Skip to main content

Taking It to Extremes – Powder Diffraction Under Non-Ambient Conditions

  • Conference paper
  • First Online:
Uniting Electron Crystallography and Powder Diffraction

Abstract

Structural studies of materials under elevated pressures provide a fascinating insight into the physical and chemical behaviour of matter under the wide range of conditions experienced throughout the Universe. Both x-ray and neutron powder diffraction techniques play a crucial role in structural studies and are therefore at the forefront of high-pressure research. These notes provide a short introduction to the principles and experimental practice of high-pressure powder diffraction techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Merrill L, Bassett WA (1974) Miniature diamond anvil pressure cell for single crystal x-ray diffraction studies. Rev Sci Instrum 45:290

    Article  ADS  Google Scholar 

  2. Norby P, Schwarz U (2008) Powder diffraction under non-ambient conditions. In: Dinnebier RE, Billinge SJL (eds) Powder diffraction theory and practice. Royal Society of Chemistry, Cambridge

    Google Scholar 

  3. Hammersley AP, Svensson SO, Hanfland M, Fitch AN, Hausermann D (1996) Two-dimensional detector software: from real detector to idealised image or two-theta scan. High Press Res 14:235

    Article  ADS  Google Scholar 

  4. Piermarini GJ, Block S, Barnett JD, Forman RA (1975) Calibration of the pressure dependence of the R1 ruby fluorescence line to 195 kbar. J Appl Phys 46:2774

    Article  ADS  Google Scholar 

  5. Syassen K (2008) Ruby under pressure. High Press Res 28:75

    Article  ADS  Google Scholar 

  6. Besson JM, Nelmes RJ, Hamel G, Loveday JS, Weill G, Hull S (1992) Neutron powder diffraction above 10 GPa. Physica B180–181:907

    Google Scholar 

  7. Marshall WG, Francis DJ (2002) Attainment of near-hydrostatic compression conditions using the Paris-Edinburgh cell. J Appl Crystallogr 35:122

    Article  Google Scholar 

  8. Decker DL, Petersen S, Debray D, Lambert M (2004) Pressure-induced ferroelastic phase transition in Pb3(PO4)2: a neutron-diffraction study. Phys Rev B 19:3552

    Article  ADS  Google Scholar 

  9. Resel R, Oehzelt M, Shimizu K, Nakayama A, Takemura K (2004) On the phase-transition in anthracene induced by high pressure. Solid State Commun 129:103

    Article  ADS  Google Scholar 

  10. Haines J, Léger JM, Gorelli F, Hanfland M (2001) Crystalline post-quartz phase in silica at high pressure. Phys Rev Lett 87:15503

    Article  Google Scholar 

  11. Machon D, Dmitriev VP, Bouvier P, Timonin PN, Shirokov VB, Weber HP (2003) Pseudoamorphization of Cs2HgBr4. Phys Rev B 68:144104

    Article  ADS  Google Scholar 

  12. Klotz S, Chervin J-C, Munsch P, Le Marchand G (2009) Hydrostatic limits of 11 pressure transmitting media. J Phys D: Appl Phys 42:075413

    Article  ADS  Google Scholar 

  13. Angel RJ, Bujak M, Zhao J, Gatta GD, Jacobsen SD (2007) Effective hydrostatic limits of pressure media for high-pressure crystallographic studies. J Appl Crystallogr 40:26

    Article  Google Scholar 

  14. Boldyreva E, Dera P (eds) (2010) High-pressure crystallography. Springer, Netherlands

    Google Scholar 

  15. Katrusiak A, McMillan P (eds) (2004) High-pressure crystallography, NATO science series II: mathematics, physics and chemistry, vol 140. Kluwer Academic Publishers, London

    Google Scholar 

  16. Grochala W, Hoffmann R, Feng J, Ashcroft NW (2007) The chemical imagination at work in very tight places. Angew Chem Int Ed 46:3620

    Article  Google Scholar 

  17. Goncharov AF, Hemley RF (2006) Probing hydrogen-rich molecular systems at high pressures and temperatures. Chem Soc Rev 35:899

    Article  Google Scholar 

  18. Santoro M, Gorelli FA (2006) High pressure solid state chemistry of carbon dioxide. Chem Soc Rev 35:918

    Article  Google Scholar 

  19. Fabbiani FPA, Pulham CR (2006) High-pressure studies of pharmaceutical compounds and energetic materials. Chem Soc Rev 35:932

    Article  Google Scholar 

  20. McMahon MI, Nelmes RJ (2006) High-pressure structures and phase transformations in elemental metals. Chem Soc Rev 35:943

    Article  Google Scholar 

  21. Horvath-Bordon E, Riedel R, Zerr A, McMillan PF, Auffermann G, Prots Y, Bronger W, Kniep R, Kroll P (2006) High-pressure chemistry of nitride-based materials. Chem Soc Rev 35:987

    Article  Google Scholar 

Download references

Acknowledgments

We thank Dstl and EPSRC for contributions toward a studentship, and the Diamond Light Source and the ISIS Neutron and Muon Facility for the provision of beamtime. We are extremely grateful to Dr Bill Marshall (ISIS) for a longstanding and fruitful collaboration.

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer Science+Business Media Dordrecht

About this paper

Cite this paper

Millar, D.I.A., Pulham, C.R. (2012). Taking It to Extremes – Powder Diffraction Under Non-Ambient Conditions. In: Kolb, U., Shankland, K., Meshi, L., Avilov, A., David, W. (eds) Uniting Electron Crystallography and Powder Diffraction. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5580-2_9

Download citation

Publish with us

Policies and ethics