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Carbon Dioxide Capture in Porous Aromatic Frameworks

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Porous Materials for Carbon Dioxide Capture

Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

Abstract

Porous solids have been proved to be good candidates as the carbon dioxide recycling sorbents. In the last decades, many efforts were devoted to improving the surface area and heat of adsorption of artificial porous materials. Among those synthesized porous solids with ultrahigh surface area, porous aromatic frameworks (PAFs) possess ultrahigh Brunauer–Emmett–Teller (BET) surface area and excellent physicochemical stability, which can meet the criteria of carbon dioxide storage and separation. PAFs are the new generation of a whole new class of organic networks with an intrinsic nanoporosity. They are characterized by a rigid aromatic open-framework structure constructed by covalent bonds that remain accessible to small molecules. In this chapter, the design, synthesis, and carbon dioxide adsorption properties of PAFs are discussed.

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Authors and Affiliations

  1. Department of Chemistry, Jilin University, Changchun, Jilin, People’s Republic of China

    Teng Ben

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, People’s Republic of China

    Shilun Qiu

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  1. Teng Ben
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  1. School of Chemical Engineering, Dalian University of Technology State Key Laboratory of Fine Chemicals, Dalian, China

    An-Hui Lu

  2. Chemical Sci. Division, Oak Ridge National Lab, Oak Ridge, Tennessee, USA

    Sheng Dai

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Ben, T., Qiu, S. (2014). Carbon Dioxide Capture in Porous Aromatic Frameworks. In: Lu, AH., Dai, S. (eds) Porous Materials for Carbon Dioxide Capture. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54646-4_4

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