Abstract
Calcium oxide is one of the major fluxing agents used for steel refining. Because unreacted CaO remains in slag in most cases, discharged slag is difficult to be recycled smoothly. With the growth of environmental concerns, improving utilization efficiency of CaO is required to reduce the amount of discharged slag and energy consumption. The authors have reported a resource and energy-saving process by using multi-phase flux for dephosphorization. Reaction behavior of phosphorus in multi-phase CaO–FeOX–SiO2–P2O5 flux system was investigated. Formation mechanism of P2O5-rich phases was clarified at the interface between solid CaO or 2CaO·SiO2 and molten CaO–FeOx–SiO2–P2O5 slag. Phase relationship and thermodynamic properties of 2CaO·SiO2-3CaO·P2O5 solid solution were observed to confirm the condensation of P2O5 in solid phase. Based on these results, reduction of CaO consumption, discharged slag curtailment, and energy-saving effects in the novel refining process by using multi-phase flux were discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Suito H, Hayashida Y, Takahashi Y (1977) Mineralogical study of LD converter slags. Tetsu-to-Hagane 63(8):1252–1259
Ono H, Matsui T, Mori H (1983) Dephosphorization kinetics of hot metal by lime injection with oxygen gas. Tetsu-to-Hagane 69(15):1763–1770
Inoue R, Suito H (2006) Phosphorous partition between 2CaO·SiO2 particles and CaO-SiO2-FetO slags. ISIJ Int 46(2):174–179
Hamano T, Fukagai S, Tsukihashi F (2006) Reaction mechanism between solid CaO and FeOx-CaO-SiO2-P2O5 Slag at 1573 K. ISIJ Int 46(4):490–495
Fukagai S, Hamano T, Tsukihashi F (2007) Formation reaction of phosphate compound in multi phase flux at 1573 K. ISIJ Int 47(1):187–189
Saito R, Matsuura H, Nakase K, Yang X, Tsukihashi F (2009) Microscopic formation mechanisms of P2O5-containing phase at the interface between solid CaO and molten slag. Tetsu-to-Hagane 95(3):258–267
Yang X, Matsuura H, Tsukihashi F (2009) Formation behavior of phosphorous compounds at the interface between solid 2CaO·SiO2 and FeOx-CaO-SiO2-P2O5 Slag at 1673K. Tetsu-to-Hagane 95(3):268–274
Yang X, Matsuura H, Tsukihashi F (2009) Condensation of P2O5 at the interface between 2CaO·SiO2 and CaO-SiO2-FeOx-P2O5 slag. ISIJ Int 49(9):1298–1307
Yang X, Matsuura H, Tsukihashi F (2010) Reaction behavior of P2O5 at the interface between solid 2CaO·SiO2 and liquid CaO-SiO2-FeOx-P2O5 slags saturated with solid 5CaO·SiO2·P2O5 at 1573 K. ISIJ Int 50(5):702–711
Yang X, Matsuura H, Tsukihashi F (2010) Dissolution behavior of solid 5CaO·SiO2·P2O5 in CaO-SiO2-FeOx slag. Mater Trans 51(6):1094–1101
Gao X, Matsuura H, Sohn II, Wang W, Min DJ, Tsukihashi F (2012) Phase relationship of CaO-SiO2-FeO-5 mass pct P2O5 system with low oxygen partial pressure at 1673 K (1400 °C). Metall Mater Trans B 43(4):694–702
Gao X, Matsuura H, Sohn II, Wang W, Min DJ, Tsukihashi F (2013) Phase relationship for the CaO-SiO2-FeO-5 mass%P2O5 system with oxygen partial pressure of 10-8 atm at 1673 K and 1623 K. Mater Trans 54(4):544–552
Gao X, Matsuura H, Miyata M, Tsukihashi F (2013) Phase equilibrium for the CaO–SiO2–FeO–5mass% P2O5–5 mass%Al2O3 system for dephosphorization of hot metal pretreatment. ISIJ Int 53(8):1381–1385
Zhong M, Matsuura H, Tsukihashi F (2015) Activity of P2O5 in solid solution between di-calcium silicate and tri-calcium phosphate at 1823 and 1873 K. ISIJ Int 55(11):2283–2288
Zhong M, Matsuura H, Tsukihashi F (2015) Activity of phosphorus pentoxide and tri-calcium phosphate in 2CaO·SiO2-3CaO·P2O5 solid solution saturated with CaO. Mater Trans 55(8):1192–1198
Zhong M, Matsuura H, Miyata M, Tsukihashi F (2016) Thermodynamic properties of phosphorus oxide in the 2CaO·SiO2-3CaO·P2O5 solid solution saturated with MgO. Metall Mater Trans B 47(3):1745–1752
Matsuura H, Hamano T, Zhong M, Gao X, Zhong M, Tsukihashi F (2014) Energy and resource saving of steelmaking process: utilization of innovative multi-phase flux during dephosphorization process. JOM 66(9):1572–1580
Fix W, Heymann H, Heinke R (1969) Subsolidus relations in the system 2CaO·SiO2-3CaO·P2O5. J Am Ceram Soc 52(6):346–347
Kimura H, Ogawa T, Kakiki M, Matsumoto A, Tsukihashi F (2005) Effect of Al2O3 and MgO additions on liquidus for the CaO-SiO2-FeOx system at 1573 K. ISIJ Int 45(4):506–512
Eisenhüttenleute VD (ed) (1995) Slag atlas, 2nd edn. Verlag Stahleisen GmbH, Düsseldorf
Turkdogan ET (2000) Assessment of P2O5 activity coefficients in molten slags. ISIJ Int 40(10):964–970
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Yang, X., Matsuura, H., Tsukihashi, F. (2018). Reaction Behavior of Phosphorus in Multi-phase CaO–FeOX–SiO2–P2O5 Flux System. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_61
Download citation
DOI: https://doi.org/10.1007/978-3-319-95022-8_61
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-95021-1
Online ISBN: 978-3-319-95022-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)