Abstract
Various pollutants have been emitted due to the development of industry, which can cause serious problems for the production of drinking water and threaten the health of human. Aquatic monitoring has attracted more and more attention and needs to be developed urgently for the analysis of trace pollutants from complex matrix. Solid-phase microextraction (SPME), as a solventless extraction technique, is applicable for both off-site and on-site sampling. Here, two general strategies for on-site SPME sampling, including active and passive sampling, are introduced in detail. The main formats for active sampling include fiber, thin film, and stir bar, while the reported formats for passive sampling are fiber, polydimethylsiloxane (PDMS) rod, PDMS membrane, and PDMS tubing. To obtain better determination effects of emerging contaminants, new adsorptive materials have been employed gradually instead of commercial adsorbents to achieve the targets of high enrichment efficiencies and short analysis time. All in all, the SPME samplers have been diversified and developed over the past decade to obtain more information about the pollution status of water environment all over the world.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
George MJ, Marjanovic L, Williams DBG (2015) Solvent-assisted headspace sampling using solid phase microextraction for the analysis of phenols in water. Anal Chem 87:9559–9562. doi:10.1021/acs.analchem.5b02539
Stevens ME Jr, Tipple CA, Smith PA et al (2013) Application of a high surface area solid-phase microextraction air sampling device: collection and analysis of chemical warfare agent surrogate and degradation compounds. Anal Chem 85:8626–8633. doi:10.1021/ac401033a
Bianchi F, Bedini A, Riboni N et al (2014) Cavitand-based solid-phase microextraction coating for the selective detection of nitroaromatic explosives in air and soil. Anal Chem 86:10646–10652. doi:10.1021/ac5025045
Risticevic S, Souza-Silva EA, DeEll JR et al (2016) Capturing plant metabolome with direct-immersion in vivo solid phase microextraction of plant tissues. Anal Chem 88:1266–1274. doi:10.1021/acs.analchem.5b03684
Zhou SN, Oakes KD, Servos MR et al (2008) Application of solid-phase microextraction for in vivo laboratory and field sampling of pharmaceuticals in fish. Environ Sci Technol 42:6073–6079. doi:10.1021/es8001162
Voice TC, Kolb B (1994) Comparison of European and American techniques for the analysis of volatile organic compounds in environmental matrices. J Chromatogr Sci 32:306–311. doi:10.1093/chromsci/32.8.306
Voice TC, Kolb B (1993) Static and dynamic headspace analysis of volatile organic compounds in soils. Environ Sci Technol 27:709–713. doi:10.1021/es00041a014
Richardson SD, Kimura SY (2016) Water analysis: emerging contaminants and current issues. Anal Chem 88:546–582. doi:10.1021/acs.analchem.5b04493
Qin Z, Bragg L, Ouyang G et al (2009) Solid-Phase microextraction under controlled agitation conditions for rapid on-site sampling of organic pollutants in water. J Chromatogr A 1216:6979–6985. doi:10.1016/j.chroma.2009.08.052
Huang S, He S, Xu H et al (2015) Monitoring of persistent organic pollutants in seawater of the pearl river estuary with rapid on-site active SPME sampling technique. Environ Pollut 200:149–158. doi:10.1016/j.envpol.2015.02.016
Basheer C, Balaji G, Chua SH et al (2011) Novel on-site sample preparation approach with a portable agitator using functional polymer-coated multi-fibers for the microextraction of organophosphorus pesticides in seawater. J Chromatogr A 1218:654–661. doi:10.1016/j.chroma.2010.12.033
Kermani FR, Pawliszyn J (2012) Sorbent coated glass wool fabric as a thin film microextraction device. Anal Chem 84:8990–8995. doi:10.1021/ac301861z
Deng Z, Chen X, Wang Y et al (2015) Headspace thin-film microextraction coupled with surface-enhanced raman scattering as a facile method for reproducible and specific detection of sulfur dioxide in wine. Anal Chem 87:633–640. doi:10.1021/ac503341g
Bragg L, Qin Z, Pawliszyn J (2006) Field sampling with a polydimethylsiloxane thin-film. J Chromatogr Sci 44:317–323. doi:10.1093/chromsci/44.6.317
Ouyang G, Zhao W, Bragg L et al (2007) Time-weighted average water sampling in lake Ontario with solid-phase microextraction passive samplers. Environ Sci Technol 11:4026–4031. doi:10.1021/es062647a
Jiang R, Pawliszyn J (2014) Preparation of a particle-loaded membrane for trace gas sampling. Anal Chem 86:403–410. doi:10.1021/ac4035339
Qin Z, Bragg L, Ouyang G et al (2008) Comparison of thin-film microextraction and stir bar sorptive extraction for the analysis of polycyclic aromatic hydrocarbons in aqueous samples with controlled agitation conditions. J Chromatogr A 1196:89–95. doi:10.1016/j.chroma.2008.03.063
Grandy JJ, Boyaci E, Pawliszyn J (2016) Development of a carbon mesh supported thin film microextraction membrane as a means to lower the detection limits of benchtop and portable GC/MS instrumentation. Anal Chem 88:1760–1767. doi:10.1021/acs.analchem.5b04008
Baltussen E, Sandra P, David F et al (1999) Stir bar sorptive extraction (SBSE), a novel extraction technique for aqueous samples: theory and principles. J Microcolumn Sep 11:737–747. doi:10.1002/(SICI)1520-667X(1999)11:10<737::AID-MCS7>3.0.CO;2-4
Gomez MJ, Herrera S, Sole D et al (2011) Automatic searching and evaluation of priority and emerging contaminants in wastewater and river water by stir bar sorptive extraction followed by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry. Anal Chem 83:2638–2647. doi:10.1021/ac102909g
Soini HA, Bruce KE, Klouckova I et al (2006) In situ surface sampling of biological objects and preconcentration of their volatiles for chromatographic analysis. Anal Chem 78:7161–7168. doi:10.1021/ac0606204
Benede JL, Chisvert A, Giokas DL et al (2016) Determination of ultraviolet filters in bathing waters by stir bar sorptive-dispersive microextraction coupled to thermal desorption-gas chromatography-mass spectrometry. Talanta 47:246–252. doi:10.1016/j.talanta.2015.09.054
Benet I, Ibanez C, Guardia MD et al (2015) Optimisation of stir-bar sorptive extraction (SBSE), targeting medium and long-chain free fatty acids in cooked ham exudates. Food Chem 185:75–83. doi:10.1016/j.foodchem.2015.03.102
Zhang W, Zhang Z, Zhang J et al (2014) Covalent immobilization of graphene onto stainless steel wire for jacket-free stir bar sorptive extraction. J Chromatogr A 1351:12–20. doi:10.1016/j.chroma.2014.05.038
Bratkowska D, Fontanals N, Cormack PA et al (2012) Preparation of a polar monolithic stir bar based on methacrylic acid and divinylbenzene for the sorptive extraction of polar pharmaceuticals from complex water samples. J Chromatogr A 1225:1–7. doi:10.1016/j.chroma.2011.12.064
Hu C, He M, Chen B et al (2015) Simultaneous determination of polar and apolar compounds in environmental samples by a polyaniline/hydroxyl multi-walled carbon nanotubes composite-coated stir bar sorptive extraction coupled with high performance liquid chromatography. J Chromatogr A 1394:36–45. doi:10.1016/j.chroma.2015.03.046
Zhou Q, Qian Y, Qian MC (2015) Analysis of volatile phenols in alcoholic beverage by ethylene glycol-polydimethylsiloxane based stir bar sorptive extraction and gas chromatography-mass spectrometry. J Chromatogr A 1390:22–27. doi:10.1016/j.chroma.2015.02.064
Zhang Z, Zhang W, Bao T et al (2015) Jacket-free stir bar sorptive extraction with bio-inspired polydopamine-functionalized immobilization of cross-linked polymer on stainless steel wire. J Chromatogr A 1407:1–10. doi:10.1016/j.chroma.2015.06.031
Mao X, Hu B, He M et al (2012) Stir bar sorptive extraction approaches with a home-made portable electric stirrer for the analysis of polycyclic aromatic hydrocarbon compounds in environmental water. J Chromatogr A 1260:16–24. doi:10.1016/j.chroma.2012.08.062
Xing R, Hu S, Chen X et al (2015) On-site sampling and sample-preparation approach with a portable sampler based on hollow-fiber/graphene bars for the microextraction of nitrobenzene compounds in lake water. J Sep Sci 38:368–373. doi:10.1002/jssc.201401129
Schwarzenbach RP, Egli T, Hofstetter TB et al (2010) Global water pollution and human health. Annu Rev Environ Resour 35:109–136. doi:10.1146/annurev-environ-100809-125342
Houtman CJ (2010) Emerging contaminants in surface waters and their relevance for the production of drinking water in Europe. J Integr Environ Sci 7:271–295. doi:10.1080/1943815X.2010.511648
Mackay D, Paterson S (1991) Evaluating the multimedia fate of organic chemicals: a level III fugacity model. Environ Sci Technol 25:427–436. doi:10.1021/es00015a008
Escher BI, Hermens JLM (2004) Peer reviewed: internal exposure: linking bioavailability to effects. Environ Sci Technol 38:455–462. doi:10.1021/es0406740
Cornelissen G, Pettersen A, Broman D et al (2008) Field testing of equilibrium passive samplers to determine freely dissolved native polycyclic aromatic hydrocarbon concentrations. Environ Toxicol Chem 27:499–508. doi:10.1897/07-253.1
Wang F, Chen Y, Hermens JLM et al (2013) Evaluation of passive samplers with neutral or ion-exchange polymer coatings to determine freely dissolved concentrations of the basic surfactant lauryl diethanolamine: measurements of acid dissociation constant and organic carbon-water sorption coefficient. J Chromatogr A 1315:8–14. doi:10.1016/j.chroma.2013.09.041
Zhao WN, Ouyang GF, Alaee M et al (2006) On-rod standardization technique for time-weighted average water sampling with a polydimethylsiloxane rod. J Chromatogr A 1124:112–120. doi:10.1016/j.chroma.2006.05.062
Duan CF, Shen Z, Wu DP et al (2011) Recent developments in solid-phase microextraction for on-site sampling and sample preparation. Trend Anal Chem 30:1568–1574. doi:10.1016/j.trac.2011.08.005
Fernandez LA, Lao WJ, Maruya KA et al (2012) Passive sampling to measure baseline dissolved persistent organic pollutant concentrations in the water column of the Palos Verdes shelf superfund site. Environ Sci Technol 46:11937–11947. doi:10.1021/es302139y
Perron MM, Burgess RM, Suuberg EM et al (2013) Performance of passive samplers for monitoring estuarine water column concentrations: 2. Emerging contaminants. Environ Toxicol Chem 32:2190–2196. doi:10.1002/etc.2248
Perron MM, Burgess RM, Suuberg EM et al (2013) Performance of passive samplers for monitoring estuarine water column concentrations: 1. Contaminants of concern. Environ Toxicol Chem 32:2182–2189. doi:10.1002/etc.2321
Mäenpää K, Leppänen MT, Figueiredo K et al (2015) Fate of polychlorinated biphenyls in a contaminated lake ecosystem: combining equilibrium passive sampling of sediment and water with total concentration measurements of biota. Environ Toxicol Chem 34:2463–2474. doi:10.1002/etc.3099
Lao WJ, Maruya KA, Tsukada D (2012) A two-component mass balance model for calibration of solid-phase microextraction fibers for pyrethroids in seawater. Anal Chem 84:9362–9369. doi:10.1021/ac302120m
Hawthorne SB, Grabanski CB, Miller DJ et al (2009) Solid-phase-microextraction measurement of 62 polychlorinated biphenyl congeners in milliliter sediment pore water samples and determination of KDOC values. Anal Chem 81:6936–6943. doi:10.1021/ac901001j
Vrana B, Popp P, Paschke A et al (2001) Membrane-enclosed sorptive coating. An integrative passive sampler for monitoring organic contaminants in water. Anal Chem 73:5191–5200. doi:10.1021/ac010630z
Haftka JJH, Scherpenisse P, Jonker MTO et al (2013) Using polyacrylate-coated SPME fibers to quantify sorption of polar and ionic organic contaminants to dissolved organic carbon. Environ Sci Technol 47:4455–4462. doi:10.1021/es400236a
Alvarez DA, Maruya KA, Dodder NG et al (2014) Occurrence of contaminants of emerging concern along the california coast (2009–2010) using passive sampling devices. Mar Pollut Bull 81:347–354. doi:10.1016/j.marpolbul.2013.04.022
Burgess RM, Lohmann R, Schubauer-Berigan JP et al (2015) Application of passive sampling for measuring dissolved concentrations of organic contaminants in the water column at three marine superfund sites. Environ Toxicol Chem 34:1720–1733. doi:10.1002/etc.2995
Zeng E, Tsukada D, Diehl AW (2004) Development of a solid-phase microextraction-based method for sampling of persistent chlorinated hydrocarbons in an urbanized coastal environment. Environ Sci Technol 38:5737–5743. doi:10.1021/es049680m
Busser FJM, Hermens JLM (2008) Poly(dimethylsiloxane) as passive sampler material for hydrophobic chemicals: effect of chemical properties and sampler characteristics on partitioning and equilibration times. Anal Chem 80:3859–3866. doi:10.1021/ac800258j
Ouyang GF, Chen Y, Pawliszyn J (2005) Time-weighted average water sampling with a solid-phase microextraction device. Anal Chem 77:7319–7325. doi:10.1021/ac051035q
Ouyang GF, Cui SF, Qin ZP et al (2009) One-calibrant kinetic calibration for on-site water sampling with solid-phase microextraction. Anal Chem 81:5629–5636. doi:10.1021/ac900315w
Ouyang GF, Zhao WN, Bragg L et al (2007) Time-weighted average water sampling in lake Ontario with solid-phase microextraction passive samplers. Environ Sci Technol 41:4026–4031. doi:10.1021/es062647a
Oemisch L, Goss KU, Endo S (2013) Determination of oil–water partition coefficients of polar compounds: silicone membrane equilibrator vs. SPME Passive Sampler. Anal Bioanal Chem 405:2567–2574. doi:10.1007/s00216-012-6689-9
Fernandez LA, Lao WJ, Maruya KA et al (2014) Calculating the diffusive flux of persistent organic pollutants between sediments and the water column on the Palos Verdes shelf superfund site using polymeric passive sampler. Environ Sci Technol 48:3925–3934. doi:10.1021/es404475c
Chen Y, Koziel JA, Pawliszyn J (2003) Calibration for On-site analysis of hydrocarbons in aqueous and gaseous samples using solid-phase microextraction. Anal Chem 75:6485–6493. doi:10.1021/ac0349328
Chen Y, Pawliszyn J (2004) Kinetics and the on-site application of standards in a solid-phase microextration fiber. Anal Chem 76:5807–5815. doi:10.1021/ac0495081
Ouyang G, Cai J, Zhang X et al (2008) Standard-free kinetic calibration for rapid on-site analysis by solid-phase microextraction. J Sep Sci 31:1167–1172. doi:10.1002/jssc.200700495
Ouyang G, Cui S, Qin Z et al (2009) One-Calibrant kinetic calibration for on-site water sampling with solid-phase microextraction. Anal Chem 81:5629–5636. doi:10.1021/ac900315w
Acknowledgement
We acknowledge financial support from the projects of NNSFC (Grants 21225731, 21377172, and 21477166) and the NSF of Guangdong Province (Grant S2013030013474).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2017 Springer-Verlag GmbH Germany
About this chapter
Cite this chapter
Huang, S., Zheng, J., Ouyang, G. (2017). Application of Solid Phase Microextraction in Aqueous Sampling. In: Ouyang, G., Jiang, R. (eds) Solid Phase Microextraction. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-53598-1_5
Download citation
DOI: https://doi.org/10.1007/978-3-662-53598-1_5
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-53596-7
Online ISBN: 978-3-662-53598-1
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)