Abstract
Intermetallic phases constitute a unique class of materials composed of two or more metals, sometimes non-metallic elements also, in definite proportions. They have well-defined stoichiometry, crystal structure and can exhibit metallic, covalent or ionic bonding. High mechanical strength, resistance to corrosion and adequate ductility of intermetallic phases make them widely applicable as structural materials for automobiles, aerospace, telecommunication, electronics, transport and heavy industries. There is a huge demand for alloys having high mechanical strength and corrosion resistance at elevated temperatures for energy applications. The physical properties and mechanical strength of alloys are governed by the presence of intermetallic phases in these alloys. The formation of these phases in a given alloy system on other hands is governed by the nature of synthesis of alloys, level of impurity phases present and the heat treatment process. Experimental conditions, like, level of vacuum, annealing temperature, rate of cooling and thermal shock are among the factors that play vital role in tailoring their properties. In the present chapter, types of intermetallic phases, various experimental procedures for their synthesis, processing and their properties will be discussed. Details of synthesis processes including heat treatment in different types of furnaces, mechanical alloying, electrochemical processes, chemical reduction methods will be discussed. Influence of annealing conditions on material properties will also be presented. The knowledge of phase diagram, structure and thermodynamic parameters in fixing the material properties will be brought out. The chapter will also include some of the technologically important intermetallic phases, their method of synthesis, properties and applications.
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References
Mehrer H (2007) Diffusion in solids: fundamentals, methods, materials, diffusion- controlled processes. In: Springer series in solid-state sciences, vol 155. Springer, Berlin, Heidelberg, New York
Westbrook JH (1993) Structural intermetallics. In: Dariola R, Lewendowski JJ, Liu CT, Martin PL, Miracle DB, Nathal MV (eds) TMS, Warrendale, PA, pp 87–96
Sauthoff G (1995) Intermetallics. Wiley – VCH Verlag GmbH, Weinheim, Germany
Horton JA, Liu CT, George EP (1995) Shape memory properties of a two-phase NiAl plus Fe alloy. Mat Sci Eng A,192–193:873–880
Pike LM, Anderson IM, Liu CT, Chang YA (2002) Site occupancies, point defect concentrations, and solid solution hardening in B2 (Ni, Fe)Al. Acta Mater 50:3859–3879
He YH, Jiang Y, Xu NP, Zou J, Huang BY, Liu CT, Liaw PK (2007) Fabrication of Ti–Al micro/nanometer-sized porous alloys through the Kirkendall effect. Adv Mater 19:2102–2106
Cahn RW (1996) Multiphase intermetallics. In: Cahn RW, Evans AG, McLean M (eds) High-temperature structural materials. Springer, Dordrecht, pp 79–91
Adeva P (1999) Revista de la Asociacion Espanola de Cientificos 1:1
Kurnakov SFZNS, Zasedatelev M (1916) J Inst Met 15:305
Aoki K, Izumi O (1979) Flow and fracture behaviour of Ni3(Al·Ti) single crystals tested in tension. J Mater Sci 14:1800–1806
He Y, Liu Y, Huang B, Qu X, Lei C (1994) Grain refiner for TiAl intermetallic compounds. J Mater Sci Technol 10:205–208
Nieh TG, Wadsworth J, Liu CT (2011) Mechanical properties of nickel beryllides. J Mater Res 4:1347–1353
Takeyama M, Liu CT (1989) Grain-boundary contamination and ductility loss in boron-doped Ni3Al. Metall Trans A 20:2017–2023
Bewlay BP, Weimer M, Kelly T, Suzuki A, Subramanian PR (2013) The science technology, and implementation of TiAl alloys in commercial aircraft engines. MRS Proc 1516:49–58
Xiao CB, Han YF, Li SS, Song JX (2003) Development of directionally solidified Ni-Al-Mo-B-Y alloy IC6A. Mater Sci Technol 19:1677–1680
Jackson AG (1991) Handbook of Crystallography: for electron microscopists and others. Spinger, New York
Li Z, Mao H, Korzhavyi PA, Selleby M (2016) Thermodynamic re-assessment of the Co–Cr system supported by first-principles calculations. Calphad 52:7
Schmid G (1999) Metal clusters in Chemistry, Braunstein P, Oro LA, Raithby PR (eds), vol 3, pp 1325
Andrews MP, O’Brien SC (1992) Gas-phase “molecular alloys” of bulk immiscible elements: iron-silver (FexAgy). J Phys Chem 96:8233–8241
Yeh JW (2006) Recent progress in high-entropy alloys. Ann Chim Sci Mat 31:633–648
Tong C-J, Chen M-R, Yeh J-W, Lin S-J, Chen S-K, Shun T-T, Chang S-Y (2005) Mechanical performance of the AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A 36:1263–1271
Herbst JF (1993) Permanent magnets. Am Sci 81:9
Li XZ (2009) Thermodynamic analysis of the simple microstructure of AlCrFeNiCu high-entropy alloy with multi-principal elements. Acta Metall Sinica 22:219–224
Tong C-J, Chen Y-L, Yeh J-W, Lin S-J, Chen S-K, Shun T-T, Tsau C-H, Chang S-Y (2005) Microstructure characterization of AlxCoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A 36:881–893
Senkov ON, Wilks GB, Miracle DB, Chuang CP, Liaw PK (2010) Refractory high-entropy alloys. Intermetallics 18:1758–1765
del Grosso MF, Bozzolo G, Mosca HO (2012) Determination of the transition to the high entropy regime for alloys of refractory elements. J Alloys Comp 534:25–31
Chun Ng, Guo S, Luan J, Shi S, Liu CT (2012) Entropy-driven phase stability and slow diffusion kinetics in an Al0.5CoCrCuFeNi high entropy alloy. Intermetallics 31:165–172
Tsai M-H (2013) Physical properties of high entropy alloys. Entropy 15:5388–5345
Cheng K-H, Lai C-H, Lin S-J, Yeh J-W (2006) Recent progress in multi-element alloy and nitride coatings sputtered from high-entropy alloy targets. Ann Chim Sci Mat 31:723–736
Chen Y Y, Duval T, Hong U T, Yeh J W, Shih H C, Wang L H, Oung J C (2007) Corrosion properties of a novel bulk Cu0.5NiAlCoCrFeSi glassy alloy in 288 °C high-purity water. Mater Lett 61:2692–2696
Singh S, Wanderka N, Murty BS, Glatzel U, Banhart J (2011) Decomposition in multi-component AlCoCrCuFeNi high-entropy alloy. Acta Mater 59:182–190
Tsai M-H, Yeh J-W, Gan J-Y (2008) Diffusion barrier properties of AlMoNbSiTaTiVZr high-entropy alloy layer between copper and silicon. Thin Solid Films 516:5527–5530
Tsai M-H, Wang C-W, Tsai C-W, Shen W-J, Yeh J-W, Gan J-Y, Wu W-W (2011) Thermal stability and performance of NbSiTaTiZr High-entropy alloy barrier for copper metallization. J Electrochem Soc 158:H1161
Tsai M-H, Yeh J-W (2014) High-entropy alloys: a critical review. Mater Res Lett 2:107–123
Williams SH (2009) PhD thesis, University of Iowa
Azami F (2005) Adv Mater Process 163:37
Lee S-H, Jung D-H, Jung S-J, Hong S-C, Lee J-J (2006) Low temperature deposition with inductively coupled plasma. Z Met 97:475–479
Yeh CL, Yeh CC (2005) Preparation of CoAl intermetallic compound by combustion synthesis in self-propagating mode. J Alloy Compd 388:241–249
Pithawalla YB, El Shall MS, Deevi SC (2000) Synthesis and characterization of nanocrystalline iron aluminide particles. Intermetallics 8:1225–1231
Rajan S, Shukla R, Kumar A, Vyas A, Brajpuriya R (2014) Structural and magnetic evolution of ball milled nanocrystalline Fe-50 at.% Al alloy. Int J Mater Res 106:114–126
Khan RBS, Vyas A, Kumar A (2015) Int J Sci Res 4:1243
Suryanarayana C (2005) Mechanical alloying and milling. Adv Mater 17:2893–2894
Suryanarayana C (2001) Mechanical alloying and milling. Prog Mater Sci 46:1–184
Suryanarayana C (1996) Recent advances in the synthesis of alloy phases by mechanical alloying/milling. Met Mater 2:195–209
Simhadri D (2003) Determination of phase fraction, lattice parameters and crystallite size in mechanically alloyed Fe-Ni powders. University of New Orleans Theses and Dissertations. 56
Azzaza MBS, Aliofkhazraci M (eds) (2016) Hand book of mechanical nanostructuring, 1st edn. Wiley-VCH Verlag GmbH & Co, KGaA
Chin ZH, Perng TP (1996) Amorphization of Ni-Si-C ternary alloy powder by mechanical alloying. Mater Sci Forum 235–238:121–126
Maziarz W, Dutkiewicz J, Senderski J (2004) Processing of nanocrystalline FeAlX (X = Ni, Mn) intermetallics using a mechanical alloying and hot pressing techniques. J Mater Sci 39:5425–5429
Chen D, Chen J, Yan H, Chen Z (2007) Synthesis of binary and ternary intermetallic powders via a novel reaction ball milling technique. Mater Sci Eng A 444:1–5
Chen D, Chen Z, Cai J, Chen Z (2008) Preparation of W-Al intermetallic compound powders by a mechanochemical approach. J Alloys Compd 461:L23–L25
Chen D, Chen G, Ni S, Chen G, Yan H, Chen Z (2008) Phase formation regularities of ultrafine TiAl, NiAl and FeAl intermetallic compound powders during solid–liquid reaction milling. J Alloys Compd 457:292–295
Bakker H, Zhou GF, Yang H (1995) Mechanically driven disorder and phase transformations in alloys. Prog Mater Sci 39:159–241
Negri D, Yavari AR, Deriu A (1999) Deformation induced transformations and grain boundary thickness in nanocrystalline B2 FeAl. Acta Mater 47:4545–4554
Yavari AR (1997) Ann Chim Sci Mater 22
Yavari AR (1993) Reordering kinetics and magnetic properties of mechanically disordered nanocrystalline Ll2-type Ni3Al + Fe alloys. Acta Metall Mater 41:1391–1403
Benameur T, Yavari AR (2011) Disordering and amorphization of L12-type alloys by mechanical attrition. J Mater Res 7:2971–2977
Yavari AR, Gialanella S, Benameur T, Cahn RW, Bochu B (2011) On the bcc, fcc, hcp, and amorphous polymorphs of Zr3Al. J Mater Res 8:242–244
Singh S, Pappachan AL, Gadiyar HS (1986) Electroproduction of cerium and Ce-Co alloy. J Less Common Metals 120:307–315
Singh S, Pappachan AL (1990) Electrodeposition of lanthanum metal from fused chloride bath. Bull Electrochem 6:97–100
Lantelme FDR, Cartailler T, Berghoute Y, Hamdani M (2001) Physicochemical properties of lanthanide and yttrium solutions in fused salts and alloy formation with nickel. J Electrochem Soc 148:C604
Masset P, Konings RJM, Malmbeck R, Serp J, Glatz J-P (2005) Thermochemical properties of lanthanides (Ln=La,Nd) and actinides (An=U,Np,Pu,Am) in the molten LiCl–KCl eutectic. J Nucl Mater 344:173–179
Fusselman SP (1999) Thermodynamic properties for rare earths and Americium in pyropartitioning process solvents. J Electrochem Soc 146:2573
Gao F, Wang C, Liu L, Guo J, Chang S, Chang L, Li R, Ouyang Y (2009) Electrode process of La(III) in molten LiCl-KCl. J Rare Earths 27:986–990
Vandarkuzhali S, Gogoi N, Ghosh S, Prabhakara Reddy B, Nagarajan K (2012) Electrochemical behaviour of LaCl3 at tungsten and aluminium cathodes in LiCl–KCl eutectic melt. Electrochimica Acta 59:245–255
Tang H, Pesic B (2014) Electrochemical behavior of LaCl3 and morphology of La deposit on molybdenum substrate in molten LiCl–KCl eutectic salt. Electrochim Acta 119:120–130
Castrillejo Y, Bermejo MR, Pardo R, Martı́nez AM (2002) Use of electrochemical techniques for the study of solubilization processes of cerium–oxide compounds and recovery of the metal from molten chlorides. J Electroanal Chem 522:124–140
Sahoo DK, Satpati AK, Krishnamurthy N (2015) Electrochemical properties of Ce(iii) in an equimolar mixture of LiCl–KCl and NaCl–KCl molten salts. RSC Adv 5:33163–33170
Bavbande DV, Mishra R, Juneja JM (2004) Studies on the kinetics of synthesis of TiC by calciothermic reduction of TiO2 in presence of carbon. J Thermal Anal Calorimetry 78:775–780
Ahmed HM, Viswanathan NN, Seetharaman S (2016) Gas-condensed phase reactions – a novel route to synthesize slloys and intermetallics involving refractory metals. Mater Today Proc 3(9):2951–2961
Gleiter H (1989) Nanocrystalline materials. Prog Mater Sci 33:223–315
Dingreville R, Qu J, Mohammed C (2005) Surface free energy and its effect on the elastic behavior of nano-sized particles, wires and films. J Mech Phys Solids 53:1827–1854
Ningthoujam RS, Sudhakar N, Rajeev KP, Gajbhiye NS (2002) Electrical resistivity study of La, B doped nanocrystalline superconducting vanadium nitride. J Appl Phys 91:6051–6056
Sambles JR, Blackman M (1971) An electron microscope study of evaporating gold particles: the Kelvin equation for liquid gold and the lowering of the melting point of solid gold particles. Proc Roy Soc London. A. Math Phys Sci 324:339–351
Goldstein AN, Echer CM, Alivisatos AP (1992) Melting in semiconductor nanocrystals. Science 256:1425
Sheng HW, Lu K, Ma E (1998) Melting of embedded Pb nanoparticles monitored using high-temperature in situ XRD. Nanostruc Mater 10:865–873
Peters KF, Cohen JB, Chung Y-W (1998) Melting of Pb nanocrystals. Phys Rev B 57:13430–13438
Cleveland CL, Luedtke WD, Landman U (1999) Melting of gold clusters. Phys Rev B 60:5065–5077
Pawlow P (1909) Ober die Abhängigkeit des Schmelzpunktes von der Oberflächenenergie eines festen Körpers (Zusatz.). Z Phys Chem 65:545–548
Buffat P, Borel JP (1976) Size effect on the melting temperature of gold particles. Phys Rev A 13:2287–2298
Borel JP (1981) Thermodynamical size effect and the structure of metallic clusters. Surf Sci 106:1–9
Dick K, Dhanasekaran T, Zhang Z, Meisel D (2002) Size-dependent melting of silica-encapsulated gold nanoparticles. J Am Chem Soc 124:2312–2317
Du YW, Xu MX, Wu J, Shi YB, Lu HX, Xue RH (1991) Magnetic properties of ultrafine nickel particles. J Appl Phys 70:5903–5905
Zhang D, Klabunde KJ, Sorensen CM, Hadjipanayis GC (1998) Magnetization temperature dependence in iron nanoparticles. Phys Rev B 58:14167–14170
Shir F, Yanik L, Bennett LH, Della Torre E, Shull RD (2003) Room temperature active regenerative magnetic refrigeration: magnetic nanocomposites. J Appl Phys 93:8295–8297
Castillo JD, Rodríguez VD, Yanes AC, Méndez-Ramos J, Torres ME (2005) Luminescent properties of transparent nanostructured Eu3+doped SnO2–SiO2 glass-ceramics prepared by the sol–gel method. Nanotechnology 16:S300–S303
Yanes AC, Del Castillo J, Torres M, Peraza J, Rodríguez VD, Méndez-Ramos J (2004) Nanocrystal-size selective spectroscopy in SnO2:Eu3+ semiconductor quantum dots. Appl Phys Lett 85:2343–2345
Yang R, Huang J, Zhao W, Lai W, Zhang X, Zheng J, Li X (2010) Bubble assisted synthesis of Sn–Sb–Cu alloy hollow nanostructures and their improved lithium storage properties. J Power Sources 195:6811–6816
Mishra R, Zemanova A, Kroupa A, Flandorfer H, Ipser H (2012) Synthesis and characterization of Sn-rich Ni–Sb–Sn nanosolders. J Alloys Compounds 513:224–229
Gajbhiye NS, Sharma S, Ningthoujam RS (2008) Synthesis of self-assembled monodisperse 3 nm FePd nanoparticles: phase transition, magnetic study, and surface effect. J Appl Phys 104:123906
Holmberg K (2004) Surfactant-templated nanomaterials synthesis. J Colloid Interf Sci 274:355–364
Holmberg K, Jönsson B, Kronberg B, Lindaman B (2003) Surfactants and polymers in aqueous solutions, 2nd edn. Wiley, Chichester
Sanchez-Dominguez M, Koleilat H, Boutonnet M, Solans C (2011) Synthesis of Pt nanoparticles in oil-in-water microemulsions: phase behavior and effect of formulation parameters on nanoparticle characteristics. J Dispersion Sci Technol 32:1765–1770
US EPA (2002) Health and environmental effects profile for hydrazine and hydrazine sulfate. report no. EPA/600/X-84/332 (NTIS PB88161963), U.S. Environmental Protection Agency: Washington, D.C. (Accessed April 15, 2018)
Ström L, Ström H, Carlsson P-A, Skoglundh M, Härelind H (2018) Catalytically active Pd–Ag alloy nanoparticles synthesized in microemulsion template. Langmuir 34:9754–9761
Nandini P, Akash K, Rohit G, Vipul S, Palani IA (2017) Investigations on the influence of liquid-assisted laser ablation of NiTi rotating target to improve the formation efficiency of spherical alloyed NiTi nanoparticles. J Mater Eng Perform 26:4707–4717
Chen Q, Song H, Zhang F, Zhang H, Yu Y, Chen Z, Wei R, Dai Y, Qiu J (2017) A strategy for fabrication of controllable 3D pattern containing clusters and nanoparticles inside a solid material. Nanoscale 9:9083–9088
Fujita Y, Aubert R, Walke P, Yuan H, Kenens B, Inose T, Steuwe C, Toyouchi S, Fortuni B, Chamtouri M, Janssen KPF, De Feyter S, Roeffaers MBJ, Uji-i H (2017) Highly controllable direct femtosecond laser writing of gold nanostructures on titanium dioxide surfaces. Nanoscale 9:13025–13033
Sarker MSI, Nakamura TZ, Herbani Y, Sato S (2013) Fabrication of Rh based solid-solution bimetallic alloy nanoparticles with fully-tunable composition through femtosecond laser irradiation in aqueous solution. Appl Phys A 110:145–152
Assis M, Cordoncillo E, Torres-Mendieta R, Beltrán-Mir H, Mínguez-Vega G, Oliveira R, Leite ER, Foggi CC, Vergani CE, Longo E, Andrés J (2018) Towards the scale-up of the formation of nanoparticles on α-Ag2WO4 with bactericidal properties by femtosecond laser irradiation. Sci Reports 8:1884
Machado TR, Macedo NG, Assis M, Doñate-Buendia C, Mínguez-Vega G, Teixeira MM, Foggi CC, Vergani CE, Beltrán-Mir H, Andrés J, Cordoncillo E, Longo E (2018) From complex inorganic oxides to Ag–Bi nanoalloy: synthesis by femtosecond laser irradiation. ACS Omega 3:9880–9887
Bönnemann H, Richards RM (2001) Nanoscopic metal particles—synthetic methods and potential applications. Eur J Inorg Chem 2455–2480
Braunstein JRP (1999) Metal clusters in Chemistry, Braunstein P, Oro LA, Raithby PR (eds), Wiley-VCH: Weinheim, vol 2, p 616
Esumi K, Tano T, Torigoe K, Meguro K (1990) Preparation and characterization of bimetallic palladium-copper colloids by thermal decomposition of their acetate compounds in organic solvents. Chem Mater 2:564–567
Bradley JS, Via GH, Bonneviot L, Hill EW (1996) Infrared and EXAFS study of compositional effects in nanoscale colloidal palladium−copper alloys. Chem Mater 8:1895–1903
Thomas JM, Johnson BFG, Raja R, Sankar G, Midgley PA (2003) High-performance nanocatalysts for single-step hydrogenations. Acc Chem Res 36:20–30
Kolay S, Kumar M, Wadawale A, Das D, Jain VK (2014) Cyclopalladation of telluro ether ligands: synthesis, reactivity and structural characterization. Dalton Trans 43:16056–16065
Mann S (2001) Biomineralization: principles and concepts. In: Bioinorganic materials Chemistry. Oxford University Press, Oxford
Mann S (1996) Biomimetic materials Chemistry. VCH, New York
Brayner R, Coradin T, Fiévet-Vincent F, Livage J, Fiévet F (2005) Algal polysaccharide capsule-templated growth of magnetic nanoparticles. New J Chem 29:681–685
Srivastava S, Samanta B, Arumugam P, Han G, Rotello VM (2007) DNA-mediated assembly of iron platinum (FePt) nanoparticles. J Mater Chem 17:52–55
Lloyd JR, Lovley DR (2001) Microbial detoxification of metals and radionuclides. Current Opinion in Biotechnol 12:248–253
Macaskie LE, Baxter-Plant VS, Creamer NJ, Humphries AC, Mikheenko IP, Mikheenko PM, Penfold DW, Yong P (2005) Applications of bacterial hydrogenases in waste decontamination, manufacture of novel bionanocatalysts and in sustainable energy. Biochem Soc Trans 33:76–79
Remita S, Mostafavi M, Delcourt MO (1996) Bimetallic Ag-Pt and Au-Pt aggregates synthesized by radiolysis. Radiat Phys Chem 47:275–279
Belloni MMJ, Remita H, Marignier J-L, Delcourt M-O (1998) Radiation-induced synthesis of mono- and multi-metallic clusters and nanocolloids. New J Chem 22:1239–1255
Belloni MMJ (1999) Metal clusters in Chemistry, Braunstein P, Oro LA, Raithby PR (eds) vol 2. Wiley-VCH, Weinheim, p 1213
Treguer M, de Cointet C, Remita H, Khatouri J, Mostafavi M, Amblard J, Belloni J, de Keyzer R (1998) Dose rate effects on radiolytic synthesis of gold−silver bimetallic clusters in solution. J Phys Chem B 102:4310–4321
Doudna CM, Bertino MF, Tokuhiro AT (2002) Structural investigation of Ag−Pd clusters synthesized with the radiolysis method. Langmuir 18:2434–2435
Doudna CM, Bertino MF, Blum FD, Tokuhiro AT, Lahiri-Dey D, Chattopadhyay S, Terry J (2003) Radiolytic synthesis of bimetallic Ag−Pt nanoparticles with a high aspect ratio. J Phys Chem B 107:2966–2970
Jiang Y, He YH, Xu NP, Zou J, Huang BY, Liu CT (2008) Effects of the Al content on pore structures of porous Ti–Al alloys. Intermetallics 16:327–332
Jiang Y, Deng C, He Y, Zhao Y, Xu N, Zou J, Huang B, Liu CT (2009) Reactive synthesis of microporous titanium-aluminide membranes. Mater Lett 63:22–24
Liang W, Jiang Y, Hongxing D, He Y, Xu N, Zou J, Huang B, Liu CT (2011) The corrosion behavior of porous Ni3Al intermetallic materials in strong alkali solution. Intermetallics 19:1759–1765
Dong HX, Jiang Y, He YH, Zou J, Xu NP, Huang BY, Liu CT, Liaw PK (2010) Oxidation behavior of porous NiAl prepared through reactive synthesis. Mater Chem Phys 122:417–423
Gao HY, He YH, Shen PZ, Zou J, Xu NP, Jiang Y, Huang BY, Liu CT (2011) Congenerous and heterogeneous brazing of porous FeAl intermetallics. Powder Metall 54:142–147
Liu X, Jiang Y, Zhang H, Yu L, Kang J, He Y (2015) Porous Ti3SiC2 fabricated by mixed elemental powders reactive synthesis. J Eur Ceram Soc 35:1349–1353
Wu L, He Y-H, Jiang Y, Zeng Y, Xiao Y-F, Nan B (2014) Effect of pore structures on corrosion resistance of porous Ni3Al intermetallics. Trans Nonferrous Met Soc China 24:3509–3516
Jiang Y, He YH, Huang BY, Zou J, Huang H, Xu NP, Liu CT (2011) Criterion to control self-propagation high temperature synthesis for porous Ti–Al intermetallics. Powder Metall 54:404–407
Chen MR, Jiang Y, He YH, Lin LW, Huang BY, Liu CT (2012) Pore evolution regulation in synthesis of open pore structured Ti–Al intermetallic compounds by solid diffusion. J Alloys Compd 521:12–15
Frenkel JJ (1945) Viscous flow of crystalline bodies under the action of surface tension. J Phys 9:385–391
Ristic MM, Milosević SĐ (2006) Frenkel’s theory of sintering. Sci Sinter 38:7–11
Hoge CE, Pask JA (1977) Thermodynamic and geometric considerations of solid state sintering. Ceramurg Int 3:95–99
Maulik O, Kumar V (2015) Synthesis of AlFeCuCrMgx (x=0, 0.5, 1, 1.7) alloy powders by mechanical alloying. Mater Charact 110:116–125
Kumar S, Kumar D, Maulik O, Pradhan AK, Kumar V, Patniak A (2018) Synthesis and air jet erosion study of AlXFe1.5CrMnNi0.5 (x = 0.3, 0.5) high-entropy alloys. Metall Mater Trans A 49:5607–5618
Tunes MA, Vishnyakov VM, Donnelly SE (2018) Synthesis and characterisation of high-entropy alloy thin films as candidates for coating nuclear fuel cladding alloys. Thin Solid Films 649:115–120
Li RX, Liaw PK, Zhang Y (2017) Synthesis of AlxCoCrFeNi high-entropy alloys by high-gravity combustion from oxides. Mater Sci Eng A 707:668–673
Ye X, Ma M, Cao Y, Liu W, Ye X, Gu Y (2011) The property research on high-entropy alloy AlxFeCoNiCuCr coating by laser cladding. Phys Procedia 12:303–312
Zeng C, Tian W, Liao WH, Hua L (2016) Microstructure and porosity evaluation in laser-cladding deposited Ni-based coatings. Surf Coat Technol 294:122–130
Zhang M, Zhou X, Yu X, Li J (2017) Synthesis and characterization of refractory TiZrNbWMo high-entropy alloy coating by laser cladding. Surf Coat Technol 311:321–329
Qiu X-W, Zhang Y-P, He L, Liu C-G (2013) Microstructure and corrosion resistance of AlCrFeCuCo high entropy alloy. J Alloys Compd 549:195–199
Basuki EA, Prajitno DH, Muhammad F (2017) Alloys developed for high temperature applications. AIP Conf Proc 1805:020003-1–020003-15
Mouritz AP (2012) Superalloys for gas turbine engines. In: Mouritz AP (ed) Introduction to aerospace materials. Woodhead Publishing, pp 251–267
Mousavi T, Hong Z, Morrison A, London A, Grant P S, Grovenor, Speller S C (2017) A new approach to fabricate superconducting NbTi alloys. Supercond Sci Technol 30:09001
Narushima T., Ueda K., Alfirano (2015) Co-Cr Alloys as Effective Metallic Biomaterials. In: Niinomi M., Narushima T., Nakai M. (eds) Advances in Metallic Biomaterials. Springer Series in Biomaterials Science and Engineering, vol 3. Springer, Berlin, Heidelberg
Elias C.N., Lima J.H.C., Valiev R. Meyers M A (2008) Biomedical applications of titanium and its alloys. JOM 60:46–49
do Prado RF, Esteves GC, Santos ELDS, Bueno DAG, Cairo CAA, Vasconcellos LGOD (2018) In vitro and in vivo biological performance of porous Ti alloys prepared by powder metallurgy. PLoS ONE 13(5): e0196169
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Mishra, R., Dawar, R. (2021). Synthesis, Properties and Applications of Intermetallic Phases. In: Tyagi, A.K., Ningthoujam, R.S. (eds) Handbook on Synthesis Strategies for Advanced Materials. Indian Institute of Metals Series. Springer, Singapore. https://doi.org/10.1007/978-981-16-1892-5_15
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