Abstract
Pyrolysis property of ammonium perchlorate (AP) are significance to the combustion properties of AP-based propellant. This study will seek to disclose the effects of the graphene-ferrite nanocomplex (rGO-MFe2O4, M = Ni, Co and Zn), fabricated via the facile one-pot solvothermal method, for AP pyrolysis. Among them, the rGO-CoFe2O4 own outstanding catalytic property for AP pyrolysis, and the high decomposition peak temperature (THDP) of AP + rGO-CoFe2O4 were decreased by 57.4 °C compared with pristine AP. Results of this study are helpful to understand the catalytic property and mechanism of rGO-MFe2O4 for AP pyrolysis.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
N.K. Dharmarathne, J.C. Mackie, E.M. Kennedy, M. Stockenhuber, Mechanism and rate of thermal decomposition of hexachlorocyclopentadiene and its importance in PCDD/F formation from the combustion of cyclodiene pesticides. J. Phys. Chem. A (2017)
F. Wang, L. Chen, D. Geng, J. Wu, J. Lu, C. Wang, Thermal decomposition mechanism of CL-20 at different temperatures by ReaxFF reactive molecular dynamics simulations. J. Phys. Chem. A 122(16), 3971–3979 (2018)
J.M. Yang, MOF-derived hollow NiO-ZnO composite micropolyhedra and their application in catalytic thermal decomposition of ammonium perchlorate. Russ. J. Phys. Chem. A 91(7), 1214–1220 (2017)
H. Cai, L. Tian, B. Huang, G. Yang, D. Guan, H. Huang, 1,1-Diamino-2,2-dintroethene (FOX-7) nanocrystals embedded in mesoporous carbon FDU-15. Microporous Mesoporous Mater. 170, 20–25 (2013)
M.M. Bishop, N. Velisavljevic, R. Chellappa, Y. Vohra, High pressure-temperature phase diagram of 1,1-diamino-2,2-dinitroethylene (FOX-7). J. Phys. Chem. A 119(37), 9739–9747 (2015)
M. Zhang, F. Zhao, Y. Yang, H. Li, J. Zhang, W. Ma, H. Gao, N. Li, Shape-dependent catalytic activity of nano-Fe2O3 on the thermal decomposition of TKX-50. Acta Phys.-Chim. Sin. 35, 0001–0009 (2019)
V.G. Kiselev, N.P. Gritsan, Unexpected Primary Reactions for Thermolysis of 1,1-Diamino-2,2-dinitroethylene (FOX-7) Revealed by ab Initio Calculations. J. Phys. Chem. A 118(36), 8002–8008 (2014)
C. Ye, X. Ju, F. Zhao, S. Xu, Adsorption and decomposition mechanism of 1,1-diamino-2,2-dinitroethylene on Al (111) surface by periodic DFT calculations. Chin. J. Chem. 30(10), 2539–2548 (2012)
X.Z. Fan, J.Z. Li, Z.R. Liu, Thermal behavior of 1,1-diamino-2,2-dinitroethylene. J. Phys. Chem. A 111(51), 13291–13295 (2007)
Y. Liu, F. Li, H. Sun, Thermal decomposition of FOX-7 studied by ab initio molecular dynamics simulations. Theoret. Chem. Acc. 133(10), 1567 (2014)
Z. Zheng, J. Xu, J. Zhao, First-principles studies on the thermal decomposition behavior of FOX-7. High Pressure Res. 30(2), 301–309 (2010)
F. He, K.Z. Xu, H. Zhang, Q.Q. Qiu, J.R. Song, F.Q. Zhao, Two new copper-FOX-7 complexes: synthesis, crystal structure, and thermal behavior. J. Coord. Chem. 66(5), 845–855 (2013)
Z.A. Dreger, Y. Tao, Y.M. Gupta, High-pressure vibrational and polymorphic response of 1,1-diamino-2,2-dinitroethene single crystals: Raman spectroscopy. J. Phys. Chem. A 118(27), 5002–5012 (2014)
A. Hu, B. Larade, H. Abou-Rachid, L.S. Lussier, H. Guo, A first principles density functional study of crystalline FOX-7 chemical decomposition process under external pressure. Propellants, Explos., Pyrotech. 31(5), 355–360 (2006)
V.V. Zakharov, N.V. Chukanov, N.N. Dremova, A.D. Chervonnyi, G.V. Shilov, B.L. Korsounskii, N.N. Volkova, High-temperature structural transformations of 1,1-diamino-2,2-dinitroethene (FOX-7). Propellants, Explos., Pyrotech. 41(6), 1006–1012 (2016)
M. Zhang, F. Zhao, Y. Yang, T. An, W. Qu, H. Li, J. Zhang, N. Li, Catalytic activity of ferrates (NiFe2O4, ZnFe2O4 and CoFe2O4) on the thermal decomposition of ammonium perchlorate. Propellants, Explos., Pyrotech. 44, 1–10 (2019)
M. Zong, Y. Huang, H. Wu, Y. Zhao, Q. Wang, X. Sun, One-pot hydrothermal synthesis of RGO/CoFe2O4 composite and its excellent microwave absorption properties. Mater. Lett. 114, 52–55 (2014)
S. Huang, Y. Xu, M. Xie, H. Xu, M. He, J. Xia, H. Li, Synthesis of magnetic CoFe2O4/g-C3N4 composite and its enhancement of photocatalytic ability under visible-light. Colloids Surf., A 478, 71–80 (2015)
L. Sun, R. Shao, L. Tang, Z. Chen, Synthesis of ZnFe2O4/ZnO nanocomposites immobilized on graphene with enhanced photocatalytic activity under solar light irradiation. J. Alloy. Compd. 564, 55–62 (2013)
A. Dey, J. Athar, P. Varma, H. Prasant, A.K. Sikder, S. Chattopadhyay, Graphene-iron oxide nanocomposite (GINC): an efficient catalyst for ammonium perchlorate (AP) decomposition and burn rate enhancer for AP based composite propellant. RSC Adv. 5(3), 1950–1960 (2015)
M. Zhang, F. Zhao, Y. Yang, J. Zhang, N. Li, H. Gao, Effect of rGO–Fe2O3 nanocomposites fabricated in different solvents on the thermal decomposition properties of ammonium perchlorate. CrystEngComm 20, 7010–7019 (2018)
Y. Yuan, W. Jiang, Y. Wang, P. Shen, F. Li, P. Li, H. Gao, Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate. Appl. Surf. Sci. 303, 354–359 (2014)
Y. Fu, X. Wang, Magnetically separable ZnFe2O4–graphene catalyst and its high photocatalytic performance under visible light irradiation. Ind. Eng. Chem. Res. 50(12), 7210–7218 (2011)
H. Xia, Y. Qian, Y. Fu, X. Wang, Graphene anchored with ZnFe2O4 nanoparticles as a high-capacity anode material for lithium-ion batteries. Solid State Sci. 17, 67–71 (2013)
R.S. Booth, L.J. Butler, Thermal decomposition pathways for 1,1-diamino-2,2-dinitroethene (FOX-7). J. Chem. Phys. 141(13), 134315 (2014)
Acknowledgements
The financial support by the National Natural Science Foundation of China (Grant number: 52027809) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 China Ordnance Society
About this paper
Cite this paper
Hou, X., Zhang, M., Zhao, F., Li, H., Zuo, Y., Li, R. (2022). Catalytic Performances of rGO-MFe2O4 (M = Ni, Co and Zn) for Pyrolysis of Ammonium Perchlorate. In: Gany, A., Fu, X. (eds) 2021 International Conference on Development and Application of Carbon Nanomaterials in Energetic Materials. ICCN 2021. Springer Proceedings in Physics, vol 276. Springer, Singapore. https://doi.org/10.1007/978-981-19-1774-5_18
Download citation
DOI: https://doi.org/10.1007/978-981-19-1774-5_18
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-19-1773-8
Online ISBN: 978-981-19-1774-5
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)