Abstract
Various novel functions on photochromic surfaces have been attracting interest. Selective metal deposition on a photochromic diarylethene surface is one such function and signifies that metal vapor atoms are deposited on the colored surface but not on the uncolored surface. This chapter introduces the phenomena, origin, extension, and applications of selective metal deposition. The origin of selective metal deposition is in a large change in the glass transition temperature (T g) based on the photoisomerization of diarylethene. Low-T g uncolored surface with active molecular motion causes metal atom desorption from the surface. The selective metal deposition phenomenon can be extended to various aspects including organic crystal and polymer surfaces. We demonstrate the following applications of selective metal deposition: patterned cathode preparation for organic light-emitting devices, micro thin-film fuse, multifunctional diffraction grating, and metal vapor integration. Selective metal deposition is expected for applications in various electric and optic fields.
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References
Smith DL (1995) Thin-film deposition: principles & practice. McGraw-Hill, New York
Tsujioka T, Sesumi Y, Takagi R, Masui K, Yokojima S, Uchida K, Nakamura S (2008) Selective metal deposition on photo-switchable molecular surfaces. J Am Chem Soc 130:10740–10747
Tsujioka T, Sesumi Y, Yokojima S, Nakamura S, Uchida K (2009) Metal atom behavior on photochromic diarylethene surfaces-deposition rate dependence of selective Mg deposition. New J Chem 33:1335–1338
Tsujioka T, Dohi M (2012) Light-controlled selective Pb deposition on photochromic surfaces. Appl Phys Express 5:041603
Iwai Y, Tsujioka T (2011) Metal deposition selectivity based on photochromism of diarylethene film in intermediate vacuum. Jpn J Appl Phys 50:081602
Tsujioka T, Tsuji K (2012) Metal-vapor deposition modulation on soft polymer surfaces. Appl Phys Express 5:021601
Sesumi Y, Yokojima S, Nakamura S, Uchida K, Tsujioka T (2010) Light-controlled selective metal deposition on a photochromic diarylethene film – toward new applications in electronics and photonics. Bull Chem Soc Jpn 83:756–761
Mas-Torrent M, Durkut M, Hadley P, Ribas X, Rovira C (2004) High mobility of dithiophene-Âtetrathiafulvalene single-crystal organic field effect transistors. J Am Chem Soc 126:984–985
Anthony JE (2006) Functionalized acenes and heteroacenes for organic electronics. Chem Rev 106:5028–5048
Tsujioka T, Sasa T, Kakihara Y (2012) Nonvolatile organic memory based on isomerization of diarylethene molecules by electrical carrier injection. Org Electr 13:681–686
Tsujioka T, Kondo K (2003) Organic bistable molecular memory using photochromic diarylethene. Appl Phys Lett 83:937–939
Tsujioka T, Iefuji N, Jiapaer A, Irie M, Nakamura S (2006) Hole-injection isomerization of photochromic diarylethene for organic molecular memory. Appl Phys Lett 89:222102
Irie M (2000) Diarylethenes for memory and switches. Chem Rev 100:1685–1716
Tsujioka T, Shimizu Y, Irie M (1994) Crosstalk in photon-mode photochromic multi-Âwavelength recording. Jpn J Appl Phys 33:1914–1919
Tsujioka T (2011) Selective metal deposition on photosensitive organic crystal surfaces. J Mater Chem 21:12639–12643
Nakajima K, Yamaguchi H, Lee JC, Kageshima M, Ikehara T, Nishi T (1997) Nanorheology of polymer blends investigated by atomic force microscopy. Jpn J Appl Phys 36:3850–3854
Tsujioka T, Takagi R, Shiozawa T (2010) Light-controlled metal deposition on photochromic polymer films. J Mater Chem 20:9623–9627
Huang J, Su J-H, Tian H (2012) The development of anthracene derivatives for organic light-Âemitting diodes. J Mater Chem 22:10977–10989
Sun Y, Liu Y, Zhu D (2005) Advances in organic field-effect transistors. J Mater Chem 15:53–65
Masui K, Takagi R, Sesumi Y, Nakamura S, Tsujioka T (2009) Selective metal deposition for a structure with a thin intermediate layer on a photochromic diarylethene film. J Mater Chem 19:3176–3180
Takagi R, Masui K, Nakamura S, Tsujioka T (2008) Metal patterning using maskless vacuum evaporation process based on selective deposition of photochromic diarylethene. Appl Phys Lett 93:213304
Martin JE, Heaney MB (2000) Reversible thermal fusing model of carbon black current-Âlimiting thermistors. Phys Rev B 62:9390–9397
Tsujioka T, Matsui N (2012) Photoreprogrammable dual-function diffraction grating based on photochromism and selective metal deposition. Opt Lett 37:70–72
Tsujioka T, Matsui N (2011) Dual-functional diffraction grating based on selective metal deposition of photochromic diarylethene. Opt Lett 36:3648–3650
Tsujioka T, Matsui A (2009) Light-controlled selective metal deposition on photopolymer films. Appl Phys Lett 94:013302
Tsujioka T, Irie M (2010) Electrical functions of photochromic molecules. J Photochem Photobiol C: Photochem Rev 11:1–14
Tsujioka T, Yamamoto M, Shoji K, Tani K (2010) Efficient carrier separation from a photochromic diarylethene layer. Photochem Photobiol Sci 9:157–161
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Tsujioka, T. (2013). Selective Metal Deposition Based on Photochromism of Diarylethenes. In: Irie, M., Yokoyama, Y., Seki, T. (eds) New Frontiers in Photochromism. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54291-9_4
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DOI: https://doi.org/10.1007/978-4-431-54291-9_4
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