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Techno-Economic Analysis of Microwave-Assisted Pyrolysis for Production of Biofuels

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Production of Biofuels and Chemicals with Microwave

Part of the book series: Biofuels and Biorefineries ((BIOBIO,volume 3))

Abstract

Microwave-assisted pyrolysis is one of the promising attempts to produce bio-fuel with a key advantage of fast internal heating by microwave irradiation. A microwave pyrolysis reactor could overcome heat transfer rate limitation which is suitable for the pyrolysis of large fragments of biomass materials. A study was carried out on the techno-economic analysis of a transportable small scale microwave assisted ex-situ catalytic pyrolysis facility converting Douglas fir pellets to aromatic hydrocarbons enriched bio-oil , syngas and biochar . The assessment showed that microwave assisted ex-situ catalytic pyrolysis of plants is profitable. The equipment costs have the largest contribution to the total capital investment, whereas the feedstock and chemicals costs have the largest contribution to the total annual production cost. Sensitivity analysis results indicate a strong impact from bio-oil yield and selling price. This implies that slight improvement in the bio-oil yield and bio-oil quality could increase the Return of Investment (ROI) significantly whereas lower yield and quality result in a rapid decrease of ROI.

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References

  1. Yoder J, Shumway R, Wandschneider P, Young D (2008) Biofuel economics and policy for Washington State. School of Economic Sciences, Washington State University, Pullman, WA 99164-6210

    Google Scholar 

  2. Borges FC, Du Z, Xie Q, Trierweiler JO, Cheng Y, Wan Y, Liu Y, Zhu R, Lin X, Chen P, Ruan R (2014) Fast microwave assisted pyrolysis of biomass using microwave absorbent. Bioresour Technol 156:267–274. http://dx.doi.org/10.1016/j.biortech.2014.01.038

  3. Kriegerbrockett B (1994) Microwave pyrolysis of biomass. Res Chem Intermed 20(1):39–49

    Article  Google Scholar 

  4. Bridgwater AV (2012) Review of fast pyrolysis of biomass and product upgrading. Biomass Bioenergy 38:68–94. http://dx.doi.org/10.1016/j.biombioe.2011.01.048

  5. Mohan D, Pittman CU, Steele PH (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20(3):848–889. doi:10.1021/ef0502397

    Article  Google Scholar 

  6. Huang YF, Kuan WH, Lo SL, Lin CF (2010) Hydrogen-rich fuel gas from rice straw via microwave-induced pyrolysis. Bioresour Technol 101(6):1968–1973. http://dx.doi.org/10.1016/j.biortech.2009.09.073

  7. Domínguez A, Menéndez JA, Fernández Y, Pis JJ, Nabais JMV, Carrott PJM, Carrott MMLR (2007) Conventional and microwave induced pyrolysis of coffee hulls for the production of a hydrogen rich fuel gas. J Anal Appl Pyrol 79(1–2):128–135. http://dx.doi.org/10.1016/j.jaap.2006.08.003

  8. Güngör A, Önenç S, Uçar S, Yanik J (2012) Comparison between the “one-step” and “two-step” catalytic pyrolysis of pine bark. J Anal Appl Pyrol 97:39–48. http://dx.doi.org/10.1016/j.jaap.2012.06.011

  9. Park HJ, Dong JI, Jeon JK, Yoo KS, Yim JH, Sohn JM, Park YK (2007) Conversion of the pyrolytic vapor of radiata pine over zeolites. J Ind Eng Chem 13(2):182–189

    Google Scholar 

  10. Aho A, Kumar N, Lashkul AV, Eränen K, Ziolek M, Decyk P, Salmi T, Holmbom B, Hupa M, Murzin DY (2010) Catalytic upgrading of woody biomass derived pyrolysis vapours over iron modified zeolites in a dual-fluidized bed reactor. Fuel 89(8):1992–2000. doi:10.1016/j.fuel.2010.02.009

    Article  Google Scholar 

  11. Iliopoulou EF, Stefanidis SD, Kalogiannis KG, Delimitis A, Lappas AA, Triantafyllidis KS (2012) Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite. Appl Catal B Environ 127:281–290. http://dx.doi.org/10.1016/j.apcatb.2012.08.030

  12. Wang L, Lei H, Lee J, Chen S, Tang J, Ahring B (2013) Aromatic hydrocarbons production from packed-bed catalysis coupled with microwave pyrolysis of Douglas fir sawdust pellets. RSC Adv 3(34):14609–14615. doi:10.1039/c3ra23104f

    Article  Google Scholar 

  13. Biddy MJ, Dutta A, Jones SB, Meyer PA (2013) Ex-situ catalytic fast pyrolysis technology pathway. Pacific Northwest National Laboratory, Richland, WA. http://www.pnl.gov/main/publications/external/technical_reports/PNNL-22317.pdf

  14. Craig Frear BZ, Fu G, Richardson M, Chen S, Fuchs MR (2005) Biomass inventory and bioenergy assessment: an evaluation of organic material resources for bioenergy production in Washington State. Washington State University, Pullman, WA

    Google Scholar 

  15. David Sjoding EK, Jensen P (2013) Developing a wood pellet/densified biomass industry in Washington state: opportunities and challenges, Technical Assessment, Vol 2013. Washington State University, Washington State University Energy Program, Olympia, Washington

    Google Scholar 

  16. Perlack RD, Turhollow AF (2003) Feedstock cost analysis of corn stover residues for further processing. Energy 28(14):1395–1403. http://dx.doi.org/10.1016/S0360-5442(03)00123-3

  17. Ruan R, Chen P, Hemmingsen R, Morey V, Tiffany D (2008) Size matters: small distributed biomass energy production systems for economic viability. Int J Agric Biol Eng 1(1):5

    Google Scholar 

  18. DOE (2011) US Billion-ton update: biomass supply for a bioenergy and bioproducts industry. Oak Ridge National Laboratory, Oak Ridge National Laboratory, Oak Ridge, TN

    Google Scholar 

  19. Jong S-J, Pradhan AR, Wu J-F, Tsai T-C, Liu S-B (1998) On the regeneration of coked H-ZSM-5 catalysts. J Catal 174(2):210–218. http://dx.doi.org/10.1006/jcat.1998.1971

  20. Brown TR, Zhang Y, Hu G, Brown RC (2012) Techno-economic analysis of biobased chemicals production via integrated catalytic processing. Biofuels Bioprod Biorefin 6(1):73–87. doi:10.1002/bbb.344

    Article  Google Scholar 

  21. Petrolia DR (2008) The economics of harvesting and transporting corn stover for conversion to fuel ethanol: a case study for Minnesota. Biomass Bioenergy 32(7):603–612. http://dx.doi.org/10.1016/j.biombioe.2007.12.012

  22. Holladay JE, White J, Bozell J, Johnson D (2007) Top value-added chemicals from biomass. Vol II—results of screening for potential candidates from biorefinery lignin. Pacific Northwest National Laboratory, Richland, WA

    Google Scholar 

  23. Zhu Y, Jones S (2009) Techno-economic analysis for the conversion of lignocellulosic biomass to gasoline via the methanol-to-gasoline (MTG) process. Pacific Northwest National Laboratory, Pacific Northwest National Laboratory, Richland, WA

    Google Scholar 

  24. Stefan Jirka TT (2013) State of the biochar industry—a survey of commercial activity in the biochar field. International Biochar Initiative. http://www.biochar-international.org/sites/default/files/StateoftheBiocharIndustry_2013_4pager_final.pdf

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Acknowledgement

This study was supported by the Joint Center for Aerospace and Technology Innovation (JCATI).

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Correspondence to Hanwu Lei .

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Wang, L., Lei, H., Ruan, R. (2015). Techno-Economic Analysis of Microwave-Assisted Pyrolysis for Production of Biofuels. In: Fang, Z., Smith, Jr., R., Qi, X. (eds) Production of Biofuels and Chemicals with Microwave. Biofuels and Biorefineries, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9612-5_12

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