Natural isotopic abundance: 0.992728.

Reference

[2012Bar]

Method

Fourier transform spectroscopy.

Equations

Equations 14, 15, and 16 in chapter “Introduction”.

Statistical errors

One standard deviation in units of the least significant full size digits.

Remarks

All values are given in cm−1.

Molecular constants determined in the same fit are given in chapter “16O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants for the (213), (114), (321), and for the Dark (080)* Vibrational States”.

Calculated constants are purposely given with a supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy.

The perturbing (080) vibrational state is supposed to be a dark state.

The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh].

Abbreviations

SE: Statistical error.

 

Coriolis type coupling parameters

Anharmonic type coupling parameters

 

<114|H|213>

 

<080|H|213>

  

<321|H|213>

 

Value

SE

Value

SE

 

Value

SE

C 011

−0.47863 × 10−2

31

−0.1027 × 10−3

19

F020

0.05065

16

C 031

  

−0.3136 × 10−4

18

F002

0.65500 × 10−3

76

C 211

−0.20126 × 10−5

49

−0.936 × 10−6

13

   

Symbols and abbreviations

Short form

Full form

C y , C yz

Coriolis coupling parameter

SE

Statistical error