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Cold Isostatic Pressing Treatment in the Preparation of Al and Y-Doped LLZO (Li6.15La3Zr1.75Al0.2Y0.25O12-δ) Solid Electrolyte

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Recent Advances in Renewable Energy Systems

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 876))

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Abstract

Synthesis of Al-Y-doped LLZO has been conducted by solid-state reaction. The synthesized powder was treated by different treatments which were sintered, non-sintered, and also the different CIP pressure. The sintering treatment was conducted at 1050 and 1200 °C. Meanwhile, the applied pressures were 20, 30, and 40 MPa. XRD analysis equipped with the Le Bail Refinement found that the Al-Y-doped LLZO was crystallized within cubic phase, with a percentage composition of 84.89%. Impedance analysis followed by ZView fitting and conductivity calculation found that the green pellet formed by 40 MPa CIP pressure provide the highest ionic conductivity, i.e., 1.06 × 10–5 S cm−1. The experiment result shows that the ionic conductivity increases by the increase of the applied pressure.

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Acknowledgements

Authors thank The Ministry of Education and Culture, Directorate General of Higher Education, Republic Indonesia for funding this research under the scheme of PDUPT 2021.

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Authors and Affiliations

  1. Research Group of Solid-State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl. Ir. Sutami 36 A Kentingan, Surakarta, 57126, Indonesia

    Septia Kurniawati Arifah, Fitria Rahmawati & Yuniawan Hidayat

Authors
  1. Septia Kurniawati Arifah
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  2. Fitria Rahmawati
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  3. Yuniawan Hidayat
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Correspondence to Fitria Rahmawati .

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Editors and Affiliations

  1. Faculty of Engineering and Science, University of Agder, Grimstad, Norway

    Mohan Kolhe

  2. Department of Mechanical and Biofunctional Systems, The University of Tokyo, Tokyo, Japan

    Aziz Muhammad

  3. Electrochemical Energy Storage, Helmholtz-Institute Ulm, Ulm, Germany

    Abdel El Kharbachi

  4. Department of Mechanical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia

    Tri Yogi Yuwono

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Arifah, S.K., Rahmawati, F., Hidayat, Y. (2022). Cold Isostatic Pressing Treatment in the Preparation of Al and Y-Doped LLZO (Li6.15La3Zr1.75Al0.2Y0.25O12-δ) Solid Electrolyte. In: Kolhe, M., Muhammad, A., El Kharbachi, A., Yuwono, T.Y. (eds) Recent Advances in Renewable Energy Systems. Lecture Notes in Electrical Engineering, vol 876. Springer, Singapore. https://doi.org/10.1007/978-981-19-1581-9_26

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  • DOI: https://doi.org/10.1007/978-981-19-1581-9_26

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