Skip to main content

Elemental Constitution Detection of Environmental Samples of Delhi Using XRF Spectroscopy

  • Conference paper
  • First Online:
Quantum Collisions and Confinement of Atomic and Molecular Species, and Photons

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 230))

  • 472 Accesses

Abstract

Metal toxicity has proven to be a major threat to human life as there are several health risks associated with it. Metal bio-magnification within living systems is a persisting problem. Due to anthropogenic activities, the concentration of various metals in environmental samples (plants, soil, air, water, etc.) is increasing at an alarming rate thus leading to their contamination. Investigations on determining the contamination level of environmental samples have been going on for a substantial amount of time in India as well as all over the world. Electrochemical, chemical or spectroscopic techniques have been popular for the abovementioned purpose. These methods although being easier and compatible, lag behind in sensitivity and accuracy. Thus, there is a need for a better technique which can detect contaminants in trace and ultra-trace amounts and also has multi-element detection capacity. Present work is an effort to identify contamination in different soil and plant samples collected from diverse land use sites in Delhi using X-Ray Fluorescence (XRF) spectroscopy. XRF offers the advantages of higher sensitivity (detection in the range of ppm), multi-element detection capability and easier sample preparation over other techniques. The samples were collected from two sites having different biological toxicity. Concentrations of the elements detected in the samples have been estimated from the X-ray spectra of the samples.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 119.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 159.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Arora, B.R.: Pollution potential of municipal waste water in Punjab. Indian J. Agric. Sci. 45, 80–85 (1985)

    Google Scholar 

  2. Su, C.: A review on heavy metal contamination in the soil worldwide: situation, impact and remediation techniques. Environ. Skept. Crit. 3(2), 24 (2014)

    Google Scholar 

  3. Verma, P., Ahmad, Ch.V., Gupta, R., Chakraborty, K., Sharma, T., Gupta, A., Gupta, S.: X-Ray fluorescence and detection of contamination in environmental samples: trace and ultra-trace levels. Yrly. Acad. J. 49–57 (2017). Kalindi College, University of Delhi. ISSN: 2348-9014

    Google Scholar 

  4. Beckett, K.P., Freer-Smith, P.H., Taylor, G.: Urban woodlands: their role in reducing the effects of particulate pollution. Environ. Pollut. 99(3), 347–360 (1998)

    Article  Google Scholar 

  5. Kumar, A., Scott Clark, C.: Lead loadings in household dust in Delhi, India. Indoor Air 19(5), 414–420 (2009)

    Article  Google Scholar 

  6. Rizwan, S.A., Nongkynrih, B., Gupta, S.K.: Air pollution in Delhi: its magnitude and effects on health. Indian J. Commun. Med. 38(1), 4 (2013). Official publication of Indian Association of Preventive & Social Medicine

    Google Scholar 

  7. Mittal, R., Allawadhi, K.L., Sood, B.S., Singh, N., Kumar, A., Kumar, P.: Determination of potassium and calcium in vegetables by X-Ray fluorescence spectrometry. X-Ray Spectrom. 22, 413–417 (1993)

    Article  ADS  Google Scholar 

  8. Deep, K., Mittal, R.: Macronutrient K variation in mung bean sprouts with lunar phases. Eur. Sci. J. 10(9), 295–306 (2014)

    Google Scholar 

  9. Bandhu, H.K., Puri, S., Garg, M.L., Singh, B., Shahi, J.S., Mehta, D., Swietlicki, E.S., Dhawan, D.K., Mangal, P.C.: Elemental composition and sources of air pollution in the city of Chandigarh, India, using EDXRF and PIXE techniques. Nucl. Instrum. Methods Phys. Res. Sect. B 160(1), 126–138 (2000)

    Article  ADS  Google Scholar 

  10. Alrakabi, M., Singh, G., Bhalla, A., Kumar, S., Kumar, S., Srivastava, A., Rai, B., Singh, N., Shahi, J.S., Mehta, D.: Study of uranium contamination of ground water in Punjab state in India using X-Ray fluorescence technique. J. Radioanal. Nucl. Chem. 294(2), 221–227 (2012)

    Article  Google Scholar 

  11. Singh, G., Bhalla, A., Kumar, S., Alrakabi, M., Srivastava, A., Rai, B., Singh, N., Shahi, J.S., Mehta, D.: Reply to query related to Study of uranium contamination of ground water in Punjab state in India using X-Ray fluorescence technique. J. Radioanal. Nucl. Chem. 298(1), 731–733 (2013)

    Article  Google Scholar 

  12. Deep, K., Mittal, R.: Calcium hardness analysis of water samples using EDXRF technique. J. Nucl. Phys. Mater. Sci. Radiat. Appl. 2(1), 105–113 (2014). Chitkara University

    Article  Google Scholar 

  13. Queralt, I., Ovejero, M., Carvalho, M.L., Marques, A.F., Llabrés, J.M.: Quantitative determination of essential and trace element content of medicinal plants and their infusions by XRF and ICP techniques. X-Ray Spectrom. 34(3), 213–217 (2005)

    Article  ADS  Google Scholar 

  14. Ene, A., Bosneagă, A., Georgescu, L.: Determination of heavy metals in soils using XRF technique. Rom. J. Phys. 55(7–8), 815–820 (2010)

    Google Scholar 

  15. Minguillón, M.C., Cirach, M., Hoek, G., Brunekreef, B., Tsai, M., Hoogh, K. de., Jedynska, A., Kooter, I.M., Nieuwenhuijsen, M., Querol, X.: Spatial variability of trace elements and sources for improved exposure assessment in Barcelona. Atmos. Environ. 89, 268–281 (2014)

    Article  ADS  Google Scholar 

  16. Achad, M., López, M.L., Ceppi, S., Palancar, G.G., Tirao, G., Toselli, B.M.: Assessment of fine and sub-micrometer aerosols at an urban environment of Argentina. Atmos. Environ. 92, 522–532 (2014)

    Article  ADS  Google Scholar 

  17. McCumber, A., Strevett, K.A.: A geospatial analysis of soil leads concentrations around regional Oklahoma airports. Chemosphere 167, 62–70 (2017)

    Article  ADS  Google Scholar 

  18. Gupta, S., Deep, K., Jain, L., Ansari, M.A., Mittal, V.K., Mittal, R.: X-Ray fluorescence (XRF) set-up with a low power X-Ray tube. Appl. Radiat. Isot. 68(10), 1922–1927 (2010)

    Article  Google Scholar 

  19. Bearden, J.A.: X-Ray wavelengths. Rev. Modern Phys. 39(1), 78 (1967)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

Professor Raj Mittal, Nuclear Science Laboratories, Physics Department, Punjabi University, Patiala, India is gratefully acknowledged for her constant guidance. We are also grateful to her for making the XRF facility of Nuclear Science Laboratories, Physics Department available for conducting the experiment. The authors also acknowledge the help and support of Ms. Preeti, Research Scholar, Nuclear Science Laboratories, Physics Department in performing the experiment successfully. One of the authors R. G. thanks IUAC, New Delhi, UFUP project 58324 for the scholarship, K. C. and Ch. V. A. acknowledge University of Delhi for the Ph.D. scholarship.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Ruchika Gupta or Punita Verma .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Gupta, R., Chakraborty, K., Vikar Ahmad, C., Ghosh, C., Verma, P. (2019). Elemental Constitution Detection of Environmental Samples of Delhi Using XRF Spectroscopy. In: Deshmukh, P., Krishnakumar, E., Fritzsche, S., Krishnamurthy, M., Majumder, S. (eds) Quantum Collisions and Confinement of Atomic and Molecular Species, and Photons. Springer Proceedings in Physics, vol 230. Springer, Singapore. https://doi.org/10.1007/978-981-13-9969-5_19

Download citation

  • DOI: https://doi.org/10.1007/978-981-13-9969-5_19

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-9968-8

  • Online ISBN: 978-981-13-9969-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics