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Determination of Spectroscopic Parameters via Judd–Ofelt Analysis of Eu3+ Doped La2Zr2O7 Phosphor

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International Conference on Intelligent Computing and Smart Communication 2019

Part of the book series: Algorithms for Intelligent Systems ((AIS))

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Abstract

Here, LZO (La2Zr2O7) phosphor doped with europium (III) ions were synthesized by modified solid-state reaction synthesis including H3BO3 using as a flux. Structural analysis of prepared phosphor was done by X-ray diffraction analysis. The photoluminescence studies of prepared phosphor were done for various concentrations of europium (III) doping ions. It is found that PL excitation spectra cover 200–400 nm region also PL emission spectra show well-resolved peak at 595 nm range. This shows intense orange emission and allowed magnetic dipole (MD) transition (5D0 → 7F1) dominant over electric dipole (ED) transition (5D0 → 7F2). Judd–Ofelt (J–O) theory significantly explains the spectral characteristics of RE ions in solids. The J–O intensity parameters ΩJ (J = 2, 4, and 6) enable us to understand the chemical bonding and structural environment between RE ions and ligand field. Herein, J–O theory is explained for europium doped LZO phosphor in detail. CIE coordinate lies in near orange–red region and compared with commercially available phosphors.

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References

  1. D.R. Modeshia, R.I. Walton, Solvothermal synthesis of perovskites and pyrochlores: crystallisation of functional oxides under mild conditions. Chem. Soc. Rev. 39(11), 4303–4325 (2010)

    Google Scholar 

  2. R.C. Ewing, W.J. Weber, J. Lian, Nuclear waste disposal—pyrochlore (A2B2O7): nuclear waste form for the immobilization of plutonium and “minor” actinides. J. Appl. Phys. 95(11), 5949–5971 (2004)

    Google Scholar 

  3. M.A. Subramanian, G. Aravamudan, G.V. Subba Rao, Oxide pyrochlores—a review. Prog. Solid State Chem. 15(2), 55–143 (1983)

    Google Scholar 

  4. L. Kong, I. Karatchevtseva, D.J. Gregg, M.G. Blackford, R. Holmes, G. Triani, A novel chemical route to prepare La2Zr2O7 pyrochlore. J. Am. Ceram. Soc. 96(3), 935–941 (2013)

    Article  Google Scholar 

  5. X. Min, Y. Sun, L. Kong, M. Guan, M. Fang, Y. Liu, W. Xiaowen, Z. Huang, Novel pyrochlore-type La2Zr2O7: Eu3+ red phosphors: synthesis, structural, luminescence properties and theoretical calculation. Dyes Pigment. 157, 47–54 (2018)

    Article  Google Scholar 

  6. M. Mohapatra, B. Rajeswari, N. S. Hon and R. M. Kadam, Uranium luminescence in La2Zr2O7: effect of concentration and annealing temperature. Luminescence (2016)

    Google Scholar 

  7. V. Singh, G. Sivaramaiah, J.L. Rao, R.S. Kumaran, P.K. Singh, T.-S. Kim, L.K. Kim, Luminescence and EPR studies of ultraviolet light emitting La2Zr2O7:Gd3+ phosphor powder. J. Mater. Sci.: Mater. Electron. (2015)

    Google Scholar 

  8. N. Tiwari, V. Dubey, Synthesis and characterization of europium doped zirconium based phosphor for display applications. Reviews in Fluorescence (2016), pp. 155–184

    Google Scholar 

  9. Z. Qi, C. Shi, G. Zhang, Z. Han, H.H. Hung, Phys. Stat. Sol. (a) 195(2), 311–316 (2013)

    Article  Google Scholar 

  10. W.G. Lee, D.H. Lee, Y.K. Kim, J.K. Kim, J.W. Park, J. Nucl. Sci. Technol. Supplement 4, 572–574 (2008)

    Google Scholar 

  11. N. Thejo Kalyani, S.J. Dhoble, Renew. Sustain. Energy Rev. 16, 2696 (2012)

    Google Scholar 

  12. N.N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd edn. (Butterworth-Heinemann, Oxford, 1997)

    Google Scholar 

  13. A.F. Wells, Structural Inorganic Chemistry (Clarendon Press, Oxford, 1984)

    Google Scholar 

  14. J.B. Hedrick, Rare Earths In Selected U.S. Defense Applications, 40th Forum On The Geology of Industrial Minerals (2004)

    Google Scholar 

  15. J. Kido, K. Nagai, Y. Okamoto, J. Alloy. Compd. 192, 30 (1993)

    Article  Google Scholar 

  16. J. Kido, K. Nagai, Y. Okamoto, T. Skotheim, Chem. Lett. 235, 1267 (1991)

    Article  Google Scholar 

  17. X. Zhang, R. Sun, Q. Zheng, T. Kobayashi, W. Li, Appl. Phys. Lett. 71, 2596 (1997)

    Article  Google Scholar 

  18. Z. Hong, W. Li, D. Zhao, C. Liang, X. Liu, J. Peng, Synth. Met. 104, 165 (1995)

    Article  Google Scholar 

  19. Y. Lan, L. Yi, L. Zhou, Z. Tong, F. Gong, R. Wang, Phys. B: Condens. Matter 405, 3489 (2010)

    Article  Google Scholar 

  20. V. Dubey, R. Tiwari, R.K. Tamrakar, J. Kaur, S. Dutta, S. Das, H.G. Visser, S. Som, J. Lumin. 180, 169–176 (2016)

    Article  Google Scholar 

  21. V. Dubey, J. Kaur, S. Agrawal, N.S. Murthy, K.V.R. Suryanarayana, Superlattices Microstruct. 67, 156–171 (2014)

    Article  Google Scholar 

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Acknowledgements

Authors are very thankful to the Department of Science and Technology funding through WOS-A fellowship. Entitled “Synthesis and Characterization of rare earth activated zirconium based phosphors for biomedical applications” File no. (Project No. SR/WOS-A/PM-14/2018 (G)).

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Authors and Affiliations

  1. Department of Physics, Government Vishwanath Yadav Tamaskar Post Graduate Autonomous College, Durg, 491001, Chhattisgarh, India

    Neha Dubey & Jagjeet Kaur

  2. Department of Physics, BIT Raipur, Kendri, 493661, Chhattisgarh, India

    Vikas Dubey

  3. Career Point University Kota, Kota, Rajasthan, India

    Manish Kumar Mishra

Authors
  1. Neha Dubey
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  2. Jagjeet Kaur
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  3. Vikas Dubey
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  4. Manish Kumar Mishra
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Corresponding author

Correspondence to Neha Dubey .

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Editors and Affiliations

  1. Machine Intelligence Research Labs, Gwalior, India

    Geetam Singh Tomar

  2. Indian Institute of Technology Indore, Indore, Madhya Pradesh, India

    Narendra S. Chaudhari

  3. Applied Computing Graduate Program, University of Vale do Rio dos Sinos, Sao Leopoldo, Rio Grande do Sul, Brazil

    Jorge Luis V. Barbosa

  4. Department of Electronics and Communication Engineering, THDC-Institute of Hydropower Engineering and Technology, Tehri, Uttarakhand, India

    Mahesh Kumar Aghwariya

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Dubey, N., Kaur, J., Dubey, V., Mishra, M.K. (2020). Determination of Spectroscopic Parameters via Judd–Ofelt Analysis of Eu3+ Doped La2Zr2O7 Phosphor. In: Singh Tomar, G., Chaudhari, N.S., Barbosa, J.L.V., Aghwariya, M.K. (eds) International Conference on Intelligent Computing and Smart Communication 2019. Algorithms for Intelligent Systems. Springer, Singapore. https://doi.org/10.1007/978-981-15-0633-8_83

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