Abstract
A layout of a resonant photoelectron diffraction, RESPED, experiment is described from the theoretical basis to the data acquisition and analysis procedures. The theory of the resonance between the directly emitted photoelectron of a selected valence band and the electron emitted by autoionization (Auger) of the same valence band is presented within a formal frame. The critical issue of the angular symmetry and distribution of the resonating electron is discussed in connection with the current computational protocols for photoelectron diffraction, PED, analysis. A few representative applications are presented, where RESPED is shown to overcome some limitations of conventional PED thanks to the possibility of enhancing the signal of low concentration species, providing a chemical selectivity in the valence band, and discriminating the contribution from atoms of the same species, but in different structural environments or valence state.
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Verdini, A., Krüger, P., Floreano, L. (2013). Resonant Photoelectron Diffraction. In: Bracco, G., Holst, B. (eds) Surface Science Techniques. Springer Series in Surface Sciences, vol 51. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-34243-1_8
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