Abstract
This chapter provides the dipole transition moment operator constants, integrated intensity for the ν1 and ν3 bands of 16O17O17O measured using Fourier transform spectroscopy.
You have full access to this open access chapter, Download chapter PDF
Similar content being viewed by others
Natural isotopic abundance: 2.88 × 10−7.
Reference | [] |
Method | Fourier transform spectroscopy. |
Equations | Equations 47, 52, and 53 in chapter “Introduction”. |
Remarks | The first order term moment operator constants, practically do not vary for the A- and B-type ν1 and ν3 bands with the isotopomer. The calculations of the line intensities have then been performed using the 16O3 values given in [87Fla2]. The integrated intensities are given in units of cm−1/molecule.cm−2 at 296 K. Their values correspond to the sum of their individual line intensities, calculated with a cut-off equal to 0.5 × 10−22 cm−1/molecule.cm−2 at 296 K. Band centers and vibrational energy and rotational and centrifugal distortion constants are given in chapter “16O17O17O Vibrational Energy and Rotational and Centrifugal Distortion Constants. Band Center for the ν1 and ν3 Bands”. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Band | Integrated intensity | Transformed dipole transition moment operators | Parameters |
|---|---|---|---|
ν 3 | 0.135 × 10−16 | ||
A-type band | φ Z | −0.188232 | |
ν 1 | |||
B-type band | 0.384 × 10−18 | φ X | −0.0154509 |
A-type band | 0.179 × 10−18 |
Symbols and abbreviations
Short form | Full form |
|---|---|
υ 1 υ 2 υ 3 | Upper vibrational level in normal mode notation |
SE | Statistical error |
References
Flaud, J.M., Camy-Peyret, C., Devi, V.M., Rinsland, C.P., and Smith, M.A.H.: The ν1 and ν3 bands of 16O3: Line positions and intensities. J. Mol. Spectrosc. 124 (1987) 209–217.
Perrin, A., Flaud, J.M., Valentin, A., Camy-Peyret, C., Gbaguidi, N., and N’Gom, A.: The ν1 and ν3 bands of the 16O17O17O isotopomer of ozone. J. Mol. Struct. 517–518 (2000) 157–163.
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer-Verlag GmbH Germany, part of Springer Nature
About this chapter
Cite this chapter
Guelachvili, G., Picqué, N. (2019). 16O17O17O Dipole Transition Moment Operator Constants, Integrated Intensity for the ν1 and ν3 Bands. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_197
Download citation
DOI: https://doi.org/10.1007/978-3-662-57960-2_197
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
Online ISBN: 978-3-662-57960-2