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155Gd Mössbauer investigation of the magnetic order and spin-reorientation in Gd3Ag4Sn4

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ICAME 2011

Abstract

In a recent study of the magnetic order in Gd3Ag4Sn4 by neutron powder diffraction and 119Sn Mössbauer Spectroscopy we showed that both the Gd(2d) and Gd(4e) sublattices order antiferromagnetically at 28.8(2) K. We also demonstrated that the ‘magnetic event’ around 8 K is in fact a ‘plane to axis’ spin-reorientation of the Gd magnetic structure. Here, we extend our study with 155Gd Mössbauer Spectroscopy. The initial magnetic ordering at 30(2) K is clear for both sites and substantial changes in the hyperfine fields are observed at 8 K when the magnetic structure reorients.

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References

  1. Rieger, W.: Die kristallstruktur von Gd6Cu8Ge8 und isotypen phasen. Monatsch. Chem. 101, 449–462 (1970)

    Article  Google Scholar 

  2. Ryan, D.H., Cadogan, J.M., Voyer, C.J., Napoletano, M., Riani, P., Cranswick, L.M.D.: Using neutron diffraction and Mössbauer spectroscopy to study magnetic ordering in the R3T4Sn4 family of compounds. Mod. Phys. Lett. B 24, 1–28 (2010)

    Article  ADS  Google Scholar 

  3. Mazzone, D., Riani, P., Napoletano, M., Canepa, F.: The magnetism of Sm3Ag4Sn4 and Gd3Ag4Sn4. J. Alloys Compd. 387, 15–19 (2005)

    Article  Google Scholar 

  4. Voyer, C.J., Ryan, D.H., Napoletano, M., Riani, P.: Magnetic ordering in Gd3Cu4Sn4 and Gd3Ag4Sn4 studied using 119Sn Mössbauer spectroscopy. J. Phys. Condens. Matter 19(156209), 10 (2007)

    Google Scholar 

  5. Cadogan, J.M., Ryan, D.H., Napoletano, M., Riani, P., Cranswick, L.M.D.: Neutron powder diffraction determination of the magnetic structure of Gd3Ag4Sn4. J. Phys. Condens. Matter 21(124201), 8 (2009)

    Google Scholar 

  6. Voyer, C.J., Ryan, D.H.: A complete solution to the Mössbauer problem, all in one place. Hyperfine Interact. 170, 91–104 (2006)

    Article  ADS  Google Scholar 

  7. Dhar, S.K., Singh, S., Bonville, P., Mazumdar, C., Manfrinetti, P., Palenzona, A.: Magnetic behaviour of Yb3Cu4Ge4 and Gd3Cu4Ge4. Physica B 312313, 846–847 (2002)

    Article  Google Scholar 

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Correspondence to J. M. Cadogan .

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Voyer, C.J., Ryan, D.H., Cadogan, J.M. (2013). 155Gd Mössbauer investigation of the magnetic order and spin-reorientation in Gd3Ag4Sn4 . In: Yoshida, Y. (eds) ICAME 2011. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4762-3_95

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