Abstract
This chapter provides the Coriolis and anharmonic coupling parameters of the (114), (213), dark (080) and (321) interacting states of 16O3 measured using Fourier transform spectroscopy.
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Natural isotopic abundance: 0.992728.
Reference | [2012Bar] |
Method | Fourier transform spectroscopy. |
Equations | Equations 14, 15, and 16 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant full size digits. |
Remarks | All values are given in cm−1. Molecular constants determined in the same fit are given in chapter “16O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants for the (213), (114), (321), and for the Dark (080)* Vibrational States”. Calculated constants are purposely given with a supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy. The perturbing (080) vibrational state is supposed to be a dark state. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviations | SE: Statistical error. |
Coriolis type coupling parameters | Anharmonic type coupling parameters | ||||||
---|---|---|---|---|---|---|---|
<114|H|213> | <080|H|213> | <321|H|213> | |||||
Value | SE | Value | SE | Value | SE | ||
C 011 | −0.47863 × 10−2 | 31 | −0.1027 × 10−3 | 19 | F020 | 0.05065 | 16 |
C 031 | −0.3136 × 10−4 | 18 | F002 | 0.65500 × 10−3 | 76 | ||
C 211 | −0.20126 × 10−5 | 49 | −0.936 × 10−6 | 13 |
Symbols and abbreviations
Short form | Full form |
---|---|
C y , C yz | Coriolis coupling parameter |
SE | Statistical error |
References
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
Barbe, A., De Backer, M.R., Starikova, E., Tashkun, S.A., Thomas, X., and Tyuterev, V.G.: FTS high resolution spectra of 16O3 in 3500 and 5500 cm−1 regions. First example of new theoretical modelling for a polyad of strongly coupled states. J. Quant. Spectrosc. Radiat. Transfer. 113 (2012) 829–839.
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Guelachvili, G., Picqué, N. (2019). 16O3 Coriolis and Anharmonic Coupling Parameters of the (114), (213), Dark (080) and (321) Interacting States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_82
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DOI: https://doi.org/10.1007/978-3-662-57960-2_82
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
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