Abstract
This chapter provides the dipole transition moment operator constants and integrated intensity for the 4ν2 + 4ν3 B-type band of 16O3 measured using continuous wave–cavity ring down spectroscopy.
You have full access to this open access chapter, Download chapter PDF
Similar content being viewed by others
Natural isotopic abundance: 0.992728.
Reference | [2011Bar] |
Method | Continuous wave – cavity ring down spectroscopy. |
Equations | Equations 47 and 53 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant digits. |
Remarks | The integrated intensity is given in units of cm/molecule at 296 K. Statistical errors are given in parentheses. Calculated constants are purposely given with a supplementary digit, in index form, in order to reproduce the line intensities to experimental accuracy. The dipole transition moment parameters and their standard deviation are given in Debye. Spectroscopic parameters are given in chapter “16O3 Rotational and Centrifugal Distortion Constants for the (044) State. Band Center of the 4ν2 + 4ν3 Vibrational Transition”. The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviation | {A,B} = AB + BA |
Band | Integrated intensity | Transformed dipole transition moment operators | Parameters |
|---|---|---|---|
4ν2 + 4ν3 | 1.66 × 10−25 | φx × 105 | −0.1241 (24) |
B-type band | {φz, iJy} × 106 | 0.33071 (43) |
Symbols and abbreviations
Short form | Full form |
|---|---|
υ 1 υ 2 υ 3 | Upper vibrational level in normal mode notation |
J x ,J y ,J z | Molecule-fixed components of J |
SE | Statistical error |
References
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
Barbe, A., De Backer-Barilly, M.R., Tyuterev, V.G., Kassi, S., and Campargue, A.: Detection and analysis of new bands of 16O3 by CRDS between 6500 and 7300 cm−1. J. Mol. Spectrosc. 269 (2011) 175−186.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer-Verlag GmbH Germany, part of Springer Nature
About this chapter
Cite this chapter
Guelachvili, G., Picqué, N. (2019). 16O3 Dipole Transition Moment Operator Constants and Integrated Intensity for the 4ν2 + 4ν3 B-Type Band. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_113
Download citation
DOI: https://doi.org/10.1007/978-3-662-57960-2_113
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
Online ISBN: 978-3-662-57960-2