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Advanced Functional Polymer-Based Porous Composites for CO2 Capture

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Polymer-Based Advanced Functional Materials for Energy and Environmental Applications

Part of the book series: Energy, Environment, and Sustainability ((ENENSU))

Abstract

Due to the uncontrolled release of greenhouse gases into the atmosphere through anthropogenic activities, the planet's temperature and natural ecosystem are being adversely affected globally. Fossil-fueled power plants and transportation are the major sources for the release of CO2 into the atmosphere. Carbon capture and sequestration (CCS) is one of the promising alternatives for CO2 mitigation. To capture this CO2, highly selective and high storage capacity adsorbent material is required. Also, the adsorbent should be chemically stable, highly porous, large surface area, minimal energy input, easy to regenerate and low cost. Amine-based technology has long been used for CO2 mitigation but this process is very much energy intensive. Physical sorbents with high CO2 selectivity are available in powder form and cannot be used for real-world applications. There is a need to transform it in some particulate form or one can form a porous framework and that can be easily done using polymers and polymers are known to be mechanically, thermally and chemically very stable. Also, polymers due to the presence of abundant functionalizable sites can be functionalized to make the polymer surface rich in CO2-philic moieties. So, this chapter is focused to highlight various functionalized organic porous polymers and their CO2 uptake capacity, CO2/N2 selectivity, regenerability and also challenges and potential of this kind of materials in gas separation is finally discussed.

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Abbreviations

BET:

Brunauer-Emmett-Teller

BHMAA:

Bis(o-hydroxyl) maleamic acid

BHMI:

Bis(o-hydroxyl)-maleimides

BisADA:

Bisphenol A type dianhydride

CCS:

Carbon capture and sequestration

CNTs:

Carbon nano tubes

DAC:

Direct air capture

DBN:

1,5-Diazabicyclo [4.3.0]-non-5-ene

Di:

Diffusion coefficient of gas CO2

Dj:

Diffusion coefficient of another gas (N2, H2 or CH4)

FFV:

Fractional free volume

GHG:

Greenhouse gas

GO:

Graphene oxide

GPU:

Gas Permeation Unit

MBB:

Molecular building blocks

MOFs:

Metal organic frameworks

OPDA:

4,4′-oxydiphthalic anhydride

PBO:

Polybenzoxazole

PBI:

Polybenzimidazole

PBZ:

Polybenzothiazole

PEO:

Poly (ethylene oxide)

Pi:

Permeability of species i

PI:

Polyimides

POF:

Porous organic framework

POPs:

Porous organic polymers

Si:

Solubility coefficient of gas component CO2

Sj:

Solubility coefficient of another gas (N2, H2 or CH4)

SNWs:

Schiff base networks

TFN:

Thin film nanocomposite

Tg:

Glass transition temperation

TR:

Thermally rearranged

αij:

Ideal selectivity of species i over j

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Authors and Affiliations

  1. Department of Chemical Engineering, School of Technology, PanditDeendayal Energy University, Gandhinagar, Gujarat, 382007, India

    Ravi Vaghasia, Bharti Saini & Anirban Dey

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  1. Ravi Vaghasia
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  2. Bharti Saini
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  1. Centre for Research and Development, Department of Chemistry, The National Institute of Engineering, Mysore, India

    Nithin Kundachira Subramani

  2. Centre for Nano and Material Sciences, Jain University, Bangalore, India

    S. K. Nataraj

  3. Department of Mechanical Engineering, Department of Chemistry, Sitarambhai Naranjibhai Patel Institute, Bardoli, India

    Chetankumar Patel

  4. Department of Chemistry, The National Institute of Engineering, Mysore, India

    Sachhidananda Shivanna

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Vaghasia, R., Saini, B., Dey, A. (2022). Advanced Functional Polymer-Based Porous Composites for CO2 Capture. In: Subramani, N.K., Nataraj, S.K., Patel, C., Shivanna, S. (eds) Polymer-Based Advanced Functional Materials for Energy and Environmental Applications. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-16-8755-6_8

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