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The Comprehensive Study of the Connate Water Chemical Composition Effect on Oil Recovery in Carbonate Rocks

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Proceedings of the International Petroleum and Petrochemical Technology Conference 2020 (IPPTC 2020)

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Abstract

Two natural cores from Middle East oilfield were used to perform core flooding experiments under reservoir conditions. Each core was run with different objectives. One core was to check salinity effect while another was to investigate the effect of potential determining ion composition (Mg2+, Ca2+, and SO42−) on oil recovery during secondary and tertiary recovery modes. Oil recovery, pressure drop and core-effluent were tracked and analyzed for each core flooding experiment. The experimental results were compared with our proposed geochemical studies which were done by introducing the reactions between rock, water, and oil, showing good consistency. Core effluent study shows the calcium concentration increased corresponding to a higher oil recovery. Supported by geochemical model studies, the lower calcium concentration in the connate water resulted in smaller oil bound on the rock surface because attraction force between rock and water became stronger. This work makes a further step towards the understanding of smart waterflooding in carbonate reservoirs.

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References

  1. Jadhunandan, P.P., Morrow, N.R.: Effect of wettability on waterflood recovery for crude-oil/brine/rock systems. SPE Reserv. Eng. (Society Pet. Eng.) (1995). https://doi.org/10.2118/22597-PA

  2. Morrow, N., Buckley, J.: Improved oil recovery by low-salinity waterflooding. J. Pet. Technol. (2011). https://doi.org/10.2118/129421-jpt

  3. Zhang, P., Austad, T.: Waterflooding in chalk: relationship between oil recovery, new wettability index, brine composition and cationic wettability modifier. In: 67th European Association of Geoscientists and Engineers, EAGE Conference and Exhibition, incorporating SPE EUROPE 2005 - Extended Abstracts (2005). https://doi.org/10.2523/94209-ms

  4. Yousef, A.A., Al-Saleh, S., Al-Kaabi, A., Al-Jawfi, M.: Laboratory investigation of novel oil recovery method for carbonate reservoirs. In: Society of Petroleum Engineers - Canadian Unconventional Resources and International Petroleum Conference 2010 (2010). https://doi.org/10.2118/137634-ms

  5. Shehata, A.M., Alotaibi, M.B., Nasr-El-Din, H.A.: Waterflooding in carbonate reservoirs: Does the salinity matter. SPE Reserv. Eval. Eng. (2014). https://doi.org/10.2118/170254-PA

  6. Xie, Q., Brady, P.V., Pooryousefy, E., Zhou, D., Liu, Y., Saeedi, A.: The low salinity effect at high temperatures. Fuel (2017). https://doi.org/10.1016/j.fuel.2017.03.088

  7. Yousef, A.A., Al-Saleh, S., Al-Jawfi, M.: The impact of the injection water chemistry on oil recovery from carbonate reservoirs. In: Society of Petroleum Engineers - SPE EOR Conference at Oil and Gas West Asia 2012, OGWA - EOR: Building Towards Sustainable Growth (2012). https://doi.org/10.2118/154077-ms

  8. Sharma, H., Mohanty, K.K.: An experimental and modeling study to investigate brine-rock interactions during low salinity water flooding in carbonates. J. Pet. Sci. Eng. (2018). https://doi.org/10.1016/j.petrol.2017.11.052

  9. Brooks, R., Corey, A.: Hydraulic properties of porous media. Hydrol. Pap. Color. State Univ. (1964)

    Google Scholar 

  10. Romanuka, J., et al.: Low salinity EOR in carbonates. In: Society of Petroleum Engineers - SPE EOR Conference at Oil and Gas West Asia 2012, OGWA - EOR: Building Towards Sustainable Growth, vol. 1, pp. 169–184 (2012). https://doi.org/10.2118/153869-ms

  11. Tang, G.Q., Morrow, N.R.: Influence of brine composition and fines migration on crude oil/brine/rock interactions and oil recovery. J. Petrol. Sci. Eng. (1999). https://doi.org/10.1016/S0920-4105(99)00034-0

  12. Zhang, P., Tweheyo, M.T., Austad, T.: Wettability alteration and improved oil recovery by spontaneous imbibition of seawater into chalk: impact of the potential determining ions Ca2+, Mg2+, and SO42−. Colloids Surf. A Physicochem. Eng. Asp. (2007). https://doi.org/10.1016/j.colsurfa.2006.12.058

  13. Chandrasekhar, S., Mohanty, K.K.: Wettability alteration with brine composition in high temperature carbonate reservoirs. In: Proceedings - SPE Annual Technical Conference and Exhibition (2013). https://doi.org/10.2118/166280-ms

  14. Alameri, W., Teklu, T.W., Graves, R.M., Kazemi, H., AlSumaiti, A.M.: Wettability alteration during low-salinity water-flooding in carbonate reservoir cores. In: Society of Petroleum Engineers - SPE Asia Pacific Oil and Gas Conference and Exhibition, APOGCE 2014 - Changing the Game: Opportunities, Challenges and Solutions (2014). https://doi.org/10.2118/171529-ms

  15. Alotaibi, M.B., Nasr-El-Din, H.A.: Electrokinetics of limestone particles and crude-oil droplets in saline solutions. SPE Reserv. Eval. Eng. (2011). https://doi.org/10.2118/151577-PA

  16. Mahani, H., Keya, A.L., Berg, S., Nasralla, R.: Electrokinetics of carbonate/brine interface in low-salinity waterflooding: effect of brine salinity, composition, rock type, and pH on ζ-potential and a surface-complexation model. SPE J. (2017). https://doi.org/10.2118/181745-pa

  17. Mahani, H., Levy Keya, A., Berg, S., Nasralla, R.: The effect of salinity, rock type and pH on the electrokinetics of carbonate-brine interface and surface complexation modeling. In: Society of Petroleum Engineers - SPE Reservoir Characterisation and Simulation Conference and Exhibition, RCSC 2015 (2015). https://doi.org/10.2118/175568-ms

  18. Zhu, G. et al.: Enhanced oil recovery by seawater flooding in Halfaya carbonate reservoir, Iraq: experiment and simulation. In: Society of Petroleum Engineers - SPE EOR Conference at Oil and Gas West Asia, OGWA 2016 (2016). https://doi.org/10.2118/179843-ms

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Correspondence to Septian Tri Nugraha .

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Nugraha, S.T., Wang, X. (2021). The Comprehensive Study of the Connate Water Chemical Composition Effect on Oil Recovery in Carbonate Rocks. In: Lin, J. (eds) Proceedings of the International Petroleum and Petrochemical Technology Conference 2020. IPPTC 2020. Springer, Singapore. https://doi.org/10.1007/978-981-16-1123-0_66

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  • DOI: https://doi.org/10.1007/978-981-16-1123-0_66

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