Abstract
The corrosion of steel in cementitious environments in nuclear applications has been studied extensively because (i) steel is widely used as reinforcement in the concrete used in nuclear power plants (NPPs) and (ii) cementitious materials are used as a waste encapsulant or backfill in some disposal concepts for low level and high level radioactive waste, where steel waste containers are used and steel wastes are processed. This section summarises the papers on corrosion in concrete that were given at the NUCPERF series of conferences. It first presents an overview of potential corrosion issues in NPPs and waste facilities and then describes the main corrosion mechanisms for steel in concrete (including passive corrosion, chloride–induced corrosion and carbonation). This is followed by an overview of the various aspects of modelling of corrosion of steel in concrete that were discussed during the NUCPERF meetings. The features of corrosion in concrete that need to be taken into consideration when developing new test programmes are summarised and the possible effects of concrete cracking on corrosion behaviour are discussed. Finally, some recommendations for future R&D on the subject of corrosion in concrete in nuclear applications are made.
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References
ACI: Protection of metals in concrete against corrosion, Committee Report No. ACI 222R–01, American Concrete Institute, Farmington Hills, USA (2001)
Ahmad, Z.: Principles of Corrosion Engineering and Corrosion Control. Elsevier, Amsterdam (2006)
Alexander, M., Otieno, M., Beushausen, H.: Corrosion in cracked concrete—and related issues of structural durability and service life, keynote lecture presented at International Workshop NUCPERF 2012: Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal, RILEM Event TC 226-CNM and EFC Event 351 (2012)
Andrade, C., Zuloaga, P., Martínez, I., Castillo, Á., Briz, S.: Effect of temperature on corrosion parameters and apparent activation energy measured by embedded sensors in pilot container in El Cabril repository. Corros. Eng. Sci. Technol. 46(2), 182–189 (2011)
Andrade, C., Fullea, J., Toro, L., Martinez, I., Rebolledo, N.: Reinforcement corrosion in alkaline chloride media with reduced oxygen concentrations. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Angst, U., Elsener, B., Larsen, C.K., Vennesland, Ø.: Critical chloride content in reinforced concrete—a review. Cem. Concr. Res. 39, 1122–1138 (2009)
Bataillon, C., Bouchon, F., Chainais-Hillairet, C., Desgranges, C., Hoarau, E., Martin, F., Perrin, S., Tupin, M., Talandier, J.: Corrosion modelling of iron based alloy in nuclear waste repository, Electrochim. Acta 55 15(1), 4451–4467 (2010)
Bentur, A., Diamond, S., Berke, N.S.: Steel Corrosion in Concrete: Fundamentals and Civil Engineering Practice. E & FN Spon, London (1997)
Berkeley, K.G.C., Pathmanaban, S.: Cathodic Protection of Reinforcement Steel in Concrete. Butterworths & Co, London (1990)
Bertolini, L., Pedeferri, P., Pastore, T.: Stainless steel in reinforced concrete structures. In: Gjørv, O.E., Sakai, K., Banthai, N. (eds.) Concrete under severe conditions 2—environment and loading (CONSEC’98), vol. 1, pp. 94–103. E&FN Spon, London (1998)
Bertolini, L., Elsener, B., Pedeferri, P., Polder, R.: Corrosion of Steel in Concrete: Prevention, Diagnosis, Repair. Wiley-VCH Verlag GmbH & Co., Weinheim (2004)
Brem, M., Büchler, M., Mailand, I.: Online corrosion monitoring and cathodic protection of a steel structure in concrete. In: L’Hostis, V., Gens, R., Gallé, C. (eds.) Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 335–342, ISBN: 978-2-31158-072-1 (2009)
Broomfield, J.P.: Corrosion of Steel in Concrete: Understanding, Investigation and Repair, 2nd edn. Taylor & Francis, London (2007)
Caré, S., Berthaud, Y., Ragueneau, F., L’Hostis, V., Millard, A.: Damage of the steel-concrete interface due to accelerated corrosion. In: L’Hostis, V., Gens, R., Gallé, C. (eds.) Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 61–70, ISBN: 978-2-31158-072-1 (2009)
Charles, S., Poyet, S., L’Hostis, V.: Impact of moisture parameters on the chloride induced corrosion in concrete. In: L’Hostis, V., Gens, R., Gallé, C. (eds.) Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 79–88, ISBN: 978-2-31158-072-1 (2009)
Chitty, W.-J., Berger, P., Dillmann, P., L’Hostis, V., Beranger, G.: Contribution of archaeological analogues to the comprehension of long-term corrosion of concrete reinforcements. J. Phys. IV 136, 295–304 (2006)
Clear, K.C.: Effectiveness of epoxy-coated reinforcing steel – interim report. Canadian Strategic Highway Research Program (C-SHRP), Ottawa (1992)
Dang, V.H., François, R., L’Hostis, V.: Effects of pre-cracks on both initiation and propagation of re-bar corrosion in pure carbon dioxide. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Duffó, G.S., Farina, S.B., Arva, E.A., Giordano, C.M., Lafont, C.J.: Studies concerning the durability of concrete vaults for intermediate level radioactive waste disposal: electrochemical monitoring and corrosion aspects. J. Phys. IV 136, 3–11 (2006)
Duffó, G., Arva, E.A., Schulz, F.M., Vazquez, D.R.: Corrosion behaviour of steel rebars embedded in a concrete designed for the construction of an intermediate-level radioactive waste disposal facility. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Farina, S.: Corrosion susceptibility of steel drums to be used as containers for intermediate level nuclear waste. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Farina, S.B., Schulz, F.M., Duffó, G.S.: Corrosion of steel drums containing cemented ion exchange-resins. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 53–60, ISBN: 978-2-31158-072-1 (2009)
Fennell, P.: The long-term prediction of corrosion damage in nuclear waste containers. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 245–253, ISBN: 978-2-31158-072-1 (2009)
François, R., Castel, A., Vidal, T., Vu, N.-A.: Long-term corrosion behaviour of reinforced concrete structures in chloride environment. J. Phys. IV 136, 285–293 (2006)
François, R., Castel, A., Zhang, R.: Effect of corrosion on load-bearing capacity and flexural stiffness of reinforced concrete elements. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 23–31, ISBN: 978-2-31158-072-1 (2009)
Gens, R., Bel, J., Pourbaix, A., Hélie, M., Wickham, S., Bennett, D.: Corrosion processes and the expected evolution of the BSC–1 Supercontainer design for disposal of Belgian HLW and spent fuel. J. Phys. IV 136, 13–23 (2006)
Hansson, C.M., Poursaee, A., Jaffer, S.J.: Corrosion of reinforcing bars in concrete. R&D Serial No. 3013, Portland Cement Association (PCA), Skokie, USA (2007)
Harnisch, J., Warkus, J., Raupach, M.: Modelling of reinforcement corrosion: macro cells and time dependence. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 71–78, ISBN: 978-2-31158-072-1 (2009)
Hurley, M.F., Scully, J.R.: Chloride threshold levels in clad 316L and solid 316LN stainless steel rebar. Paper presented at CORROSION 2002, Denver, 7–11 April 2002, Paper 02224 (2002)
Jung, H., Kwon, K.-J., Lee, E., Kim, D.-G., Kim, G.Y.: Effect of dissolved oxygen on corrosion properties of reinforcing steel. Corr. Eng. Sci. Technol. 46(2), 195–198 (2011)
King, F., Padovani, C.: Review of the corrosion performance of selected canister materials for disposal of UK HLW and/or spent fuel. Corros. Eng. Sci. Technol. 46(2), 82–90 (2011)
Kursten, B., Druyts, F., Macdonald, D.D., Smart, N.R., Gens, R., Wang, L., Weetjens, E., Govaerts, J.: Review of corrosion studies of metallic barrier in geological disposal conditions with respect to Belgian Supercontainer concept. Corros. Eng. Sci. Technol. 46(2), 91–97 (2011)
Kurtis, K.E., Mehta, K.A.: Critical review of deterioration of concrete due to corrosion of reinforcing steel. In: Malhotra, V.M. (ed.) Proceedings of the fourth CANMET/ACI international conference on durability of concrete, American Concrete Institute publication SP–170, pp. 535–554 (1997)
L’Hostis, V., Amblard, E., Blanc, C., Miserque, F., Paris, C., Bellot-Gurlet, L.: Passive corrosion of steel in concrete in context of nuclear waste disposal. Corros. Eng. Sci. Technol. 46(2), 177–181 (2011)
Legat, A., Česen, A., Gartner, N., Kuhar, V., Kosec, T.: Use of stainless steel reinforcement in the engineered barriers of LILW repository. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 295–303, ISBN: 978-2-31158-072-1 (2009)
Macdonald, D.D., Azizi, O., Saleh, A.: The passivity and corrosion resistance of carbon steel in simulated Boom Clay HLNW environments. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 35–44, ISBN: 978-2-31158-072-1 (2009)
Macdonald, D.D., Urquidi-Macdonald, M., Engelhardt, G.R., Azizi, O., Saleh, A., Almazooqi, A., Rosas-Camacho, O Some important issues in electrochemistry of carbon steel in simulated concrete pore water: part 1—theoretical issues. Corros. Eng. Sci. Technol. 46(2), 98–103 (2011a)
Macdonald, D.D., Saleh, A., Lee, S.K., Azizi, O., Rosas-Camacho, O., Al-Marzooqi, A., Taylor, M.: The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2011b)
Mehta, P.K., Monteiro, P.J.M.: Concrete: Structure, Properties and Materials. Prentice-Hall, New Jersey (1993)
Mendoza, A.R.: Corrosion of reinforcing steel in loaded cracked concretes exposed to de-icing salts. Ph.D. thesis, University of Waterloo pp. 16–17 (2003)
Mindess, S., Young, J.F., Darwin, D.: Concrete, 2nd edn. Prentice-Hall Inc, New Jersey (2003)
Miserque, F., Huet, B., Azou, G., Bendjaballah, D., L’Hostis, V.: X-ray photoelectron spectroscopy and electrochemical studies of mild steel FeE500 passivation in concrete simulated water. J. Phys. IV 136, 89–97 (2006)
Neff, D., Dillmann, P., Burger, E., Demoulin, A., L’Hostis, V.: Thick corrosion layers in reinforced concrete: characterization and properties—a review. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 213–219, ISBN: 978-2-31158-072-1 (2009)
Pabalan, R., Chiang, K.-T.: Experimental study and reactive transport modelling of boric acid leaching of concrete. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Pabalan, R.T., Glasser, F.P., Pickett, D.A., Walter, G.R., Biswas, S., Juckett, M.R., Sabido, L.M., Myers, J.L.: Review of literature and assessment of factors relevant to performance of grouted systems for radioactive waste disposal. Report No. CNWRA 2009–001, Center for Nuclear Waste Regulatory Analyses (CNWRA), San Antonio, US (2009)
Pabalan, R.T., Yang, L., Chiang, K.-T.: Boric acid corrosion of concrete rebar. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Pourbaix, A., L’Hostis, V.: Passivation, localised corrosion and general corrosion of steel in concrete and bentonite: theory and experimentals. J. Phys. IV 136, 71–78 (2006)
Saheb, M., Marsal, F., Matthiesen, H., Neff, D., Dillmann, P., Pellegrini, D.: Fluctuations of redox conditions in radioactive waste disposal cell: characterisation of corrosion layers formed on archaeological analogues. Corros. Eng. Sci. Technol. 46(2), 199–204 (2011)
Saleh, A., Azizi, O., Rosas-Camacho, O., Al-Marzooqi, A., Macdonald, D.D.: Some important issues in electrochemistry of carbon steel in simulated concrete pore water: Part 2—Experimental. Corros. Eng. Sci. Technol. 46(2), 104–110 (2011)
Schulz, F.M., Arva, E.A., Duffó, G.S.: Studies concerning the reinforcement corrosion of concrete vaults for intermediate-level radioactive waste disposal. In: L’Hostis, V., Gens, R., Gallé, C. (eds.) Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 13–21, ISBN: 978-2-31158-072-1 (2009)
Smart, N.R., Rance, A.P., Winsley, R.J., Fennell, P.A.H., Reddy, B., Kursten, B.: The effect of irradiation on the corrosion of carbon steel in alkaline media. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 45–52, ISBN: 978-2-31158-072-1 (2009)
Smart, N.R., Fennell, P.A.H., Rance, A.P., Winsley, R.J., Reddy, B., Kursten, B.: Experimental studies of the effect of irradiation on the anaerobic corrosion of carbon steel in relation to the Belgian supercontainer concept. EPJ Web Conf. 12, 02003 (2011)
Smart, N.R., Rance, A.P., Fennell, P.A.H., Kursten, B.: The anaerobic corrosion of carbon steel in alkaline media—phase 2 results. In: Proceedings of NUCPERF 2012 Workshop, Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plant and Radioactive Waste Storage and Disposal Special issue of The European Physical Journal, vol. 56—2013 (2013)
Tikalsky, P.J., Beh, D.E.: Synthesis guide to best practices for corrosion resistant concrete. Utah Department of Transportation, Salt Lake City, Utah, USA, report UT-08.27 (2008)
Wegemar, B.: Corrosion failure of a BWR embedded reactor containment liner. J. Phys. IV 136, 257–262 (2006)
Weiss, C.A., Morefield, S.W., Malone, P.G., Koenigstein, M.L.: Role of reactive vitreous coatings in reinforced concrete in nuclear plant construction. In: Proceedings of the RILEM Workshop on Long-Term Performance of Cementitious Barriers and Reinforced Concrete in Nuclear Power Plants and Waste Management, EFC Event 317, RILEM Proceedings PRO 64, pp. 287–294, ISBN: 978-2-31158-072-1 (2009)
Winsley, R.J., Smart, N.R., Rance, A.P., Fennell, P.A.H., Reddy, B., Kursten, B.: Further studies on the effect of irradiation on the corrosion of carbon steel in alkaline media. Corros. Eng. Sci. Technol. 46(2), 111–116 (2011)
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Kursten, B., Smart, N. (2016). Corrosion. In: L'Hostis, V., Gens, R. (eds) Performance Assessment of Concrete Structures and Engineered Barriers for Nuclear Applications. RILEM State-of-the-Art Reports, vol 21. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-0904-8_3
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