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Inorganic Ion Exchangers in Paper and Thin-Layer Chromatographic Separations

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Ion Exchange Technology II

Abstract

Planar chromatography, i.e., paper and thin-layer chromatography, is a simple and fast method for the separation of various classes of organic and inorganic compounds. Numerous inorganic and organic stationary phases were used in planar chromatography providing effective separations based on different mechanisms. Apart from the most commonly used stationary phases such as cellulose, silica gel, alumina, and modified silica gels, various inorganic ion exchangers were successfully used as sorbents in planar chromatography in a large number of cases. Due to the introduction of ion exchange as an additional separation mechanism, the selectivity of planar chromatography was significantly improved, especially for the separation of inorganic ions and polar organic substances. Numerous literature data related to the usage of inorganic ion exchangers in both paper and thin-layer chromatographic separations are presented through corresponding applications.

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References

  1. Miller JM (2005) Chromatography: concepts and contrasts. Wiley, New Jersey

    Google Scholar 

  2. Sherma J, Fried B (2003) Handbook of thin-layer chromatography. Marcel Dekker, New York

    Book  Google Scholar 

  3. Poole CF (2003) The essence of chromatography. Elsevier, Amsterdam

    Google Scholar 

  4. Burma DP (1953) Partition mechanism of paper chromatography. Anal Chem 25(4):549–553

    Article  CAS  Google Scholar 

  5. Sherma J (2010) Planar chromatography. Anal Chem 82:4895–4910

    Article  CAS  Google Scholar 

  6. Oьшaнoвa КM, Пoтaпoвa MA, Кoпылoвa BД, Mopoзoвa HM (1965) Pукoвoдcтвo пo иoнooбмeннoй, pacпpeдeлитeльнoй и ocaдoчнoй xpoмaтoгpaфии. Xимия, Mocквa

    Google Scholar 

  7. Rabel FM (2003) Sorbents and precoated layers in thin-layer chromatography. In: Sherma J, Fried B (eds) Handbook of thin-layer chromatography, 3rd edn. Marcel Dekker, New York

    Google Scholar 

  8. Naushad Mu (2009) Inorganic and composite ion-exchange materials and their applications. Ion Exch Lett 2:1–14

    CAS  Google Scholar 

  9. Townsend RP (1986) Ion-exchange in zeolites: some recent developments in theory and practice. Pure Appl Chem 58(10):1359–1366

    Article  CAS  Google Scholar 

  10. Troup JM, Clearfield A (1977) Mechanism of ion-exchange in zirconium phosphates. 20. Refinement of the crystal structure of ά-zirconium phosphate. Inorg Chem 16(12):3311–3314

    Article  CAS  Google Scholar 

  11. Clearified A (1993) Ion-exchange and adsorption in layered phosphates. Mat Chem Phys 35(3–4):257–263

    Article  Google Scholar 

  12. Qureshi M, Kumar R, Rathore KS (1972) Separation of cadmium(II) from zinc(II) and other metal ions on a cadmium selective exchangers: titanium selenite. Anal Chem 44(6):1081–1084

    Article  CAS  Google Scholar 

  13. Alberti GM, Massucci MA (1970) Crystalline insoluble salts of tetravalent metals. IX Thorium arsenate, a new inorganic ion-exchanger specific for lithium. J Inorg Nucl Chem 32(5):1719–1727

    Article  CAS  Google Scholar 

  14. Inoue Y (1964) Studies on the synthetic inorganic ion-exchangers. Synthesis of stannic phosphate and some of its properties. J Inorg Nucl Chem 26(12):2241–2253

    Article  CAS  Google Scholar 

  15. Tandon SN (1973) Synthesis and ion-exchange properties of ceric tungstate. Talanta 20(6):585–588

    Article  CAS  Google Scholar 

  16. Qureshi M, Kumar RM, Rathore HS (1972) Studies on chromium(III) hydroxide, arsenate, antimonate, molybdate and tungstate. Talanta 19(11):1377–1386

    Article  CAS  Google Scholar 

  17. Rawat JP, Thind PS (1976) Studies on inorganic ion-exchangers. I Preparation, properties and applications of ferric phosphate. Can J Chem 54(12):1892–1898

    Article  CAS  Google Scholar 

  18. Qureshi M, Gupta JP, Sharma V (1973) Synthesis of a reproducible and chemically stable tantalum antimonate. Anal Chem 45(11):1901–1906

    Article  CAS  Google Scholar 

  19. Torok G, Diehl JF (1971) Preparation and properties of antimony(V) aquaoxide for separation of sodium in activation analysis. Radiochim Acta 15(2):96–100

    CAS  Google Scholar 

  20. Nagy LG, Torok G, Foti G (1975) Investigation on the structure and sorption properties of hydrated antimony pentoxide used for the selective removal of radiosodium. Proc Int Conf Coll Surf Sci 1:33–40

    CAS  Google Scholar 

  21. Gill JS, Tandon SN (1972) Preparation and ion-exchange properties of stannic ferrocyanide. J Inorg Nuc Chem 34(12):3885–3892

    Article  CAS  Google Scholar 

  22. Gupta AP, Qureshi M, Sunanda Y (1983) Studies on a new adsorbent ion-exchange material: hydrous antimony sulphide. J Chem Sec A 22A(8):721–722

    CAS  Google Scholar 

  23. Krtil J, Chavko M (1967) Ion-exchange properties of ammonium salts of heteropolyacids: VII sorption of 137Cs and 86Rb on acid and normal ammonium and thallous salts of phosphotungstanic and phosphomolybdic acid. J Chromatogr 27:460–473

    Article  CAS  Google Scholar 

  24. Wei H, Collinson MM (1998) Functional-group effects on the ion-exchange properties of organically modified silicates. Anal Chim Acta 397:113–121

    Article  Google Scholar 

  25. Varshney KG, Tayal N et al (2001) Synthesis, characterization and analytical applications of lead(II) selective polyacrylonitrile thorium(IV) phosphate: a novel fibrous ion-exchanger. Coll Surf 181:123–129

    Article  CAS  Google Scholar 

  26. Pandit B, Chudasma U (2001) Synthesis, characterization and application of an inorganic organic material: p-chlorophenol anchored onto zirconium tungstate. Bull Mater Sci 24(3):265–271

    Article  CAS  Google Scholar 

  27. Khan AA, Niwas R, Alam MM (2002) Ion-exchange materials on styrene supported zirconium(IV) tungstate: an organic-inorganic type cation-exchanger. Ind J App Chem 9(3):256–260

    CAS  Google Scholar 

  28. Inamuddin KSA, Siddiqui WA et al (2007) Synthesis, characterization and ion-exchange properties of a new and novel ‘organic–inorganic’ hybrid cation-exchanger: Nylon-6,6, Zr(IV) phosphate. Talanta 71:841–847

    Article  CAS  Google Scholar 

  29. Sairam Sundaram C, Meenakshi S (2009) Fluoride sorption using organic–inorganic hybrid type ion-exchangers. J Colloid Interface Sci 333:58–62

    Article  CAS  Google Scholar 

  30. Khan AA, Akhtar T (2009) Synthesis, characterization and ion-exchange properties of a fibrous type ‘polymeric-inorganic’ composite cation-exchanger Nylon-6,6 Sn(IV) phosphate: its application in making Hg(II) selective membrane electrode. Electrochim Acta 54:3320–3329

    Article  CAS  Google Scholar 

  31. Alam Z, Inamuddin NSA (2010) Synthesis and characterization of a thermally stable strongly acidic Cd(II) ion selective composite cation-exchanger: polyaniline Ce(IV) molybdate. Desalination 250:515–522

    Article  CAS  Google Scholar 

  32. Amphlett CB (1964) Inorganic ion-exchangers. Elsevier, Amsterdam

    Google Scholar 

  33. Walton HF (1968) Ion-exchange chromatography. Anal Chem 40(5):51R–62R

    Article  CAS  Google Scholar 

  34. Walton HF (1974) Ion-exchange. Anal Chem 46(5):398R–413R

    Article  CAS  Google Scholar 

  35. Sherma J, Zweig G (1971) Paper chromatography and electrophoresis, vol 2, Paper chromatography. Academic, New York

    Google Scholar 

  36. Sherma J, Fried B (1990) Handbook of thin-layer chromatography. Marcel Dekker, New York

    Google Scholar 

  37. Gocan S (2002) Stationary phases for thin-layer chromatography. J Chromatogr Sci 40(10):538–549

    CAS  Google Scholar 

  38. Alberti G, Grassini G (1960) Chromatography on paper impregnated with zirconium phosphate. J Chromatogr 4:83–85

    Article  CAS  Google Scholar 

  39. Nunes MJ, Jeronimo MAS (1961) Zirconium selenite as ion-exchanger. J Chromatogr 5:546–546

    Google Scholar 

  40. Alberti G, Dobici F, Grassini G (1962) Chromatography on paper impregnated with inorganic ion-exchangers. III Chromatography of inorganic ions on zirconium phosphate papers with HCl, HNO3, HClO4 and CH3COOH at various concentration. J Chromatogr 8:103–107

    Article  CAS  Google Scholar 

  41. Sastri MN, Rao AP (1962) Separation of the valency states of some elements on paper impregnated with zirconium phosphate. J Chromatogr 9:250–251

    Article  CAS  Google Scholar 

  42. Grassini G, Padiglione C (1964) The exchange capacity of papers impregnated with zirconium phosphates. J Chromatogr 13:561–564

    Article  CAS  Google Scholar 

  43. Sakodinsky K, Lederer M (1965) The chromatographic properties of paper impregnated with titanium hydroxide. J Chromatogr 20(2):358–366

    CAS  Google Scholar 

  44. Qureshi M, Akhtar I, Mathur KN (1967) Separation of metal ions on stannic phosphate and stannic tungstate papers. Anal Chem 39(14):1766–1770

    Article  CAS  Google Scholar 

  45. Qureshi M, Fahmida K (1968) Fast separation of titanium(IV), arsenic(III), tungsten(VI), gold(III) from numerous metal ions and of iron-aluminium-titanium by paper chromatography. J Chromatogr 34(2):222–236

    CAS  Google Scholar 

  46. Qureshi M, Kishore MN (1968) Quantitative separation of selenium from metal ions on tin(IV) tungstate papers. Anal Chim Acta 41(3):560–563

    Article  CAS  Google Scholar 

  47. Qureshi M, Husain W (1969) Separation of metal ions on titanum(IV) tungstate papers. Sep Sci 4(3):197–207

    Article  CAS  Google Scholar 

  48. Qureshi M, Mathur KN, Israli AH (1969) Separation of metal ions on tin(IV) tungstanate and selenite papers. Talanta 16(4):503–509

    Article  CAS  Google Scholar 

  49. Qureshi M, Qureshi ZS (1972) Relative exchange capacities on stannic phosphate papers. Sep Sci 7(2):187–191

    Article  CAS  Google Scholar 

  50. Qureshi M, Varshney KG, Fahmida K (1972) Synthesis, ion-exchange behavior, and analytical applications of stannous ferrocyanide. Separation of magnesium-calcium, magnesium-barium, manganese-nickel and yttrium-thorium. J Chromatogr 65(3):547–555

    Article  CAS  Google Scholar 

  51. Husain SW (1972) Chromatographic separation of metal ions on ion-exchange papers. Analusis 1(4):314–316

    CAS  Google Scholar 

  52. Qureshi M, Sharma SD (1973) Prediction of Ksp from RF values. Chromatography of 48 metal ions on stannic arsenate and plain papers in butanol – nitric acid media. Anal Chem 45(7):1283–1288

    Article  CAS  Google Scholar 

  53. Qureshi M, Varshney KG, Fahmida K (1973) Chromatographic separation of metal ions on stannous ferrocyanide papers. Sep Sci 8(2):279–284

    Article  CAS  Google Scholar 

  54. Qureshi M, Sharma SD (1975) Chromatographic behavior of 48 cations on stannic and titanium arsenate papers in aqueous nitric acid system. Talanta 22(2):129–133

    Article  CAS  Google Scholar 

  55. Qureshi M, Varshney KG, Rajput RPS (1975) Chromatography of 49 metal ions on stannic antimonate papers in dimethylsulfoxide-nitric acid systems. Anal Chem 57(9):1520–1524

    Article  Google Scholar 

  56. Qureshi M, Nabi SA, Zehra N (1975) Chromatographic separations of amino acids on titanium arsenate. Sep Sci 10(6):801–808

    Article  CAS  Google Scholar 

  57. Singh NJ, Tandon SN (1977) Rapid separation of metal ions on hydrous zirconium oxide papers. Chromatographia 10(6):309–311

    Article  CAS  Google Scholar 

  58. Rajeev JM, Tandon SN (1977) Rapid separation of alkali metal ions on zirconium antimonite papers. Chromatographia 10(1):45–46

    Article  Google Scholar 

  59. Angus HJF, Briggs J, Sug NA et al (1978) Chromatography of polyhydroxy compounds on cellulose impregnated with tungstate: determination of pseudostability constants of complexes. Carbohydr Res 66(1):25–32

    Article  CAS  Google Scholar 

  60. Qureshi M, Anees A, Mohammed SA, Ahmad SN (1987) Separation of certain organic pollutants containing tertiary nitrogen on stannic molybdosilicate papers. Anal Lett 20(8):1157–1169

    Article  CAS  Google Scholar 

  61. Surendra KVN, Tandon SN (1988) Chromatographic separation of anions on papers impregnated with hydrous titanium oxide. J Liq Chromatogr Related Technol 11(7):1433–1439

    Article  Google Scholar 

  62. Dabral SK, Singh MKP, Rawat JR (1988) Ion-exchange chromatographic separations of some anions on hydrate stannic oxide impregnated paper. Ind J Chem Sect A 27A(8):745–746

    Google Scholar 

  63. Dabral SK, Muktawat KPS, Rawat JP (1988) Ion-exchange chromatographic separation on hydrated bismuth oxide impregnated papers. Anal Lett 21(4):613–620

    Article  CAS  Google Scholar 

  64. Dabral SK, Muktawat KPS, Rawat JP (1989) Ion-exchange chromatographic studies of some physiologically important organic acids on impregnated papers. Anal Lett 22(1):61–69

    Article  CAS  Google Scholar 

  65. Dabral SK, Rawat JP, Muktawat KPS (1989) Ion-exchange chromatographic determination of amino acids on impregnated papers. Anal Lett 22(3):537–543

    Article  CAS  Google Scholar 

  66. Dabral SK (1989) The effect of surfactants on the chromatographic separation of phenols on paper impregnated with hydrated cerium oxide. Anal Lett 22(6):1623–1629

    Article  CAS  Google Scholar 

  67. Sharma SD, Misra S, Gupta R, Agarwal A (1995) Increased selectivity for planar chromatography by ion-exchange: ion chromatography on papers impregnated with stannic antimonate and stannic arsenate. J Ind Chem Soc 72(9):657–660

    CAS  Google Scholar 

  68. Sharma SD, Gupta R (2000) Increased selectivity for planar chromatography by ion-exchange: cation chromatography on papers impregnated with titanium(IV) based inorganic exchangers in DMSO-HNO3 mobile phase. J Ind Chem Soc 77(4):204–206

    CAS  Google Scholar 

  69. Misra AK, Pachauree S (2001) Retention behavior of synthetic dyes on zirconium antimonate papers. Acta Chromatogr 11:139–153

    CAS  Google Scholar 

  70. Lederer M (1999) Fifty years of inorganic chromatography. Chem Intell 5(3):31–34

    CAS  Google Scholar 

  71. Lederer M (1994) Chromatography for inorganic chemistry. Wiley, Chichester

    Google Scholar 

  72. Mohammad A (2003) Inorganic and organometallic compounds. In: Sherma J, Fried B (eds) Handbook of thin-layer chromatography, 3rd edn. Marcel Dekker, New York

    Google Scholar 

  73. Geiss F (1987) Fundamentals of thin-layer chromatography (planar chromatography). Huthig, Heidelberg

    Google Scholar 

  74. Engelhardt H (1979) High performance liquid chromatography. Springer, Heidelberg

    Book  Google Scholar 

  75. Hauck HE, Mack M, Jost W (1991) Chromatogr Sci 55:87–111

    CAS  Google Scholar 

  76. Boehm HP (1966) Functional groups on the surface of solids. Angew Chemie 78(12):617–628

    Article  CAS  Google Scholar 

  77. Smith RL, Pietrzyk DJ (1984) Liquid chromatographic separation of metal ions on a silica column. Anal Chem 56:610–614

    Article  CAS  Google Scholar 

  78. Ohta K, Sando M, Tanaka K et al (1996) Simultaneous determination of common mono- and divalent cations by ion chromatography with an unmodified silica gel column. J Chromatogr A 752:167–172

    Article  CAS  Google Scholar 

  79. Hirata Sh, Kozaki D, Sakanishi K et al (2010) Simultaneous determinations of Cr(VI) and Cr(III) by ion-exclusion/cation-exchange chromatography with an unmodified silica-gel column. Anal Sci 26:387–390

    Article  CAS  Google Scholar 

  80. Druding LF, Hagel RB (1966) Separation of cis-trans-cobalt(III) amine complexes by thin layer chromatography. Anal Chem 38:478–480

    Article  CAS  Google Scholar 

  81. Mohammad A (1996) Inorganic and organometallics. In: Sherma J, Fried B (eds) Handbook of thin-layer chromatography, 2nd edn. Marcel Dekker, New York

    Google Scholar 

  82. ŽLj Tešić, Grgurić SR, Trifunović SR et al (1997) Planar chromatography of facial and meridional isomers of some aminocarboxylato cobalt(III) complexes. J Planar Chromatogr 10:457–459

    Google Scholar 

  83. Milojković-Opsenica DM, Malinar MJ, Tešić ŽLj (1999) Effect of the chelate ring size of diamine-Co(III) complexes on their hRF values obtained under salting-out thin-layer chromatography conditions. J Chromatogr A 847:291–296

    Article  Google Scholar 

  84. Shepherd RE (2003) Chromatographic and related electrophoretic methods in the separation of transition metal complexes or their ligands. Coord Chem Rev 247:147–184

    Article  CAS  Google Scholar 

  85. Radoičić A, Majstorović H, Sabo T et al (2009) Hydrophilic-interaction planar chromatography of some water-soluble Co(III) complexes on different adsorbents. J Planar Chromatogr 22(4):249–253

    Article  CAS  Google Scholar 

  86. Lederer M (1999) The story of ion-exchange resin papers. Chem Intell 5(4):32–34

    CAS  Google Scholar 

  87. Zabin BA, Rollins CB (1964) Inorganic ion-exchangers for thin-layer chromatography. J Chromatogr 14(3):534–535

    CAS  Google Scholar 

  88. Husain SW, Kazmi SK (1972) Thin layer chromatography of metal ions on a new synthetic inorganic ion-exchanger. Experientia 28(8):988–989

    Article  CAS  Google Scholar 

  89. Husain SW, Eivazi F (1975) Thin layer chromatography of 57 metal ions on an inorganic ion-exchanger in mixed solvent systems. Chromatographia 8(6):277–282

    Article  CAS  Google Scholar 

  90. Husain SW, Rasheedzad S (1978) Thin-layer chromatographic separation of platinum metals on a semi-crystalline inorganic ion-exchanger. Mikrochim Acta 1(1–2):11–18

    Article  CAS  Google Scholar 

  91. Husain SW, Rasheedzad S (1979) Chromatography of toxic metals on thin layers of lanthanum tungstate. Recent Dev Chromatogr Electrophor 1:239–245

    CAS  Google Scholar 

  92. De AK, Rajput RPS, Das SK (1979) Synthetic inorganic ion-exchangers. XII. Thin-layer chromatography of metals ions on thorium antimonate: quantitative separation of mercury(II) from several metal ions. Sep Sci Technol 14(8):735–739

    Article  CAS  Google Scholar 

  93. De AK, Pal BK (1979) Synthetic inorganic ion-exchangers. XV. Thin-layer chromatography of metal ions on thorium tungstate: quantitative separation of mercury(II) from several other metal ions. J Liq Chromatogr 2(7):935–941

    Article  CAS  Google Scholar 

  94. De AK, Pal BK (1980) Synthetic inorganic ion-exchangers. XVI. Thin-layer chromatography of metal ions on zirconium tungstate: quantitative separation of mercury(II) from several other metal ions and from mixtures. Sep Sci Technol 15(5):1271–1275

    Article  CAS  Google Scholar 

  95. De AK, Chakraborty P (1981) Synthetic inorganic ion-exchangers. XX. Thin layer chromatography of metal ions on lanthanum antimonate. Quantitative separation of mercury(II) from several metal ions. J Liq Chromatogr 4(12):2223–2228

    Article  CAS  Google Scholar 

  96. Yin B, Lei G, Xie L (1982) Ion-exchange properties of stannic phosphate. II. The thin-layer chromatographic behavior of forty metallic ions. Huaxue Xuebao 40(3):281–286

    CAS  Google Scholar 

  97. Ying B, Lei G, Liu G (1982) Ion-exchange properties of stannic phosphate. (III). Chromatographic behavior of forty-four cations on stannic phosphate layers. Gaodeng Xuexiao Huaxue Xuebao 3(1):28–34

    CAS  Google Scholar 

  98. Seth NS, Rajput RPS (1983) Thin-layer chromatography of metal ions on titanium(IV) antimonate in aqueous and mixed solvent systems containing DMF: quantitative separation of palladium(II) from several metal ions. Indian J Chem Sect A 22A(12):1088–1090

    CAS  Google Scholar 

  99. Varshney KG, Khan AA, Anwar S (1985) Chromatography of alkaline earths and transition metals on tin(IV) arsenosilicate and arsenophosphate thin layers in buffered EDTA solutions. J Liq Chromatogr 8(7):1347–1353

    Article  CAS  Google Scholar 

  100. Yin B, Liu J (1985) Thin layer chromatographic behavior of noble metal ions on a semicrystalline inorganic ion-exchanger. Huaxue Tongbao 7:25–27

    Google Scholar 

  101. Rajput RPS, Agrawal Sh (1985) Chromatographic behavior of anions of zirconium(IV) molybdate papers and silica gel ‘G’ thin layers. Anal Lett 18(A14):1783–1788

    Article  CAS  Google Scholar 

  102. Song J, Yin B (1985) Ion-exchange properties of semicrystalline form of stannic phosphate -centrifugal thin-layer chromatographic separation of noble metals. Xibei Daxue Xuebao Ziran Kexueban 15(2):56–60

    CAS  Google Scholar 

  103. Liu L, Liu J, Huang Zh et al (1987) Inorganic ion-exchanger containing phosphorus. III. Thin-layer chromatographic separation of noble metals on stannic pyrophosphate. Wuhan Daxue Xuebao. Ziran Kexueban 1:64–70

    Google Scholar 

  104. Liu Xu, Liu J, Liu L et al (1987) Studies on the new inorganic ion-exchanger containing phosphorus. (IV). Thin-layer chromatography separation of noble metals on stannic selenopyrophosphate. Gaodeng Xuexiao Huaxue Xuebao 8(8):688–692

    CAS  Google Scholar 

  105. Bold A, Popa A, Vasile A et al (1989) Zeolite molecular sieves as stationary phase in thin layer chromatography. V. On migration mechanism. Rev Roum Chim 34(1):59–63

    CAS  Google Scholar 

  106. Husain SW, Ghoulipour V (1989) Thin-layer chromatography of metal ions on an ion-exchanger – stannic silicate. J Planar Chromatogr-Mod TLC 2(6):474–476

    CAS  Google Scholar 

  107. Husain SW, Ishghy Z, Chaloosi M (1990) Quantitative TLC of toxic elements on inorganic ion-exchangers. I. Separation and determination of mercury. J Planar Chromatogr-Mod TLC 3:271–272

    CAS  Google Scholar 

  108. Husain SW, Ishghy Z (1992) Quantitative TLC of toxic elements on inorganic ion-exchangers. IV. Cadmium and lead. J Liq Chromatogr 15(10):1681–1687

    Article  CAS  Google Scholar 

  109. Mohammad A, Ajmal M, Fatima N et al (1992) Some observations on the sorption behavior of heavy metals on layers prepared from mixtures of silica and inorganic ion-exchange gels. J Planar Chromatogr-Mod TLC 5(5):368–375

    CAS  Google Scholar 

  110. Varshney KG, Khan AA, Siddiqui MS (1993) Thin layer and paper chromatography of metal ions on some inorganic ion-exchangers using nicotine as a developer at different pH values. Proc Nat Acad Sci India Sect A Phys Sci 63(3):495–499

    CAS  Google Scholar 

  111. Husain SW, Avanes A, Ghoulipour V (1996) Thin layer chromatography of metal ions on cerium(III) silicate: a new ion-exchanger. J Planar Chromatogr-Mod TLC 9(1):67–69

    CAS  Google Scholar 

  112. Husain SW, Mirzaie A (1997) Chromatographic separation of inorganic ions on thin layers of lanthanum silicate ion-exchanger. Chromatographia 45:347–350

    Article  CAS  Google Scholar 

  113. Su Zh, Feng H, Yin B (1997) Studies on inorganic ion-exchangers. IV. Thin-layer chromatographic application of metaphosphate. Lizi Jiaohuan Yu Xifu 13(5):459–465

    CAS  Google Scholar 

  114. Ghoulipour V, Husain SW (1999) New sorbents in planar chromatography: I. Separation of inorganic ions on layered double hydroxides. J Planar Chromatogr-Mod TLC 12(5):378–382

    CAS  Google Scholar 

  115. Ghoulipour V, Husain SW (2000) New adsorbents in planar chromatography: II. Behavior of metal ions on titanium(IV) silicate ion-exchanger. J Planar Chromatogr-Mod TLC 13(5):354–358

    CAS  Google Scholar 

  116. Ghoulipour V, Husain SW (2000) Ion-exchanger bismuth silicate as a novel sorbent in thin layer chromatography. Anal Sci 16:1079–1081

    Article  CAS  Google Scholar 

  117. Mohammad A, Yousuf R, Hamid Y (2001) Thin layer chromatography of inorganic ions on blended inorganic ion-exchangers with tributyl phosphate-formic acid as mobile phase. Acta Chromatogr 11:171–182

    CAS  Google Scholar 

  118. Ghatuary RK, Mukhopadhyay AK, Sarkar CK (2001) Thin layer chromatographic separation of anions by naturally occurring mixed oxides impregnated plates. J Indian Chem Soc 78(9):492–494

    CAS  Google Scholar 

  119. Ghoulipour V, Husain SW (2001) Thin layer chromatography of toxic metals on mixed bed of titania and silica. Ann Chim (Rome) 91(1–2):111–116

    CAS  Google Scholar 

  120. Sharma SD, Gupta R (2001) Retention behavior of metal ions on plain and tri-n-butylamine impregnated titanium(IV) tungstate layers. J Indian Chem Soc 78(6):301–304

    CAS  Google Scholar 

  121. Ghoulipour V, Husain SW (2002) Inorganic ion-exchangers for quantitative TLC of toxic elements. V. Separation and determination of chromium(VI). Acta Chromatogr 12:170–176

    CAS  Google Scholar 

  122. Ghoulipour V, Husain SW (2006) Quantitative TLC of toxic elements on inorganic ion-exchangers. VI. Separation and determination of cadmium. J Planar Chromatogr-Mod TLC 19(109):246–250

    Article  CAS  Google Scholar 

  123. Lowe BM, Cook HL (1982) Investigation of zeolites by thin-layer chromatography. Zeolites 2(1):29–32

    Article  CAS  Google Scholar 

  124. Nabi SA, Farooqui WU, Rahman N (1985) A semicrystalline inorganic ion-exchanger for thin-layer chromatographic separation of phenolic compounds. Chromatographia 20(2):109–111

    Article  CAS  Google Scholar 

  125. Kulshrestha S, Dabral SK, Muktawat KPS et al (2002) The effect of ionic surfactants on the behavior of phenols on bismuth tungstate thin layers. J Indian Chem Soc 79(9):739–742

    CAS  Google Scholar 

  126. Nabi SA, Farooqui WU, Siddiqui ZM et al (1983) Thin-layer chromatographic separations of amino acids on stannic tungstate. J Liq Chromatogr 6(1):109–122

    Article  CAS  Google Scholar 

  127. Siddiqi ZM, Rani S (1995) Studies of Tin(IV) selenoarsenate III: thin layer chromatography of α-amino acids. J Planar Chromatogr-Mod TLC 8(2):141–143

    CAS  Google Scholar 

  128. Sharma SD, Sharma H, Sharma SC (2002) Thin layer chromatography of amino acids on titanium tungstate using dimethyl sulfoxide as the mobile phase. Chem Environ Res 11(1 & 2):179–187

    CAS  Google Scholar 

  129. Kulshrestha Sh, Dabral SK, Muktawat KPS (2001) Bismuth tungstate inorganic ion-exchanger – an absorbent for thin layer chromatography of organic acids. J Ind Chem Soc 78(7):374–376

    CAS  Google Scholar 

  130. Nabi SA, Gupta A, Khan MA et al (2002) Thin-layer chromatographic separations of some common pesticides on mixed stannic oxide–silica gel G layers. Acta Chromatogr 12:201–210

    CAS  Google Scholar 

  131. Husain SW, Kiarostami V, Morrovati M et al (2003) Multiresidue determination of diazinon and ethion in pistachio nuts by use of matrix solid phase dispersion with a lanthanum silicate co-column and gas chromatography. Acta Chromatogr 13:208–214

    CAS  Google Scholar 

  132. Nabi SA, Laiq E, Islam A (2004) Selective separation and determination of cephalosporins by TLC on stannic oxide layers. Acta Chromatogr 14:92–101

    CAS  Google Scholar 

  133. Husain SW, Ghoulipour V, Sepahrian H (2004) Chromatographic behavior of antibiotics on thin layer of an inorganic ion-exchanger. Acta Chromatogr 14:102–109

    CAS  Google Scholar 

  134. Hassankhani-Majd Z, Ghoulipour V, Husain SW (2006) Chromatographic behavior of performance-enhancing drugs on thin layers of bismuth silicate ion-exchanger. Acta Chromatogr 16:173–180

    CAS  Google Scholar 

  135. Purghazi K, Ghoulipou V, Husain SW et al (2007) Rapid chromatographic separation of food additives on thin layers of an inorganic ion-exchanger. Acta Chromatogr 18:219–225

    CAS  Google Scholar 

  136. Ghoulipour V, Amini S, Haghshenas A et al (2010) Chromatographic behaviour of food additives on thin layers of titanium(IV) silicate ion-exchanger. J Planar Chromatogr 23(4):250–254

    Article  CAS  Google Scholar 

  137. Mirzaie A, Jamshidi A, Husain SW (2007) TLC quantification of methylparaben on an inorganic ion-exchanger in the presence of other food additives. J Planar Chromatogr-Mod TLC 20(2):141–143

    Article  CAS  Google Scholar 

  138. Mirzaie A, Jamshidi A, Husain SW (2007) Quantitative ion-exchange TLC of p-hydroxybenzoic acid in the presence of preservatives. J Planar Chromatogr-Mod TLC 20(4):303–306

    Article  CAS  Google Scholar 

  139. Jamshidi A, Husain SW (2007) Fast chromatographic separation of plasticizers on thin layers of an inorganic ion-exchanger: quantitative determination of di(2-ethylhexyl)phthalate. Chromatographia 65(3/4):245–248

    Google Scholar 

  140. Kulshrestha Sh, Awasthi A, Dabral SK (2010) Effect of ionic surfactants on the resolution of amines of hydrated stannic oxide impregnated thin layer chromatography. Asian J Chem 22(4):2507–2510

    CAS  Google Scholar 

  141. Thomas R, Janardanan C (2007) Synthesis, properties and analytical applications of titanium(IV) iodosulfosalicylate – a new hybrid inorganic-organic ion – exchanger. J Ind Counc Chem 24(2):5–10

    CAS  Google Scholar 

  142. Thomas R (2008) Synthesis, properties and analytical applications of titanium(IV) phosphosulphosalicylate – a new hybrid inorganic-organic ion-exchanger. Orient J Chem 24(1):139–146

    CAS  Google Scholar 

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Acknowledgment

The authors are grateful to the Ministry of Science and Technological Development of the Republic of Serbia (Grant No. 172017) for financial support.

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Correspondence to Živoslav Tešić .

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Tešić, Ž., Milojković-Opsenica, D. (2012). Inorganic Ion Exchangers in Paper and Thin-Layer Chromatographic Separations. In: Inamuddin, D., Luqman, M. (eds) Ion Exchange Technology II. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4026-6_15

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