Abstract
Nowadays, numerous types of gas sensors are available in the market. Amongst them semiconducting gas sensors are more favourable due to its cost-effectiveness, high electron mobility, electrical conductivity, thermal, chemical, and mechanical stability. Moreover they possess better sensitivity towards various oxidizing and reducing gases. This chapter describes synthesis, physico-chemical properties, gas sensing performance and the factors influencing the sensing performance of nanostructured tungsten oxide nanocomposites. Influence of (i) noble metal loading (Ruthenium), (ii) structure-assisting agent (glycine), and (iii) graphene oxide loading (RGO) is discussed intensively. The range of reduced and oxidizing gases such as acetone, ethanol, propanol, ammonia, NOX, and H2S is scanned for better selectivity. Depending upon the type of additives used to fabricate the WO3 nanocomposites, the aforementioned gases showed variant selectivity. For example, glycine-modified WO3 showed decent selectivity towards acetone, whereas Ru and RGO loading enhanced the H2S sensing performance. The sensor developed with Ru-loaded WO3 nanocomposite showed a selective response of 83.87% for barely 1 ppm H2S. Further, the single and unique strategy of developing microporous WO3 with different morphologies spanning over nano-to-micro, using glycine as a structure-assisting agent, showed 83.87% sensing towards acetone at 10 ppm concentration. The morphological correlation with the sensitivity is described. Sensor derived from RGO-loaded WO3 nanocomposite showed a selective response of 64.2% for barely 1 ppm H2S. All the developed sensor materials are compared to their gas sensing performance and discussed.
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References
Seiyama T, Kato A (1962) A new detector for gaseous components using semiconductor thin film. Anal Chem 34:1502–1503
Taguchi N (1971) Gas detecting devices. U.S. Patent 3,631,436, 28 Dec 1971
Aswal DK, Gupta SK (2007) Science and technology of chemiresistor gas sensors. Nova Science Publishers
Victor DG, Zhou (2014) Climate change 2014, Ch. 1: Introductory chapter. Fifth assessment report of the intergovernmental panel on climate change. https://www.ipcc.ch/site/assets/uploads/2018/02/ipcc_wg3_ar5_full.pdf
IPCC AR4 SYR Appendix Glossary (PDF). Retrieved 14 Dec 2008
NASA GISS: science briefs: greenhouse gases: refining the role of carbon dioxide. www.giss.nasa.gov. Retrieved 26 Apr 2016
Karl TR, Trenberth KE (2003) Modern global climate change. Science 302(5651):1719–1723
Chansin G, Pugh D (2017) Environmental gas sensors 2017–2027: technologies, manufacturers, forecasts. Scientific report. www.idtechex.com/research/reports/environmental-gas-sensors-2017-2027-000500.asp
Zhang J, Sokolovskij R, Chen G, Zhu Y, Qi Y, Li XLW, Zhang GQ, Jiang Y-L (2019) Impact of high temperature H2 pre-treatment on Pt-AlGaN/GaN HEMT sensor for H2S detection. Sens Actuators B: Chem 280:138
Zhao Y, Song J-G, Ryu GH, Ko KY, Woo WJ, Kim Y, Kim D, Lim JH, Lee S, Lee Z, Park J, Kim H (2018) Low-temperature synthesis of 2D MoS2 on a plastic substrate for a flexible gas sensor. Nanoscale 10:9338–9345
Mehta SS, Nadargi DY, Tamboli MS, Chaudhary LS, Patil PS, Mulla IS, Suryavanshi SS (2018) Ru-loaded mesoporous WO3 microflowers for dual applications: enhanced H2S sensing and sunlight driven photocatalysis. Dalton Trans 47:16840
Mehta S, Nadargi D, Tamboli M, Patil V, Mulla I, Suryavanshi S (2019) Macroporous WO3: tunable morphology as a function of glycine concentration and its excellent acetone sensing performance. Ceram Int 45(1):409
Rajkumar C, Thirumalraj B, Chen SM, Veerakumar P, Liu SB, Appl ACS (2017) Mater Interfaces 37:31794
Mendieta-Reyes NE, Díaz-García AK, Gómez R (1990) ACS Catal. 2018:8
Wang Z, Fan X, Li C, Men G, Han D, Gu F, Appl ACS (2018) Mater Interfaces 10:3776
Cook B, Liu Q, Butler J, Smith K, Shi K, Ewing D, Casper M, Stramel A, Elliot A, Wu JZ, Appl ACS (2018) Mater Interfaces 10:873
Mehta SS, Tamboli MS, Mulla IS, Suryavanshi SS (2018) J Solid State Chem 258:256
Li S, Lin P, Zhao L, Wang C, Liu D, Liu F, Sun P, Liang X, Liu F, Yan X, Gao Y, Lu G (2018) Sens Actuators B 259:505
Berenguer AG, Celorrio V, Iniesta J, Fermin DJ, Ania CO (2016) Carbon 108:471
Mehta SS, Nadargi DY, Tamboli MS, Chaudhary LS, Patil PS, Mulla IS, Suryavanshi SS (2018) Dalton Trans 47:16840
Fujioka Y, Frantti J, Nieminen RM, Asiri AM (2013) J Phys Chem C 117:7506
Kim SJ, Choi SJ, Jang JS, Kim NH, Hakim M, Tuller HL, Kim ID (2016) ACS Nano 10:5891
Patil J, Nadargi D, Mulla IS, Suryavanshi SS (2018) Mater Lett 213:27
Chen D, Zhang H, Liu Y, Li J (2013) Energy Environ Sci 6:1362
Wang Q, Wen Z, Jeong Y, Choi J, Lee K, Li J (2006) Nanotechnology 17:3116
Wen Z, Wu W, Liu Z, Zhang H, Li J, Chen J (2013) Phys Chem Chem Phys 15:6773
Mehta SS, Nadargi DY, Tamboli MS, Mulla IS, Suryavanshi SS (2019) Ceramic Int 45(1):409
Lin S, Guo Y, Li X, Liu Y (2015) Mater Lett 152:102–104
Yin M, Yu L, Liu S (2017) J Alloy Compd 696:490–497
Hummers WS, Offeman RE (1958) J Am Chem Soc 80:1339
Lu Y, Zhang J, Wang F, Chen X, Feng Z, Li C (2018) ACS Appl Energy Mater 15:2067–2077
Haiyun Xu, Gao Jie, Li Minhan, Zhao Yuye, Zhang Ming, Zhao Tao, Wang Lianjun, Jiang Wan, Zhu Guanjia, Qian Xiaoyong, Fan Yuchi, Yang Jianping, Luo Wei (2019) Front Chem 7:266
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Nadargi, D.Y., Mulla, I.S., Suryavanshi, S.S. (2020). Tungsten Oxide Nanocomposites as High-Performance Gas Sensors: Factors Influencing the Sensor Performance. In: Thomas, S., Joshi, N., Tomer, V. (eds) Functional Nanomaterials. Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-15-4810-9_1
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