Skip to main content

Future Challenges of the Perovskite Materials

  • Chapter
  • First Online:
Revolution of Perovskite

Part of the book series: Materials Horizons: From Nature to Nanomaterials ((MHFNN))

Abstract

In order to achieve photovoltaic technologies’ commercial availability, high power conversion efficiency, low cost, large area, low toxicity, and long lifetime are crucial attributes. In recent years, perovskite materials have emerged as one of the most-studied photovoltaic materials for its high-performance and cost-effectiveness. However, the development of protocols to industrialize the perovskite technology still faces several severe challenges. In this chapter, we summarize the challenges and obstacles of perovskite material research from four aspects. For successful commercialization, the high stability and long-term lifetime is primary and essential. Second, Lead toxicity is also an important obstacle for practical application due to its threat to human health Third, for improving the fabrication repeatability, hysteresis and relevant measurement standards is discussed. Finally, the capacity to fabricate large-area and flexible modules based on recently reported state-of-the-art perovskite solar cells are also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Pathak SK, Abate A, Ruckdeschel P, Roose B, G€odel KC, Vaynzof Y, Santhala A, Watanabe S-I, Hollman DJ, Noel N, Sepe A, Wiesner U, Friend R, Snaith HJ, Steiner U (2014) Performance and stability enhancement of dye-sensitized and perovskite solar cells by Al doping of TiO2. Adv Func Mater 24:6046–6055

    Google Scholar 

  2. Pathak SK, Abate A, Leijtens T, Hollman DJ, Teuscher J, Pazos L, Docampo P, Steiner U, Snaith HJ (2014) Towards long-term photostability of solid-state dye sensitized solar cells. Adv Energy Mater 4:1301667

    Article  Google Scholar 

  3. Leijtens T, Eperon GE, Pathak S, Abate A, Lee MM, Snaith HJ (2013) Nat Commun 4:2885

    Article  Google Scholar 

  4. Pathak SK, Abate A, Ruckdeschel P, Roose B, Gödel KC, Vaynzof Y, Santhala A, Watanabe SI, Hollman DJ, Noel N, Sepe A, Wiesner U, Friend R, Snaith HJ, Steiner U (2014) Adv Funct Mater 24:6046

    Article  CAS  Google Scholar 

  5. Roose B, Gödel KC, Pathak S, Sadhanala A, Baena JPC, Wilts BD, Snaith HJ, Wiesner U, Grätzel M, Steiner U, Abate A (2016) Adv Energy Mater 6:1501868

    Article  Google Scholar 

  6. Shin SS, Yeom EJ, Yang WS, Hur S, Kim MG, Im J, Seo J, Noh JH, Seok SI (2017) Colloidally prepared La-doped BaSnO3 electrodes for efficient, photostable perovskite solar cells. Science 356:167–171

    Article  CAS  Google Scholar 

  7. Saliba M, Matsui T, Domanski K, Seo JY, Ummadisingu A, Zakeeruddin SM, Correa-Baena JP, Tress WR, Abate A, Hagfeldt A, Gratzel M (2016) Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance. Science 354:206–209

    Article  CAS  Google Scholar 

  8. Huang F, Jiang L, Pascoe AR, Yan Y, Bach U, Spiccia L, Cheng Y-B (2016) Fatigue behavior of planar CH3NH3PbI3 perovskite solar cells revealed by light on/off diurnal cycling. Nano Energy 27:509–514

    Article  CAS  Google Scholar 

  9. Anaraki EH, Kermanpur A, Steier L, Domanski K, Matsui T, Tress W, Saliba M, Abate A, Gratzel M, Hagfeldt A, Correa-Baena J-P (2016) Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide. Energy Environ Sci 9:3128–3134

    Article  CAS  Google Scholar 

  10. Hailegnaw B, Kirmayer S, Edri E, Hodes G, Cahen D (2015) Rain on methylammonium lead iodide based perovskites: possible environmental effects of perovskite solar cells. J Phys Chem Lett 6:1543–1547

    Article  CAS  Google Scholar 

  11. Shao S, Liu J, Portale G, Fang H-H, Blake GR, ten Brink GH, Koster LJA, Loi MA (2018) Adv Energy Mater 8:1702019

    Article  Google Scholar 

  12. Yang D, Lv J, Zhao X, Xu Q, Fu Y, Zhan Y, Zunger A, Zhang L (2017) Chem Mater 29:524

    Article  CAS  Google Scholar 

  13. Liao W, Zhao D, Yu Y, Grice CR, Wang C, Cimaroli AJ, Schulz P, Meng W, Zhu K, Xiong R-G, Yan Y (2016) Adv Mater 28:9333

    Article  CAS  Google Scholar 

  14. Noel NK, Stranks SD, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A-A, Sadhanala A, Eperon GE, Pathak SK, Johnston MB, Petrozza A, Hertz LM, Snaith HJ (2014) Energy Environ Sci 7:3061

    Article  CAS  Google Scholar 

  15. Sun P-P, Li QS, Yang L-N, Li Z-S (2016) Nanoscale 8:1503

    Article  CAS  Google Scholar 

  16. Stranks SD, Snaith HJ (2015) Metal-halide perovskites for photovoltaic and light-emitting devices. Nat Nanotechnol 10:391–402

    Article  CAS  Google Scholar 

  17. Heo JH, Han HJ, Kim DS, Ahn TK, Im SH (2015) Hysteresis-less inverted CH3NH3PbI3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency. Energy Environ Sci 8:1602–1608

    Google Scholar 

  18. Zhang T, Chen HN, Bai Y, Xiao S, Zhu L, Hu C, Xue QZ, Yang SH (2016) Understanding the relationship between ion migration and the anomalous hysteresis in high-efficiency perovskite solar cells: A fresh perspective from halide substitution. Nano Energy 26:620–630

    Article  CAS  Google Scholar 

  19. Frost JM, Walsh A (2016) What is moving in hybrid halide perovskite solar cells? Acc Chem Res 49:528–535

    Article  CAS  Google Scholar 

  20. Ono LK, Qi YB (2016) Surface and interface aspects of organometal halide perovskite materials and solar cells. J Phys Chem Lett 7:4764–4794

    Article  CAS  Google Scholar 

  21. Fan Z, Xiao JX, Sun K, Chen L, Hu YT, Ouyang JY, Ong KP, Zeng KY, Wang J (2015) Ferroelectricity of CH3NH3PbI3 perovskite. J Phys Chem Lett 6:1155–1161

    Article  CAS  Google Scholar 

  22. Miyano K, Yanagida M, Tripathi N, Shirai Y (2016) Hysteresis, stability, and ion migration in lead halide perovskite photovoltaics. J Phys Chem Lett 7:2240–2245

    Article  CAS  Google Scholar 

  23. Tress W, Marinova N, Moehl T, Zakeeruddin SM, Nazeeruddin MK, Grzatzel M (2015) Understanding the rate-dependent J-V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field. Energy Environ Sci 8:995–1004

    Article  CAS  Google Scholar 

  24. Leijtens T, Eperon GE, Noel NK, Habisreutinger SN, Petrozza A, Snaith HJ (2015) Stability of metal halide perovskite solar cells. Adv Energy Mater 5:1500963

    Article  Google Scholar 

  25. Ye M, Hong X, Zhang F, Liu X (2016) Recent advancements in perovskite solar cells: flexibility, stability and large scale. J Mater Chem A 4:6755

    Article  CAS  Google Scholar 

  26. Zhou Y, Cai B, Zhou B, Yao TT, Yu W, Liu SZF, Zhang W-H, Li C (2015) An up-scalable approach to CH3NH3PbI3 compact films for high-performance perovskite solar cells. Nano Energy 15:670–678

    Article  Google Scholar 

  27. Williams ST, Rajagopal A, Chueh C-C, Jen AK-Y (2016) Current challenges and prospective research for upscaling hybrid perovskite photovoltaics. J Phys Chem Lett 7:811–819

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Longwei Yin .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Fu, L., Li, B., Li, S., Yin, L. (2020). Future Challenges of the Perovskite Materials. In: Arul, N., Nithya, V. (eds) Revolution of Perovskite. Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-15-1267-4_11

Download citation

Publish with us

Policies and ethics