Skip to main content

Carbon Nanotube Synthesis and the Role of Catalyst

  • Chapter
  • First Online:
Frontiers of Graphene and Carbon Nanotubes

Abstract

This chapter describes the synthesis of single-walled carbon nanotubes (SWCNTs) by chemical vapour deposition (CVD). Nanoparticles called catalyst are indispensable to grow SWCNTs. Although commonly used catalyst species are iron-group metals, Fe, Co and Ni, they are not limited to metals but also encompass nonmetallic species. The essential role of the catalyst particle is to provide a large curvature surface for the formation of cap structure that includes five-membered rings and acts as the nucleus of SWCNT.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Iijima S (1991) Helical microtubles of graphitic carbon. Nature 354:56

    Article  Google Scholar 

  2. Thess A, Lee R et al (1996) Crystalline ropes of metallic carbon nanotubes. Science 273:483

    Article  Google Scholar 

  3. Aikawa S, Kizu T, Nishikawa E, Kioka T (2007) Carbon nanomaterial synthesis from sucrose solution without using graphetic electrodes. Chem Lett 36:1426

    Article  Google Scholar 

  4. Kong J, Soh H et al (1998) Synthesis of single single-walled carbon nanotubes on patterned silicon wafers. Nature 395:878

    Article  Google Scholar 

  5. Kong J, Cassell AM, Dai H (1998) Chemical vapor deposition of methane for single-walled carbon nanotubes. Chem Phys Lett 292:567

    Article  Google Scholar 

  6. Hamilton JC, Blakely JM (1980) Carbon segregation to single crystal surfaces of Pt, Pd and Co. Surf Sci 91:199

    Article  Google Scholar 

  7. Gavillet J, Loiseau A et al (2001) Root-growth mechanism for single-wall carbon nanotubes. Phys Rev Lett 87:275504

    Article  Google Scholar 

  8. Yoshida H, Takeda S et al (2008) Atomic-scale in-situ observation of carbon nanotube growth from solid state iron carbide nanoparticles. Nano Lett 8:2082

    Article  Google Scholar 

  9. Kodambaka S, Tersoff J et al (2007) Germanium nanowire growth below the eutectic temperature. Science 316:729

    Article  Google Scholar 

  10. Takagi D, Homma Y et al (2006) Single-walled carbon nanotube growth from highly activated metal nanoparticles. Nano Lett 6:2642

    Article  Google Scholar 

  11. Yuan D, Ding L et al (2008) Horizontally aligned single-walled carbon nanotube on quartz from a large variety of metal catalysts. Nano Lett 8:2576

    Article  Google Scholar 

  12. Takagi D, Hibino H et al (2007) Carbon nanotube growth from semiconductor nanoparticles. Nano Lett 7:2272

    Article  Google Scholar 

  13. Liu H, Takagi D et al (2008) Growth of single-walled carbon nanotubes from ceramic particles by alcohol chemical vapor deposition. Appl Phys Express 1:014001

    Article  Google Scholar 

  14. Takagi D, Kobayashi Y, Homma Y (2009) Carbon nanotube growth from diamond. J Am Chem Soc 131:6922

    Article  Google Scholar 

  15. Yu X, Zhang J et al (2010) From opened C60 to single-walled carbon nanotubes. Nano Lett 10:3343

    Article  Google Scholar 

  16. Fan X, Buczko R et al (2003) Nucleation of single-walled carbon nanotubes. Phys Rev Lett 90:145501

    Article  Google Scholar 

  17. Raty JY, Gygi F et al (2005) Growth of carbon nanotubes on metal nanoparticles: a microscopic mechanism from ab initio molecular dynamics simulations. Phys Rev Lett 95:096103

    Article  Google Scholar 

  18. Ding F, Larsson P et al (2008) The importance of strong carbon-metal adhesion for catalytic nucleation of single-walled carbon nanotubes. Nano Lett 8:463

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yoshikazu Homma .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer Japan

About this chapter

Cite this chapter

Homma, Y. (2015). Carbon Nanotube Synthesis and the Role of Catalyst. In: Matsumoto, K. (eds) Frontiers of Graphene and Carbon Nanotubes. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55372-4_9

Download citation

  • DOI: https://doi.org/10.1007/978-4-431-55372-4_9

  • Published:

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-55371-7

  • Online ISBN: 978-4-431-55372-4

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics