Skip to main content

Thermal Stability and Flame Retardancy of Epoxy/Synthetic Fiber Composites

  • Living reference work entry
  • First Online:
Handbook of Epoxy/Fiber Composites

Abstract

Epoxy is one of the most important and widely used thermosetting resins. Epoxy resins can further be reinforced with synthetic fibers to improve their performance from the aspects of stronger specific stiffness and strength, better fatigue endurance, and being more resistant to corrosion and chemicals. However, most neat epoxy-based thermosets are easily flammable. The presence of synthetic fiber reinforcements also affects the thermal decomposition process, pyrolysis kinetics, and combustion behaviors of epoxy resins. Depending on epoxy monomers and curing agents, although most of the cured epoxy resins show flame retardancy to some extent, they are still not enough to pass a stringent industrial standard flammable test, so that their more extensive applications in engineering fields are still limited. Therefore, to reduce their inherent fire risk and widen their application range, different flame retardant strategies have been developed to enhance the thermal stability and reduce the flammability of epoxy-based materials, including phosphorus-based, silicon-based, nitrogen-based, nanomaterials-based, and metal-organic framework materials, etc. For these different systems, their specific flame retardant mechanisms are introduced in this chapter, and their advantages and shortcomings are also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  • L. Ahmed, B. Zhang, R. Shen, R.J. Agnew, H. Park, Z. Cheng, M.S. Mannan, Q. Wang, J. Therm. Anal. Calorim. 132(3), 1853–1865 (2018)

    Article  CAS  Google Scholar 

  • M. Asim, M. Jawaid, N. Saba, M. Nasir, M.T.H. Sultan, in Hybrid Polymer Composite Materials, ed. by V. K. Thakur, M. K. Thakur, A. Pappu, (Elsevier, 2017), p. 1

    Google Scholar 

  • A.A. Azeez, K.Y. Rhee, S.J. Park, D. Hui, Compos. Part B Eng. 45(1), 308–320 (2013)

    Article  CAS  Google Scholar 

  • V. Babushok, W. Tsang, Combust. Flame 123(4), 488–506 (2000)

    Article  CAS  Google Scholar 

  • M. Bar, R. Alagirusamy, A. Das, Fibers Polym. 16(4), 705–717 (2015)

    Article  CAS  Google Scholar 

  • C.M. Becker, T.A. Dick, F. Wypych, H.S. Schrekker, S.C. Amico, Polym. Test. 31(6), 741–747 (2012)

    Article  CAS  Google Scholar 

  • B. Biswas, B.K. Kandola, Polym. Adv. Technol. 22(7), 1192–1204 (2011)

    Article  CAS  Google Scholar 

  • U. Braun, A.I. Balabanovich, B. Schartel, U. Knoll, J. Artner, M. Ciesielski, M. Döring, R. Perez, J.K. Sandler, V. Altstädt, Polymer 47(26), 8495–8508 (2006)

    Article  CAS  Google Scholar 

  • M.C. Celina, A.R. Dayile, A. Quintana, Polymer 54(13), 3290–3296 (2013)

    Article  CAS  Google Scholar 

  • K.C. Cheng, S.Y. Yu, W.Y. Chiu, J. Appl. Polym. Sci. 83(13), 2733–2740 (2002)

    Article  CAS  Google Scholar 

  • M. Ciesielski, B. Burk, C. Heinzmann, M. Döring, in Novel Fire Retardant Polymers and Composite Materials, ed. by D.-Y. Wang, (Elsevier, Amsterdam, 2017), p. 3

    Chapter  Google Scholar 

  • Y. Feng, C. He, Y. Wen, Y. Ye, X. Zhou, X. Xie, Y.-W. Mai, Compos. Part A Appl. Sci. Manuf. 103, 74–83 (2017)

    Article  CAS  Google Scholar 

  • A. Hartwig, D. Pütz, B. Schartel, M. Bartholmai, M. Wendschuh-Josties, Chem. Phys. 204(18), 2247–2257 (2003)

    CAS  Google Scholar 

  • R. Hicklin, R. Padda, G. Lenotte, in Fire Retardancy of Polymers: New Strategies and Mechanisms, ed. by T. R. Hull, B. K. Kandola, (Royal Society of Chemistry, Cambridge, 2008), p. 255

    Chapter  Google Scholar 

  • Y. Hou, W. Hu, Z. Gui, Y. Hu, Compos. Sci. Technol. 152, 231–242 (2017)

    Article  CAS  Google Scholar 

  • Y. Hu, X. Wang (eds.), Flame Retardant Polymeric Materials: A Handbook (CRC Press, Boca Raton, 2019)

    Google Scholar 

  • J. Hu, J. Shan, D. Wen, X. Liu, J. Zhao, Z. Tong, Polym. Degrad. Stab. 109, 218–225 (2014)

    Article  CAS  Google Scholar 

  • S. Huo, J. Wang, S. Yang, C. Li, X. Wang, H. Cai, Polym. Degrad. Stab. 159, 79–89 (2019)

    Article  CAS  Google Scholar 

  • S.-D. Jiang, G. Tang, J. Chen, Z.-Q. Huang, Y. Hu, J. Hazard. Mater. 342, 689–697 (2018)

    Article  CAS  Google Scholar 

  • E.N. Kalali, X. Wang, D.-Y. Wang, Ind. Eng. Chem. Res. 55(23), 6634–6642 (2016)

    Article  CAS  Google Scholar 

  • P.K. Kaul, A.J. Samson, G.T. Selvan, I. Enoch, P.M. Selvakumar, Appl. Clay Sci. 135, 234–243 (2017)

    Article  CAS  Google Scholar 

  • P. Kiliaris, C.D. Papaspyrides, Prog. Polym. Sci. 35(7), 902–958 (2010)

    Article  CAS  Google Scholar 

  • M. Kilinc, in Non-Halogenated Flame Retardant Handbook, ed. by A. B. Morgan, C. A. Wilkie, (Wiley, Hoboken, 2014), p. 169

    Chapter  Google Scholar 

  • C.-F. Kuan, W.-J. Chen, Y.-L. Li, C.-H. Chen, H.-C. Kuan, C.-L. Chiang, J. Phys. Chem. Solids 71(4), 539–543 (2010)

    Article  CAS  Google Scholar 

  • S.V. Levchik, in Flame Retardant Polymer Nanocomposites, ed. by A. B. Morgan, C. A. Wilkie, (Wiley, Hoboken, 2007), p. 1

    Google Scholar 

  • S.V. Levchik, in Non-Halogenated Flame Retardant Handbook, ed. by A. B. Morgan, C. A. Wilkie, (Wiley, Hoboken, 2014), p. 17

    Chapter  Google Scholar 

  • S.V. Levchik, E.D. Weil, Polym. Int. 53(12), 1901–1929 (2004)

    Article  CAS  Google Scholar 

  • A. Li, W. Xu, R. Chen, Y. Liu, W. Li, Compos. Part A Appl. Sci. Manuf. 112, 558–571 (2018)

    Article  CAS  Google Scholar 

  • Y. Liu, C.-L. Deng, J. Zhao, J.-S. Wang, L. Chen, Y.-Z. Wang, Polym. Degrad. Stab. 96(3), 363–370 (2011)

    Article  CAS  Google Scholar 

  • H. Liu, K. Xu, H. Cai, J. Su, X. Liu, Z. Fu, M. Chen, Polym. Adv. Technol. 23(1), 114–121 (2012)

    Article  CAS  Google Scholar 

  • S. Liu, V.S. Chevali, Z. Xu, D. Hui, H. Wang, Compos. Part B Eng. 136, 197–214 (2018)

    Article  CAS  Google Scholar 

  • Q. Liu, D. Wang, Z. Li, Z. Li, X. Peng, C. Liu, Y. Zhang, P. Zheng, Materials 13(9), 2145 (2020)

    Article  CAS  Google Scholar 

  • M.E. Mngomezulu, M.J. John, V. Jacobs, A.S. Luyt, Carbohydr. Polym. 111, 149–182 (2014)

    Article  CAS  Google Scholar 

  • A.B.. Morgan, Polym. Rev. 59(1), 25–54 (2019)

    Google Scholar 

  • A.B.. Morgan, J.W. Gilman, Fire Mater. 37(4), 259–279 (2013)

    Google Scholar 

  • A.P. Mouritz, A.G. Gibson, Fire Properties of Polymer Composite Materials (Springer Science & Business Media, Dordrecht, 2007)

    Google Scholar 

  • S. Pack, in Flame Retardants: Polymer Blends, Composites and Nanocomposites, ed. by P. M. Visakh, Y. Arao, (Springer International Publishing, Cham, 2015), p. 115

    Chapter  Google Scholar 

  • M. Pecora, Y. Pannier, M.-C. Lafarie-Frenot, M. Gigliotti, C. Guigon, Polym. Test. 52, 209–217 (2016)

    Article  CAS  Google Scholar 

  • A. Pegoretti, M. Traina, in Handbook of Properties of Textile and Technical Fibres, ed. by A. R. Bunsell, (Elsevier, 2018), p. 621

    Chapter  Google Scholar 

  • C.M.C. Pereira, M.S.S. Martins, in Polymer Green Flame Retardants, ed. by C. D. Papaspyrides, P. Kiliaris, (Elsevier, Amsterdam, 2014), p. 551

    Chapter  Google Scholar 

  • C.A. Pittinger, A.M. Pecquet, Environ. Sci. Pollut. Res. 25(15), 14361–14372 (2018)

    Article  CAS  Google Scholar 

  • Z. Qi, W. Zhang, X. He, R. Yang, Compos. Sci. Technol. 127, 8–19 (2016)

    Article  CAS  Google Scholar 

  • Y. Qiao, O. Das, S.N. Zhao, T.S. Sun, Q. Xu, L. Jiang, Polymers 12(11), 2739 (2020)

    Article  CAS  Google Scholar 

  • J. Qin, W. Zhang, R. Yang, Mater. Des. 178, 107834 (2019)

    Article  CAS  Google Scholar 

  • M. Rakotomalala, S. Wagner, M. Döring, Materials 3(8), 4300–4327 (2010)

    Article  CAS  Google Scholar 

  • H. Ren, J. Sun, B. Wu, Q. Zhou, Polym. Degrad. Stab. 92(6), 956–961 (2007)

    Article  CAS  Google Scholar 

  • N. Roenner, K. Hutheesing, A. Fergusson, G. Rein, Fire Saf. J. 91, 200–207 (2017)

    Article  CAS  Google Scholar 

  • N. Saba, M. Jawaid, in Hybrid Polymer Composite Materials, ed. by V. K. Thakur, M. K. Thakur, A. Pappu, (Elsevier, 2017), p. 57

    Chapter  Google Scholar 

  • K.A. Salmeia, S. Gaan, Polym. Degrad. Stab. 113, 119–134 (2015)

    Article  CAS  Google Scholar 

  • B. Schartel, Materials 3(10), 4710–4745 (2010)

    Article  CAS  Google Scholar 

  • B. Schartel, A. Weiß, H. Sturm, M. Kleemeier, A. Hartwig, C. Vogt, R. Fischer, Polym. Adv. Technol. 22(12), 1581–1592 (2011)

    Article  CAS  Google Scholar 

  • M. O. Seydibeyoglu, A. K. Mohanty, M. Misra (eds.), Fiber Technology for Fiber-Reinforced Composites (Woodhead Publishing, 2017)

    Google Scholar 

  • R. Shen, L.C. Hatanaka, L. Ahmed, R.J. Agnew, M.S. Mannan, Q. Wang, J. Therm. Anal. Calorim. 128(3), 1443–1451 (2017)

    Article  CAS  Google Scholar 

  • X.-H. Shi, Y.-J. Xu, J.-W. Long, Q. Zhao, X.-M. Ding, L. Chen, Y.-Z. Wang, Chem. Eng. J. 353, 550–558 (2018)

    Article  CAS  Google Scholar 

  • M. Shibata, T. Ohkita, Eur. Polym. J. 92, 165–173 (2017)

    Article  CAS  Google Scholar 

  • F. Sun, T. Yu, C. Hu, Y. Li, Compos. Sci. Technol. 136, 76–84 (2016)

    Article  CAS  Google Scholar 

  • M.C. Tanzi, S. Farè, G. Candiani, Foundations of Biomaterials Engineering (Academic, 2019)

    Google Scholar 

  • T.-Y. Tsai, N. Bunekar, C.-C. Huang, Y.-S. Huang, L.-C. Chen, RSC Adv. 5(116), 95649–95656 (2015)

    Article  CAS  Google Scholar 

  • P. Wang, Z. Cai, Polym. Degrad. Stab. 137, 138–150 (2017)

    Article  CAS  Google Scholar 

  • H. Wang, L. Zhang, AIP Adv. 9(12), 125110 (2019)

    Article  Google Scholar 

  • X. Wang, W. Xing, X. Feng, B. Yu, L. Song, Y. Hu, Polym. Chem. 5(4), 1145–1154 (2014)

    Article  CAS  Google Scholar 

  • B. Wang, H. Sheng, Y. Shi, W. Hu, N. Hong, W. Zeng, H. Ge, X. Yu, L. Song, Y. Hu, Polym. Degrad. Stab. 113, 96–109 (2015)

    Article  CAS  Google Scholar 

  • X. Wang, E.N. Kalali, J.-T. Wan, D.-Y. Wang, Prog. Polym. Sci. 69, 22–46 (2017)

    Article  CAS  Google Scholar 

  • X. Wang, W. Guo, L. Song, Y. Hu, Compos. Part B Eng. 179, 107487 (2019)

    Article  CAS  Google Scholar 

  • W. Xu, G. Wang, Y. Liu, R. Chen, W. Li, RSC Adv. 8(5), 2575–2585 (2018)

    Article  CAS  Google Scholar 

  • Y. Xu, Y. Yang, R. Shen, T. Parker, Y. Zhang, Z. Wang, Q. Wang, Polym. Compos. 40(12), 4530–4546 (2019)

    Article  CAS  Google Scholar 

  • Y. Xu, C. Lv, R. Shen, Z. Wang, Q. Wang, Polym. Compos. 41(9), 3778–3786 (2020)

    Article  CAS  Google Scholar 

  • Y.M. Yun, M.W. Seo, G.H. Koo, H.W. Ra, S.J. Yoon, Y.K. Kim, J.G. Lee, J.H. Kim, Fuel 137, 321–327 (2014)

    Article  CAS  Google Scholar 

  • W. Zhang, G. Camino, R. Yang, Prog. Polym. Sci. 67, 77–125 (2017)

    Article  Google Scholar 

  • J. Zhao, X. Dong, S. Huang, X. Tian, L. Song, Q. Yu, Z. Wang, Polym. Degrad. Stab. 156, 89–99 (2018)

    Article  CAS  Google Scholar 

  • X. Zhou, X. Mu, W. Cai, J. Wang, F. Chu, Z. Xu, L. Song, W. Xing, Y. Hu, A.C.S. Appl, Mater. Interfaces 11(44), 41736–41749 (2019)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Qingsheng Wang .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 Springer Nature Singapore Pte Ltd.

About this entry

Check for updates. Verify currency and authenticity via CrossMark

Cite this entry

Shen, R., Quan, Y., Wang, Q. (2022). Thermal Stability and Flame Retardancy of Epoxy/Synthetic Fiber Composites. In: Mavinkere Rangappa, S., Parameswaranpillai, J., Siengchin, S., Thomas, S. (eds) Handbook of Epoxy/Fiber Composites . Springer, Singapore. https://doi.org/10.1007/978-981-15-8141-0_11-1

Download citation

  • DOI: https://doi.org/10.1007/978-981-15-8141-0_11-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-8141-0

  • Online ISBN: 978-981-15-8141-0

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics