Abstract
This chapter provides the resonance coupling constants for the (223)-1, (dark4) and (dark5) interacting states of 18O16O18O measured using Fourier transform spectroscopy.
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Natural isotopic abundance: 4.19 × 10−6.
Reference | [2013Deb] |
Method | Fourier transform spectroscopy. |
Equations | Equations 19 and 24 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant full size digit. |
Remarks | All values are given in cm−1. Molecular constants determined in the same fit are given in chapter “18O16O18O Vibrational Energy and Rotational and Centrifugal Distortion Constants of the (223)-1 State in Interaction with the (dark4) and (dark5) States. Band Centers of the (2ν1 + 2ν2 + 3ν3)-1 and (dark4)–(000) and (dark5) –(000) Transitions”. Calculated constants are purposely given with one supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviation | SE: Statistical error. |
Parameter | <dark4|H|(223)-1> Value | SE |
|---|---|---|
C 011 | 0.001165 | 48 |
Parameter | <dark5|H|(223)-1> Value | SE |
|---|---|---|
F 002 | 0.0003826 | 41 |
Symbols and abbreviations
Short form | Full form |
|---|---|
C y , C yz | Coriolis coupling parameter |
SE | Statistical error |
References
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
De Backer, M.R., Barbe, A., Starikova, E., Tyuterev, V.G., Mondelain, D., Kassi, S., and Campargue, A.: The CW-CRDS spectra of the 16O/18O isotopologues of ozone between 5930 and 6340 cm−1—Part 3: 16O18O18O and 18O16O18O. J. Quant. Spectrosc. Radiat. Transfer. 127 (2013) 24–36.
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Guelachvili, G., Picqué, N. (2019). 18O16O18O Resonance Coupling Constants for the (223)-1, (dark4) and (dark5) Interacting States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_278
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DOI: https://doi.org/10.1007/978-3-662-57960-2_278
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
Online ISBN: 978-3-662-57960-2