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Thermodynamic Studies of Supramolecular Systems

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Handbook of Macrocyclic Supramolecular Assembly

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Abstract

Supramolecular chemistry is highly interdisciplinary in various fields due to host-guest interactions. Since most non-covalent interactions are relatively weak, many supramolecular systems are under thermodynamic control. Traditionally, thermodynamics in understanding the factors contributing to complex stability and selectivity is important in supramolecular systems. Therefore, we focus on a summary of thermodynamics of supramolecular systems in this chapter. Firstly, we will discuss thermodynamic parameters based on various methods, in particularly ITC method. Then related thermodynamic researches on the applications of macrocyclic hosts including cyclodextrins, crown ethers, calixarenes, and cucurbiturils will be summarized. We hope this chapter could provide more thoughts or inspirations for thermodynamic analysis in supramolecular systems.

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Acknowledgments

We thank NNSFC (21432004, 21672113, 21772099, 21861132001) for financial support.

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Authors and Affiliations

  1. School of Textile Science and Engineering, State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin, People’s Republic of China

    Nan Li

  2. College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, People’s Republic of China

    Yu Liu

  3. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, People’s Republic of China

    Yu Liu

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  1. Nan Li
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  2. Yu Liu
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Correspondence to Yu Liu .

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Editors and Affiliations

  1. College of Chemistry, Nankai University College of Chemistry, Tianjin, Tianjin, China

    Yu Liu

  2. College of Chemistry, Nankai University College of Chemistry, Tianjin, Tianjin, China

    Yong Chen

  3. College of Chemistry, Nankai University College of Chemistry, Tianjin, Tianjin, China

    Heng-Yi Zhang

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Li, N., Liu, Y. (2019). Thermodynamic Studies of Supramolecular Systems. In: Liu, Y., Chen, Y., Zhang, HY. (eds) Handbook of Macrocyclic Supramolecular Assembly . Springer, Singapore. https://doi.org/10.1007/978-981-13-1744-6_46-1

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  • DOI: https://doi.org/10.1007/978-981-13-1744-6_46-1

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