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Application of the Optimization Technique in Analytical and Electrochemistry for the Anticorrosive and Complexing Activity of 2,4-Dihydroxyacetophenone Benzoylhydrazone

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Mobile Radio Communications and 5G Networks

Part of the book series: Lecture Notes in Networks and Systems ((LNNS,volume 140))

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Abstract

2,4-Dihydroxyacetophenone benzoylhydrazone (DHABH) collectively has been used for the anticorrosive activity towards soft cast steel and as a complexing agent for formation of a coordination complex with tungsten (VI). The corrosion inhibition properties of the reagent are examined in acidic medium at variable concentrations and temperatures utilizing different techniques like gravimetric and electrochemical including polarization measurements and electrochemical impedance spectroscopy (EIS) and quantum chemical calculations. It has been found from the study that inhibition potency increased with increasing concentration of DHABH as indicated by weight loss measurement, polarization curves and EIS studies. However, the complexation conduct of the reagent with tungsten (VI) to form 1:3; W(VI): DHABH complex is studied spectrophotometrically. The produced method of determination has been observed to be exceedingly sensitive, selective, quick, reproducible and satisfactorily pertinent to a wide variety of technical and synthetic samples.

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Acknowledgements

Sincere thanks are due to the authorities, MMDU, Mullana; UIET, KU, Kurukshetra; and DCRUST, Murthal, for providing the required facilities.

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Authors and Affiliations

  1. Department of Chemistry, Maharishi Markandeshwar (Deemed to be University), Mullana, Ambala, Haryana, 133207, India

    Navneet Kaur & Nivedita Agnihotri

  2. Department of Applied Science, UIET, Kurukshetra University, Kurukshetra, Haryana, 136119, India

    Rajesh Agnihotri

  3. Department of Chemistry, DCRUST, Murthal, Sonepat, Haryana, India

    Sonia Nain & Rajiv Kumar

Authors
  1. Navneet Kaur
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  2. Nivedita Agnihotri
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  3. Sonia Nain
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  4. Rajiv Kumar
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  5. Rajesh Agnihotri
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Correspondence to Nivedita Agnihotri .

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Editors and Affiliations

  1. Department of Electronics and Communication Engineering, University Institute of Engineering and Technology (UIET), Kurukshetra University, Kurukshetra, Haryana, India

    Nikhil Marriwala

  2. University Institute of Engineering and Technology (UIET), Kurukshetra University, Kurukshetra, Haryana, India

    C. C. Tripathi

  3. Department of Electrical and Computer System Engineering, RMIT University, Melbourne, VIC, Australia

    Dinesh Kumar

  4. Department of Electronics and Communication Engineering, Jaypee University of Information Technology, Waknaghat, Himachal Pradesh, India

    Shruti Jain

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Kaur, N., Agnihotri, N., Nain, S., Kumar, R., Agnihotri, R. (2021). Application of the Optimization Technique in Analytical and Electrochemistry for the Anticorrosive and Complexing Activity of 2,4-Dihydroxyacetophenone Benzoylhydrazone. In: Marriwala, N., Tripathi, C.C., Kumar, D., Jain, S. (eds) Mobile Radio Communications and 5G Networks. Lecture Notes in Networks and Systems, vol 140. Springer, Singapore. https://doi.org/10.1007/978-981-15-7130-5_21

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  • DOI: https://doi.org/10.1007/978-981-15-7130-5_21

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-7129-9

  • Online ISBN: 978-981-15-7130-5

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