Abstract
Three generations of hyperbranched polyester polyol were synthesized by the reactions from pentaerythritol (PE) and 2,2-dihydroxy-methyl-propionic acid (DMPA) by melt polycondensation technique. They were characterized by 1H NMR, 13C NMR and the results indicated that each had a high degree of branching. Then HBPE-3 was end-caped by urethane acrylate (UA) synthesized from isophorone diisocyanate and (IPDI) and hydroxyethyl methacrylate (HEMA) to obtain a novel hyperbranched polyurethane acrylate (HPUA). The structure of it was characterized by FTIR, DSC and TG techniques. The results showed low glass transition temperature (Tg) and good thermal stability. Tg of HBPE-3 was 56.13 °C, HPUA-3 was a kind of semi-crystalline material, its Tg was 35.56 °C, cold crystallization temperature (Tc) 110.92 °C and melting temperature (Tm) 134.74 °C. The introduction of a large number of unsaturated units to the end portion can provide new ideas for the development of new UV-curable materials.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Benthem RAV (2000) Novel hyperbranched resins for coating applications. Prog Org Coat 40:203–214
Yates CR, Hayes W (2004) Synthesis and applications of hyperbranched polymers. Eur Polymer J 40:1257–1281
Kou HG, Shi WF (2000) Study of photopolymerization characteristics of hyperbranched methacrylated poly(amine-ester)s. J Polymer Sci 5:554–558
Zhang LY (2011) The preparation of dendritic hyperbranched maleate resin and its application in uv-curable coating. In: Machinery, materials science and energy engineering (ICMMSEE 2015), pp 403–416
Sabani S, Onen AH, Gungor A (2012) Preparation of hyperbranched polyesterpolyol-based urethaneacrylates and applications on UV-curable wood coatings. Technol Res 9:703–716
Acknowledgements
This work was financially supported by Chinese National Natural Science Foundation of China (21404042), State Key Laboratory of Pulp and Paper Engineering Project (2016C01,2016C02), and the Science and Technology Planning Project in Guangzhou (2016070220045).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Wang, Y., Chen, G., He, M., Chen, Q. (2018). Synthesis of Novel Hyperbranched Polyurethane Acrylate Based on Pentaerythritol. In: Zhao, P., Ouyang, Y., Xu, M., Yang, L., Ren, Y. (eds) Applied Sciences in Graphic Communication and Packaging. Lecture Notes in Electrical Engineering, vol 477. Springer, Singapore. https://doi.org/10.1007/978-981-10-7629-9_82
Download citation
DOI: https://doi.org/10.1007/978-981-10-7629-9_82
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-10-7628-2
Online ISBN: 978-981-10-7629-9
eBook Packages: EngineeringEngineering (R0)