Skip to main content

Relationship Between Arsenic Phases and Leaching in Excavated Mudstone After Removal of Leachable Fraction

  • Conference paper
  • First Online:
Proceedings of the 8th International Congress on Environmental Geotechnics Volume 1 (ICEG 2018)

Part of the book series: Environmental Science and Engineering ((ENVENG))

Included in the following conference series:

  • 3109 Accesses

Abstract

Huge amount of excavated rock is generated in tunnel construction for roads and railways. The excavated rock contains toxic trace metals and/or metalloids at the same level or slightly higher than background level. Our previous studies showed that in the column leaching test, the amount of arsenic leached from the excavated rock till the arsenic concentration was steadily below 0.01 mg/L was comparable with the amount of the first two arsenic fractions in the sequential extraction. In this study, the leachable arsenic fraction was removed from the excavated rock (mudstone) sample in order to obtain the excavated rock sample which artificially undergoes the leaching process. The column leaching test using the leachable-arsenic-arsenic-fraction-removed sample shows the behavior of arsenic leaching was different depending on the samples. They decreased from 66% to 31% of summed amounts of F1 and F2 arsenic fraction in the sequential extraction, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 229.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 299.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 299.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Wenzel WW, Kirchbaumer N, Prohaska T, Stingeder G, Lombi E, Adriano DC (2001) Arsenic fractionation in soils using an improved sequential extraction procedure. Anal Chim Acta 436:309–323

    Article  Google Scholar 

  2. Tabelin CB, Igarashi T, Takahashi R (2012) Mobilization and speciation of arsenic from hydrothermally altered rock in laboratory column experiments under ambient conditions. Appl Geochem 27:326–342

    Article  Google Scholar 

  3. Tamoto S, Tabelin CB, Igarashi T, Ito M, Hiroyoshi N (2015) Short and long term release mechanisms of arsenic, selenium and boron from a tunnel-excavated sedimentary rock under in situ conditions. J Contam Hydrol 175–176:60–71

    Article  Google Scholar 

  4. Tabelin CB, Hashimoto A, Igarashi T, Yoneda T (2014) Leaching of boron, arsenic and selenium from sedimentary rocks: II. pH dependence, speciation and mechanisms of release. Sci Total Environ 473–474:244–253

    Article  Google Scholar 

  5. Sharma P, Kappler A (2011) Desorption of arsenic from clay and humic acid-coated clay by dissolved phosphate and silicate. J Contam Hydrol 126:216–225

    Article  Google Scholar 

  6. Yang G, Liu Y, Song S (2015) Competitive adsorption of As(V) with co-existing ions porous hematite in aqueous solutions. J Environ Chem Eng 3:1497–1503

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shoji Suzuki .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Suzuki, S., Katoh, M. (2019). Relationship Between Arsenic Phases and Leaching in Excavated Mudstone After Removal of Leachable Fraction. In: Zhan, L., Chen, Y., Bouazza, A. (eds) Proceedings of the 8th International Congress on Environmental Geotechnics Volume 1. ICEG 2018. Environmental Science and Engineering(). Springer, Singapore. https://doi.org/10.1007/978-981-13-2221-1_75

Download citation

Publish with us

Policies and ethics