of Fe@N-doped carbon nanotubes on iron foam for ultralow voltage electrolysis in neutral media. Adv. Sci. 6, 1901458 (2019). https://doi.org/10.1002/advs.201901458
T. Li, G. Luo, K. Liu, X. Li, D. Sun, L. Xu, Y. Li, Y. Tang, Encapsulation of Ni3Fe nanoparticles in N-doped carbon nanotube-grafted carbon nanofibers as high-efficiency hydrogen evolution electrocatalysts. Adv. Func. Mater. 28, 1805828 (2018). https://doi.org/10.1002/adfm.201805828
J. Su, Y. Yang, G. Xia, J. Chen, P. Jiang, Q. Chen, Ruthenium-cobalt nanoalloys encapsulated in nitrogen-doped graphene as active electrocatalysts for producing hydrogen in alkaline media. Nat. Commun. 8, 14969 (2017). https://doi.org/10.1038/ncomms14969
J. Wang, R. Zhu, J. Cheng, Y. Song, M. Mao, F. Chen, Y. Cheng, Co, Mo2C encapsulated in N-doped carbon nanofiber as self-supported electrocatalyst for hydrogen evolution reaction. Chem. Eng. J. 397, 125481 (2020). https://doi.org/10.1016/j.cej.2020.125481
Z. Chen, R. Wu, Y. Liu, Y. Ha, Y. Guo, D. Sun, M. Liu, F. Fang, Ultrafine Co nanoparticles encapsulated in carbon-nanotubes-grafted graphene sheets as advanced electrocatalysts for the hydrogen evolution reaction. Adv. Mater. 30, 1802011 (2018). https://doi.org/10.1002/adma.201802011
J. Ma, M. Wang, G. Lei, G. Zhang, F. Zhang, W. Peng, X. Fan, Y. Li, Polyaniline derived N-doped carbon-coated cobalt phosphide nanoparticles deposited on N-doped graphene as an efficient electrocatalyst for hydrogen evolution reaction. Small 14, 1702895 (2018). https://doi.org/10.1002/smll.201702895
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Zhao, B., Xu, S. (2022). Carbon-Based Nanomaterials for Hydrogen Evolution Reaction. In: Zhang, JN. (eds) Carbon-Based Nanomaterials for Energy Conversion and Storage. Springer Series in Materials Science, vol 325. Springer, Singapore. https://doi.org/10.1007/978-981-19-4625-7_6
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DOI: https://doi.org/10.1007/978-981-19-4625-7_6
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Publisher Name: Springer, Singapore
Print ISBN: 978-981-19-4624-0
Online ISBN: 978-981-19-4625-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)