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Glass in the Middle East and Western Europe at the End of the First Millennium CE, Transition from Natron to Plant Ash Soda or Forest Glasses

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Ancient Glass of South Asia

Abstract

The production of natron glass started at the beginning of the first millennium BCE and prevailed in the Mediterranean world for almost two thousand years. This production seems to cease progressively from the end of the eighth century CE onwards, with a different timing based on the region (e.g. Syria, Egypt). A recent study of Islamic glass weights and stamps, which provide a fairly continuous chronology of glass compositions from the reign of Abd al-Malik (685–705 CE) to the reign of the Fatimid caliph al-Hakim (996–1020 CE), shows that natron glass was produced in Egypt at least until the middle of the ninth century. Thus, in the Mediterranean world, a radical change is observed in glass recipes between the end of the eighth century and the tenth century CE resulting in the systematic use of soda plant ashes instead of natron. This recipe was then adopted all around the Mediterranean and became predominant in that area by the end of the twelfth century.

In Western Europe, the halt of the import of natron glass at the end of the eighth century also induced a period of transition that led to the emergence of the production of new glass types. There, imported natron glass is progressively replaced by locally made glass produced with fluxes containing potash, lime or lead. Two case studies of glass workshops are used to illustrate some original solutions developed to maintain glass manufacturing in these regions.

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References

  • Angelini, I., Artioli, G., Bellintani, P., Diella, V., Gemmi, M., Polla, A., & Rossi, A. (2004). Chemical analyses of Bronze Age glasses from Frattesina di Rovigo, Northern Italy. Journal of Archaeological Science, 31(8), 1175–1184.

    Article  Google Scholar 

  • Balog, P. (1976). Umayyad’,Abbasid and Tulunid: Glass weights and vessel stamps. American Numismatic Society.

    Google Scholar 

  • Bates, M. L. (1981). The function of fāṭimid and ayyūbid glass wėights. Journal of the Economic and Social History of the Orient /journal De L’histoire Économique Et Sociale De L’orient, 24, 63–92.

    Google Scholar 

  • Bayley, J. (2009). Early medieval lead-rich glass in the British Isles—a survey of the evidence. In K. Janssens, P. Degryse, P. Cosyns, J. Caen, & L. Van’t dack (Eds.), Annales du 17e Congrès de l’Association Internationale pour l’Histoire du Verre, Anvers, 4–8 septembre 2006 (pp. 255–260). Brussels.

    Google Scholar 

  • Bellintani, P. (1997). Frattesina: l’ambra e la produzione vitrea nel contesto delle relazioni transalpine. Ori Delle Alpi, Quaderni Della Sezione Archeologica Castello Del Buonconsiglio, 6, 116–129.

    Google Scholar 

  • Bezborodov, M. A. (1975). Chimie und technologie der antiken und mittelalterlichen Gläser. Verlag P. von Zabhern.

    Google Scholar 

  • Biavati, A., & Verità, M. (1989). The glass from Frattesina, a glassmaking center in the late Bronze Age, dans Rivista della Stazione Sperimentale Vetro. 4, 295–299.

    Google Scholar 

  • Brill, R. H. (1995). Appendix 3: Chemical analyses of some glass fragments from Nishapur in the Corning Museum of Art. In J. Kroeger (Ed.), Nishapur: Glass of the early Islamic period (pp. 211–233). Metropolitan Museum of Art.

    Google Scholar 

  • Brill, R. H. (1999). Chemical analyses of early glasses. Corning Museum of Glass.

    Google Scholar 

  • Cagno, S., Favaretto, L., Mendera, M., Izmer, A., Vanhaecke, F., & Janssens, K. (2012). Evidence of early medieval soda ash glass in the archaeological site of San Genesio (Tuscany). Journal of Archaeological Science, 39, 1540–1552.

    Article  Google Scholar 

  • Carmona, N., Angeles Villegas, M., Jimenez, P., Navarro, J., & Garcia-Heras, M. (2009). Islamic glasses from al-Andalus: Characterisation of materials from a Murcian workshop (12th century AD, Spain). Journal of Cultural Heritage, 10, 439–445.

    Article  Google Scholar 

  • De Juan Ares, J., Fernández Calderón, N., Muñiz López, I., García Álvarez-Busto, A., & Schibille, N. (2018). Islamic soda-ash glasses in the Christian kingdoms of Asturias and León (Spain). Journal of Archaeological Science: Reports, 22, 257–263.

    Google Scholar 

  • De Juan Ares, J., & Schibille, N. (2017). Glass import and production in Hispania during the early medieval period: the glass from Ciudad de Vascos (Toledo). PLoS One 12(7). https://doi.org/10.1371/journal.pone.0182129.

  • Décobert, C. (2003). Le natron égyptien au Moyen-Age. In D. Foy, & M. D. Nenna (Eds.), Echanges et commerce du verre dans le monde antique (Actes du colloque de l’Association Française pour l’Archéologie du Verre, Aix-en- Provence et Marseille, 7–9 juin 2001) (pp. 125–127). Montagnac.

    Google Scholar 

  • Duckworth, C. N., Córdoba de la Llave, R., Faber, E. W., Govantes Edwards, D. J., & Henderson, J. (2015). Electron microprobe analysis of 9th–12th century Islamic glass from Córdoba. Archaeometry, 57(1), 27–50.

    Article  Google Scholar 

  • Foy, D. (2001). Le verre médiéval et son artisanat en France méditerranéenne. CNRS Editions.

    Google Scholar 

  • Foy, D., Picon, M., & Vichy M. (2003a). Verres Omeyyades et Abbassides D’origine Egyptienne: les Témoignages de l’Archéologie et de L'Archéométrie. In AIHV Annales du 15e Congrès, 2001 (pp. 135–143). AIHV.

    Google Scholar 

  • Foy, D., Picon, M., Vichy, M., & Thirion-Merle, V. (2003b). Caractérisation des verres de la fin de l’antiquité en Méditerranée Occidentale: L’émergence de nouveaux courants commerciaux. In D. Foy, & M. D. Nenna (Eds.), Echanges et Commerce du Verre dans le Monde Antique (Actes du colloque de l’Association Française pour l’Archéologie du Verre, Aix-en- Provence et Marseille, 7–9 juin 2001) (pp. 41–85). Montagnac.

    Google Scholar 

  • Foy, D., & Nenna, M. D. (2001). Tout Feu Tout Sable: Mille Ans de Verre Antique dans le Midi de la France Marseille. Musées de Marseille.

    Google Scholar 

  • Freestone, I. C., & Gorin-Rosen, Y. (1999). The great glass slab at Bet She‘arim, Israel: An Early Islamic glassmaking experiment? Journal of Glass Studies, 41, 105–116.

    Google Scholar 

  • Freestone, I. C. Forthcoming. Glass production in the first millennium CE: a compositional perspective. In F. Klimscha, H. J. Karlsen, S. Hansen, & J. Renn (Eds.) Glas und Glasproduktion in Ur- und Frühgeschichtlicher Zeit. TOPOI.

    Google Scholar 

  • Freestone, I. C. (2002). Composition and affinities of glass from the furnaces on the Island Site, Tyre. Journal of Glass Studies, 44, 67–77.

    Google Scholar 

  • Freestone, I. C., Degryse, P., Lankton, J., Gratuze, B., & Schneider, J. (2018). HIMT, glass composition and commodity branding in the primary glass industry. In D. Rosenow, M. Phelps, A. Meek, & I. C. Freestone (Eds.), Things that travelled: Mediterranean glass in the first millennium CE (pp. 159–190). UCL Press.

    Chapter  Google Scholar 

  • Freestone, I. C., Gorin-Rosen, Y., & Hughes, M. J. (2000). Primary glass from Israel and the production of glass in late antiquity and the early Islamic period. In M. D. Nenna (Ed.), La Route du Verre: Ateliers Primaires et Secondaires du Second Millénaire av. J.-C. au Moyen Age (pp. 65–83). Maison de l'Orient Méditerranéen.

    Google Scholar 

  • Gratuze, B. (1988). Analyse non destructive d'objets en verre par des méthodes nucléaires, Application à l’étude des estampilles et poids monétaires islamiques (PhD thesis). Université d’Orléans.

    Google Scholar 

  • Gratuze, B. (2020). The blue and bluish green glass sherds, decorated with opaque white glass strands, discovered at Vetricella (Scarlino, Grosseto): Analytical study. In G. Bianchi, & R. Hodges (Eds.), The nEU-Med project: Vetricell, an Early Medieval royal property on Tuscany's Mediterranean, 28 ( pp. 77–88). All'Insegna del Giglio, Biblioteca di Archeologia Mediavale.

    Google Scholar 

  • Gratuze, B., & Barrandon, J. N. (1990). Islamic glass weights and stamps—analysis using nuclear techniques. Archaeometry, 32, 155–162.

    Article  Google Scholar 

  • Gratuze, B., Guérit, M., Simon, L., Villaverde, L., & Barbier, E. (2014). Des verres carolingiens de compositions atypiques à Bressuire et Faye-sur-Ardin (nord de la région melloise, Deux-Sèvres). Bulletin De L’association Française Pour L’archéologie Du Verre, 2014, 114–120.

    Google Scholar 

  • Henderson, J. (1995). An investigation of early Islamic glass production at Raqqa, Syria. In P. Vandiver (Ed.), Materials Issues in Art and Archaeology IV (pp. 433–444). Materials Research Society.

    Google Scholar 

  • Henderson, J. (1999). Archaeological and scientific evidence for the production of early Islamic glass in Al-Raqqa. Levant, 31, 225–240.

    Article  Google Scholar 

  • Henderson, J. (2002). Tradition and experiment in first millennium AD glass production—the emergence of early Islamic glass technology in late antiquity. Accounts of Chemical Research, 35, 594–602.

    Article  Google Scholar 

  • Henderson, J. (2013). Ancient glass: An interdisciplinary exploration. Cambridge University Press.

    Google Scholar 

  • Henderson, J., McLoughlin, S. D., & McPhail, D. S. (2004). Radical changes in Islamic glass technology: Evidence for conservatism and experimentation with new glass recipes from early and middle Islamic Raqqa. Archaeometry, 46, 439–468.

    Article  Google Scholar 

  • Hirn, V., Gaultier, M., Aunay, C., Génies, C., Gerbaud, C., Husi, P., & Sarreste, F. (2017). Un habitat du haut Moyen Âge à “ Foujouin ” (Vernou-sur-Brenne, Indre-et-Loire). Revue archéologique du Centre de la France 56, 1–60. https://journals.openedition.org/racf/2493.

  • Kato, N., Nakai, I., & Shindo, Y. (2009). Change in chemical composition of early Islamic glass excavated in Raya, Sinai Peninsula, Egypt: On-site analyses using a portable Xray fluorescence spectrometer. Journal of Archaeological Science, 36, 1698–1707.

    Article  Google Scholar 

  • Krueger, I. (2014). Islamic lead glass and Mīnā. Journal of Glass Studies, 56, 61–84.

    Google Scholar 

  • Matson, F. R. (1948). The manufacture of eighth-century Egyptian glass weights and stamps. In George C. M. (Ed.), Early arabic glass weights and stamps numismatic notes and monographs (Vol. 3, pp. 31–69). The American Numismatic Society.

    Google Scholar 

  • Mecking, O. (2013). Medieval lead glass in central Europe. Archaeometry, 55(4), 640–662.

    Article  Google Scholar 

  • Mirti, P., Pace, M., Malandrino, M., & Negro, P. M. (2009). Sasanian glass from Veh Ardašīr: New evidences by ICP-MS analysis. Journal of Archaeological Science, 36(4), 1061–1069. https://doi.org/10.1016/j.jas.2008.12.008

    Article  Google Scholar 

  • Mirti, P., Pace, M., Negro, P. M., & Aceto, M. (2008). ICP–MS analysis of glass fragments of Parthian and Sasanian Epoch from Seleucia and Veh Ardašīr (Central Iraq). Archaeometry, 50(3), 429–450.

    Article  Google Scholar 

  • Morton, A. H. (1985). A catalogue of early islamic glass stamps in the British Museum. Published for the Trustees of the British Museum by British Museum Publications.

    Google Scholar 

  • Noujaim-Le Garrec, S. (2004). Estampilles, dénéraux, poids forts et autres disques en verre. Réunion des musées nationaux.

    Google Scholar 

  • Ollivier, E. (2019). Poids et mesures de l'Egypte musulmane: Poids et estampilles en verre de la Bibliothèque nationale et universitaire de Strasbourg. Collège de France.

    Google Scholar 

  • Pactat, I., Gratuze, B., & Derbois, M. (2015). Un atelier de verrier carolingien à Méru, “ZAC Nouvelle France” (Oise). Bulletin De L’association Française Pour L’archéologie Du Verre, 2015, 73–78.

    Google Scholar 

  • Pactat, I., Guérit, M., Simon, L., Gratuze, B., Raux, S., & Aunay, C. (2017). Evolution of glass recipes during the Early Middle Ages in France: Analytical evidence of multiple solutions adapted to local contexts. In S. Wolf, & A. de Pury-Gysel (Eds.), Annales du 20e congrès de L’Association Internationale pour l’Histoire du Verre, Fribourg / Romont 7–11 septembre 2015 (pp. 334–340).

    Google Scholar 

  • Pactat, I., Gratuze, B., & Hilberg, V. (2020). La fabrication des verres à décor rapport à l’époque carolingienne: matières premières et colorants, une histoire commune ?,. In Y. Henigfeld, P. Husi, & F. Ravoire (Eds.), L’objet au Moyen Âge et à l’époque modern: fabriquer, échanger, consommer et recycler. (Actes du XIe congrès international de la Société d’Archéologie Médiévale, Moderne et Contemporaine (Bayeux, 28–30 mai 2015) Collection Publications du CRAHAM, (pp. 73–84). Presses universitaires de Caen.

    Google Scholar 

  • Phelps, M. (2018). Glass supply and trade in early Islamic Ramla: An investigation of the plant ash glass. In D. Rosenow, M. Phelps, A. Meek, & I. C. Freestone (Eds.), Things that travelled: Mediterranean glass in the first millennium CE (pp. 236–282). UCL Press.

    Chapter  Google Scholar 

  • Phelps, M., Freestone, I. C., Gorin-Rosen, Y., & Gratuze, B. (2016). Natron glass production and supply in the late antique and early medieval Near East: The effect of the byzantine—Islamic transition. Journal of Archaeological Science, 75, 57–71.

    Article  Google Scholar 

  • Picon, M., Thirion-Merle, V., & Vichy, M. (2008). Les verres au natron et les verres aux cendres du Wadi Natrun Egypte. Bulletin De L’association Française Pour L’archéologie Du Verre, 22, 36–41.

    Google Scholar 

  • Picon, M., & Vichy, M. (2003). D'Orient en Occident: l'origine du verre à l'époque romaine et durant le haute Moyen Age. In D. Foy, & M. D. Nenna (Eds.), Échanges et commerce du verre dans le monde antique: actes du colloque de l'Association française pour l'archéologie du verre, Aix-en-Provence et Marseille, 7–9 juin 2001 (pp. 17–31).

    Google Scholar 

  • Pulak, C. (2008). The Uluburun shipwreck and late bronze Age trade. In J. Aruz, K. Benzel, & J. M. Evans (Eds.), Beyond Babylon: Art, Trade, and Diplomacy in the Second Millennium B.C., the Metropolitan Museum of Art Exhibition Catalog (pp. 3999–4005). Yale University Press.

    Google Scholar 

  • Sayre, E. V. (1965). Summary of the brookhaven program of analysis of ancient glass In Application of Science in Examinations of Works of Art, Proceedings of the seminar held at the Boston Museum of Fine Arts, Boston, Massachusetts, September 7- 16, 1965 (pp. 145–154). The Museum of Fine Arts.

    Google Scholar 

  • Sayre, E. V., & Smith, R. W. (1974). Analytical studies of ancient Egyptian glass. In A. Bishay (Ed.), Recent advances in science and technology of materials (pp. 47–70). Plenum Press.

    Chapter  Google Scholar 

  • Scapova, J. L. (1992). Un lissoir de Novgorod, réflexions sur la verrerie médiévale. Acta Archeologica, 62, 231–243.

    Google Scholar 

  • Schibille, N., Gratuze, B., Ollivier, E., & Blondeau, E. (2019). Chronology of early Islamic glass compositions from Egypt. Journal of Archaeological Science, 104, 10–18.

    Article  Google Scholar 

  • Schibille, N., De Juan Ares, J., Casal García, M. T., & Guerrot, C. C. (2020). Ex novo development of lead glassmaking in early Umayyad Spain. Proceedings of the National Academy of Sciences of the United States of America, 117(28), 16243–16249.

    Article  Google Scholar 

  • Schibille, N., Meek, A., Tobias, B., Entwistle, C., Avisseau-Broustet, M., Da Mota, H., & Gratuze, B. (2016). Comprehensive chemical characterisation of byzantine glass weights. PLoS ONE, 11, e0168289. https://doi.org/10.1371/journal.pone.0168289

    Article  Google Scholar 

  • Schibille, N., Meek, A., Wypyski, M. T., Kröger, J., Rosser-Owen, M., & Haddon, R. W. (2018). The glass walls of Samarra (Iraq): Ninth-century Abbasid glass production and imports. PLoS ONE, 13, 0201749. https://doi.org/10.1371/journal.pone.0201749

    Article  Google Scholar 

  • Schibille, N., Sterrett-Krause, A., & Freestone, I. C. (2017). Glass groups, glass supply and recycling in Late Roman Carthage. Archaeological and Anthropological Sciences, 9, 1223–1241.

    Article  Google Scholar 

  • Shortland, A., Schachner, L., Freestone, I. C., & Tite, M. (2006). Natron as a flux in the early vitreous materials industry: Sources, beginnings and reasons for decline. Journal of Archaeological Science, 33, 521–530.

    Article  Google Scholar 

  • Shortland, A. J., Rogers, N., & Eremin, K. (2007). Trace element discriminants between Egyptian and Mesopotamian late bronze age glasses. Journal of Archaeological Science, 34, 781–789.

    Article  Google Scholar 

  • Siemianowska, S., Pankiewicz, A., & Sadowski, K. (2019). On technology and production techniques of early medieval glass rings from Silesia. Archaeometry, 61(3), 614–646.

    Article  Google Scholar 

  • Silvestri, A., Molin, G., & Salviulo, G. (2005). Roman and medieval glass from the Italian area: Bulk characterization and relationships with production technologies. Archaeometry, 47, 797–816.

    Article  Google Scholar 

  • Simon-Hiernard, D., & Gratuze, B. (2011). Le vase de Saint-Savin en Poitou et les verres médiévaux bleu-cobalt à décors blancs. Bulletin De L’association Française Pour L’archéologie Du Verre, 2011, 69–73.

    Google Scholar 

  • Sode, T., & Gratuze, B. (2015). Franske forbindelser—sømglattere fra vikingetidens Ribe. In By, Marsk Og Geest, (Vol. 27, pp. 59–70). Sydvestjyske Museer.

    Google Scholar 

  • Sterpenich, J., & Libourel, G. (1997). Les vitraux médiévaux: Caractérisation physico-chimique de l’altération. Techne, 6, 70–84.

    Google Scholar 

  • Téreygeol, F., Gratuze, B., Foy, D. & Lancelot, J. (2004). Les scories de plomb argentifère: une source d'innovation technique carolingienne? In N. Coquery (Ed.), Artisans, industrie, nouvelles révolutions du Moyen Age à nos jours, Cahiers d'histoire et de philosophie des sciences, (Vol. 52, pp. 31–40).

    Google Scholar 

  • Tite, M., Shortland, A., Maniatis, Y., Kavoussanaki, D., & Harris, S. (2006). The composition of the soda—rich and mixed alkali plant ashes used in the production of glass. Journal of Archaeological Science, 33(9), 1284–1292.

    Article  Google Scholar 

  • Van Wersch, L., Loisel, C., Mathis, F., Strivay, D., & Bully, S. (2016). Analyses of early medieval stained glass from the monastery of Baume-les-Messieurs (Jura, France). Archaeometry, 58(6), 930–946.

    Article  Google Scholar 

  • Velde, B. (2009). Composition des vitraux en France du VIIIe au XIIe siècle: de la soude à la potasse. In S. Balcon-Berry, F. Perrot, & C. Sapin (Eds.), Vitrail, verre et archéologie entre le Ve et le XIIe siècle. Actes de la table ronde tenue à Auxerre les 15–16 juin 2006 (pp. 21–26). CTHS.

    Google Scholar 

  • Verità, M. (2013). Venetian soda glass. In K. H. A. Janssens (Ed.), Modern methods for analysing archaeological and historical glass (pp. 516–536). Wiley.

    Google Scholar 

  • Vrielynck, O., & Mathis, F. (2012). Les lissoirs en verre médiévaux: Analyse de quelques exemplaires découverts en Wallonie. Annales De La Société Archéologique De Namur, 86, 119–143.

    Google Scholar 

  • Wedepohl, K. H., & Baumann, A. (1997). Isotope composition of medieval lead glasses reflecting early silver production in Central Europe. Mineralium Deposita, 32, 292–295.

    Article  Google Scholar 

  • Wedepohl, K. H., & Simon, K. (2010). The chemical composition of medieval wood ash glass from Central Europe. Chemie Der Erde, 70, 89–97.

    Article  Google Scholar 

  • Wedepohl, K. H., Winkelmann, W., & Hartmann, G. (1997). Glasfunde aus der karolingischen Pfalz in Paderborn und die frühe Holzasche-Glasherstellung. In Ausgrabungen und Funde in Westfalen-Lippe (Vol. 9(A), pp. 41–53).

    Google Scholar 

  • Whitehouse, D. (2002). The transition from natron to plant ash in the levant. Journal of Glass Studies, 44, 193–196.

    Google Scholar 

  • Wypyski, M. T. (2015). Chemical analysis of early Islamic glass from Nishapur. Journal of Glass Studies, 57, 121–136.

    Google Scholar 

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Funding

Some of the data presented here are part of a project funded by the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (grant agreement No. 647315 to NS). The funding organization had no influence in the study design, data collection and analysis, decision to publish or preparation of the manuscript.

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Gratuze, B., Schibille, N., Pactat, I. (2021). Glass in the Middle East and Western Europe at the End of the First Millennium CE, Transition from Natron to Plant Ash Soda or Forest Glasses. In: Kanungo, A.K., Dussubieux, L. (eds) Ancient Glass of South Asia. Springer, Singapore. https://doi.org/10.1007/978-981-16-3656-1_2

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