Skip to main content

Abstract

Thanks to variable structures and properties, dendrimers are attractive for catalytic applications. They can act as catalytically active species, as well as, soluble supports onto which catalytically active species can be attached. Different sorts of dendrimer-encapsulated nanoparticles are used both in homogeneous and in heterogeneous catalysis. Examples of dendrimeric catalysts and their applications in many sorts of reactions, including chiral dendrimer catalysts and enantioselectivity in catalysis are given. Chiral dendrimer catalysts with a high level of molecular monodispersity, well-defined catalytic sites, and structural regularity, can be prepared either by attachment of achiral complexes to chiral dendrimer structures or by immobilization of chiral catalysts to achiral dendrimers.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Albiter, M.A., Morales, R., Zaera, F.: Dendrimer-based synthesis of pt catalysts for hydrocarbon conversion. Appl. Catal. A 391(1–2), 386–393 (2011)

    CAS  Google Scholar 

  2. Astruc, D., Ornelas, C., Diallo, A.K., Ruiz, J.: Extremely efficient catalysis of carbon-carbon bond formation using “click” dendrimer-stabilized palladium nanoparticles. Molecules 15(7), 4947–4960 (2010)

    Article  PubMed  CAS  Google Scholar 

  3. Biswas, R., Maillard, N., Kofoed, J., Reymond, J.L.: Comparing dendritic with linear esterase peptides by screening spot arrays for catalysis. Chem. Commun. 46, 8746–8748 (2010)

    Article  CAS  Google Scholar 

  4. Dahan, A., Portnoy, M.: Dendrons and dendritic catalysts immobilized on solid support: synthesis and dendritic effects in catalysis. J. Polym. Sci. A 43(2), 235–262 (2005)

    Article  CAS  Google Scholar 

  5. Gatard, S., Liang, L., Salmon, L., Ruiz, J., Astruc, D., Bouquillon, S.: Water-soluble glycodendrimers: synthesis and stabilization of catalytically active Pd and Pt nanoparticles. Tetrahedron Lett. 52(16), 1842–1846 (2011)

    Article  CAS  Google Scholar 

  6. Hadad, C., Majoral, J.P., Muzart, J., Caminade, A.M., Bouquillon, S.: First phosphorous d-xylose-derived glycodendrimers. Tetrahedron Lett. 50(17), 1902–1905 (2009)

    Article  CAS  Google Scholar 

  7. Helms, B., Frechet, J.: The dendrimer effect in homogeneous catalysis. Adv. Synth. Catal. 348(10–11), 1125–1148 (2006)

    Article  CAS  Google Scholar 

  8. Jensen, A., Maru, B., Zhang, X., Mohanty, D., Fahlman, B., Swanson, D., Tomalia, D.: Preparation of fullerene-shell dendrimer-core nanoconjugates. Nano Lett. 5(6), 1171–1173 (2005)

    Article  PubMed  CAS  Google Scholar 

  9. Karakhanov, E., Maksimov, A., Runova, E., Kardasheva, Y., Terenina, M., Kardashev, S., Skorkin, V., Karapetyan, L., Talanova, M.: Design of supramolecular metal complex catalytic systems for petrochemical and organic synthesis. Russ. Chem. Bull. 57(4), 780–792 (2008)

    Article  CAS  Google Scholar 

  10. Kassube, J., Gade, L.: Stereoselective dendrimer catalysis. Top. Organometal. Chem. 20, 61–96 (2006)

    Article  CAS  Google Scholar 

  11. Kassube, J., Wadepohl, H., Gade, L.: Immobilisation of the binap ligand on dendrimers and hyper-branched polymers: dependence of the catalytic properties on the linker unit. Adv. Synth. Catal. 351(4), 607–616 (2009)

    Article  CAS  Google Scholar 

  12. Kehat, T., Goren, K., Portnoy, M.: Dendrons on insoluble supports: synthesis and applications. New J. Chem. 31(7), 1218–1242 (2007)

    Article  CAS  Google Scholar 

  13. King, A.S.H., Twyman, L.J.: Heterogeneous and solid supported dendrimer catalysts. J. Chem. Soc. Perkin. Trans. (20), 2209–2218 (2002)

    Article  Google Scholar 

  14. Liang, C., Frechet, J.: Applying key concepts from nature: transition state stabilization, pre-concentration and cooperativity effects in dendritic biomimetics. Prog. Polym. Sci. 30(3–4), 385–402 (2005)

    Article  CAS  Google Scholar 

  15. Lo, C.M., Chow, H.F.: Structural effects on the catalytic, emulsifying, and recycling properties of chiral amphiphilic dendritic organocatalysts. J. Org. Chem. 74(15), 5181–5191 (2009)

    Article  PubMed  CAS  Google Scholar 

  16. Maillard, N., Darbre, T., Reymond, J.L.: Identification of catalytic peptide dendrimers by “off-bead” in silica high-throughput screening of combinatorial libraries. J. Comb. Chem. 11(4), 667–675 (2009)

    Article  PubMed  CAS  Google Scholar 

  17. Newkome, G., Shreiner, C.: Poly(amidoamine), polypropylenimine, and related dendrimers and dendrons possessing different 1 → 2 branching motifs: an overview of the divergent procedures. Polymer 49(1), 1–173 (2008)

    Article  CAS  Google Scholar 

  18. Newkome, G.R., Shreiner, C.: Dendrimers derived from 1 → 3 branching motifs. Chem. Rev. 110(10), 6338–6442 (2010)

    Article  PubMed  CAS  Google Scholar 

  19. Niederhafner, P., Sebestik, J., Jezek, J.: Glycopeptide dendrimers. Part II. J. Pept. Sci. 14(1), 44–65 (2008)

    CAS  Google Scholar 

  20. Scholl, M., Kadlecova, Z., Klok, H.A.: Dendritic and hyperbranched polyamides. Prog. Polym. Sci. 34(1), 24–61 (2009)

    Article  CAS  Google Scholar 

  21. Sebestik, J., Niederhafner, P., Jezek, J.: Peptide and glycopeptide dendrimers and analogous dendrimeric structures and their biomedical applications. Amino Acids 40(2), 301–370 (2011)

    Article  PubMed  CAS  Google Scholar 

  22. Svenson, S.: Dendrimers. Kirk-Othmer Encyclop. Chem. Technol. 26, 786–812 (2007)

    CAS  Google Scholar 

  23. Van Dongen, S., De Hoog, H.P., Peters, R., Nallani, M., Nolte, R., Van Hest, J.: Biohybrid polymer capsules. Chem. Rev. 109(11), 6212–6274 (2009)

    Article  PubMed  Google Scholar 

  24. Witham, C., Huang, W., Tsung, C.K., Kuhn, J., Somorjai, G., Toste, F.: Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles. Nat. Chem. 2(1), 36–41 (2010)

    Article  PubMed  CAS  Google Scholar 

  25. Yan, N., Xiao, C., Kou, Y.: Transition metal nanoparticle catalysis in green solvents. Coord. Chem. Rev. 254(9–10, SI), 1179–1218 (2010)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer-Verlag Wien

About this chapter

Cite this chapter

Šebestík, J., Reiniš, M., Ježek, J. (2012). Dendrimers in Catalysis. In: Biomedical Applications of Peptide-, Glyco- and Glycopeptide Dendrimers, and Analogous Dendrimeric Structures. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1206-9_9

Download citation

Publish with us

Policies and ethics