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The Heat Capacity of Nanotube Bundles with 1D Chains of Gas Adsorbates

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Nanotechnology in the Security Systems

Abstract

The heat capacity of 1D chains of Xe adsorbed in the outer grooves of bundles of closed single-walled carbon nanotubes (c-SWNTs) have been investigated in the temperature range 2–85 K. The experimental results of heat capacity are close to the theoretical calculation below 8 K. Above 8 K the experimental curve exceeds the theoretical one and excess increases monotonously with temperature. It was assumed that the sharp increase of the difference between the experimental and theoretical curves of heat capacity above 30 K is associated with the occurrence of the thermally created vacancies in the chains due to spatial redistribution of the xenon atoms. The molar enthalpy of vacancy formation in the chain has been calculated.

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Author information

Authors and Affiliations

  1. B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine, 47 Lenin Ave., Kharkov, 61103, Ukraine

    M. S. Barabashko, M. I. Bagatskii & V. V. Sumarokov

Authors
  1. M. S. Barabashko
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  2. M. I. Bagatskii
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  3. V. V. Sumarokov
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Corresponding author

Correspondence to M. S. Barabashko .

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Editors and Affiliations

  1. Faculty of Mathematics and Physics, University of Ljubljana and Department of Theoretical Physics, J. Stefan Institute, Ljubljana, Slovenia

    Janez Bonča

  2. Bogolyubov Institute for Theoretical Physics, Kiev, Ukraine

    Sergei Kruchinin

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Barabashko, M.S., Bagatskii, M.I., Sumarokov, V.V. (2015). The Heat Capacity of Nanotube Bundles with 1D Chains of Gas Adsorbates. In: Bonča, J., Kruchinin, S. (eds) Nanotechnology in the Security Systems. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9005-5_11

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