Abstract
Thanks to variable structures and properties, dendrimers are attractive for catalytic applications. They can act as catalytically active species, as well as, soluble supports onto which catalytically active species can be attached. Different sorts of dendrimer-encapsulated nanoparticles are used both in homogeneous and in heterogeneous catalysis. Examples of dendrimeric catalysts and their applications in many sorts of reactions, including chiral dendrimer catalysts and enantioselectivity in catalysis are given. Chiral dendrimer catalysts with a high level of molecular monodispersity, well-defined catalytic sites, and structural regularity, can be prepared either by attachment of achiral complexes to chiral dendrimer structures or by immobilization of chiral catalysts to achiral dendrimers.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Albiter, M.A., Morales, R., Zaera, F.: Dendrimer-based synthesis of pt catalysts for hydrocarbon conversion. Appl. Catal. A 391(1–2), 386–393 (2011)
Astruc, D., Ornelas, C., Diallo, A.K., Ruiz, J.: Extremely efficient catalysis of carbon-carbon bond formation using “click” dendrimer-stabilized palladium nanoparticles. Molecules 15(7), 4947–4960 (2010)
Biswas, R., Maillard, N., Kofoed, J., Reymond, J.L.: Comparing dendritic with linear esterase peptides by screening spot arrays for catalysis. Chem. Commun. 46, 8746–8748 (2010)
Dahan, A., Portnoy, M.: Dendrons and dendritic catalysts immobilized on solid support: synthesis and dendritic effects in catalysis. J. Polym. Sci. A 43(2), 235–262 (2005)
Gatard, S., Liang, L., Salmon, L., Ruiz, J., Astruc, D., Bouquillon, S.: Water-soluble glycodendrimers: synthesis and stabilization of catalytically active Pd and Pt nanoparticles. Tetrahedron Lett. 52(16), 1842–1846 (2011)
Hadad, C., Majoral, J.P., Muzart, J., Caminade, A.M., Bouquillon, S.: First phosphorous d-xylose-derived glycodendrimers. Tetrahedron Lett. 50(17), 1902–1905 (2009)
Helms, B., Frechet, J.: The dendrimer effect in homogeneous catalysis. Adv. Synth. Catal. 348(10–11), 1125–1148 (2006)
Jensen, A., Maru, B., Zhang, X., Mohanty, D., Fahlman, B., Swanson, D., Tomalia, D.: Preparation of fullerene-shell dendrimer-core nanoconjugates. Nano Lett. 5(6), 1171–1173 (2005)
Karakhanov, E., Maksimov, A., Runova, E., Kardasheva, Y., Terenina, M., Kardashev, S., Skorkin, V., Karapetyan, L., Talanova, M.: Design of supramolecular metal complex catalytic systems for petrochemical and organic synthesis. Russ. Chem. Bull. 57(4), 780–792 (2008)
Kassube, J., Gade, L.: Stereoselective dendrimer catalysis. Top. Organometal. Chem. 20, 61–96 (2006)
Kassube, J., Wadepohl, H., Gade, L.: Immobilisation of the binap ligand on dendrimers and hyper-branched polymers: dependence of the catalytic properties on the linker unit. Adv. Synth. Catal. 351(4), 607–616 (2009)
Kehat, T., Goren, K., Portnoy, M.: Dendrons on insoluble supports: synthesis and applications. New J. Chem. 31(7), 1218–1242 (2007)
King, A.S.H., Twyman, L.J.: Heterogeneous and solid supported dendrimer catalysts. J. Chem. Soc. Perkin. Trans. (20), 2209–2218 (2002)
Liang, C., Frechet, J.: Applying key concepts from nature: transition state stabilization, pre-concentration and cooperativity effects in dendritic biomimetics. Prog. Polym. Sci. 30(3–4), 385–402 (2005)
Lo, C.M., Chow, H.F.: Structural effects on the catalytic, emulsifying, and recycling properties of chiral amphiphilic dendritic organocatalysts. J. Org. Chem. 74(15), 5181–5191 (2009)
Maillard, N., Darbre, T., Reymond, J.L.: Identification of catalytic peptide dendrimers by “off-bead” in silica high-throughput screening of combinatorial libraries. J. Comb. Chem. 11(4), 667–675 (2009)
Newkome, G., Shreiner, C.: Poly(amidoamine), polypropylenimine, and related dendrimers and dendrons possessing different 1 → 2 branching motifs: an overview of the divergent procedures. Polymer 49(1), 1–173 (2008)
Newkome, G.R., Shreiner, C.: Dendrimers derived from 1 → 3 branching motifs. Chem. Rev. 110(10), 6338–6442 (2010)
Niederhafner, P., Sebestik, J., Jezek, J.: Glycopeptide dendrimers. Part II. J. Pept. Sci. 14(1), 44–65 (2008)
Scholl, M., Kadlecova, Z., Klok, H.A.: Dendritic and hyperbranched polyamides. Prog. Polym. Sci. 34(1), 24–61 (2009)
Sebestik, J., Niederhafner, P., Jezek, J.: Peptide and glycopeptide dendrimers and analogous dendrimeric structures and their biomedical applications. Amino Acids 40(2), 301–370 (2011)
Svenson, S.: Dendrimers. Kirk-Othmer Encyclop. Chem. Technol. 26, 786–812 (2007)
Van Dongen, S., De Hoog, H.P., Peters, R., Nallani, M., Nolte, R., Van Hest, J.: Biohybrid polymer capsules. Chem. Rev. 109(11), 6212–6274 (2009)
Witham, C., Huang, W., Tsung, C.K., Kuhn, J., Somorjai, G., Toste, F.: Converting homogeneous to heterogeneous in electrophilic catalysis using monodisperse metal nanoparticles. Nat. Chem. 2(1), 36–41 (2010)
Yan, N., Xiao, C., Kou, Y.: Transition metal nanoparticle catalysis in green solvents. Coord. Chem. Rev. 254(9–10, SI), 1179–1218 (2010)
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2012 Springer-Verlag Wien
About this chapter
Cite this chapter
Šebestík, J., Reiniš, M., Ježek, J. (2012). Dendrimers in Catalysis. In: Biomedical Applications of Peptide-, Glyco- and Glycopeptide Dendrimers, and Analogous Dendrimeric Structures. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1206-9_9
Download citation
DOI: https://doi.org/10.1007/978-3-7091-1206-9_9
Published:
Publisher Name: Springer, Vienna
Print ISBN: 978-3-7091-1205-2
Online ISBN: 978-3-7091-1206-9
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)