Abstract
The chalcopyrite -molybdenite (Cu-Mo ) flotation industry is increasingly turning to organic depressants as suitable replacements for inorganic reagents, such as NaHS, due to environmental and safety concerns as well as high consumption rates of the inorganic reagents. This presents an opportunity for improvements or design and synthesis of alternative reagents. Disodium carboxymethyl trithiocarbonate (Orfom® D8) depressant is an organic depressant with a carboxylate group on one end and a trithiocarbonate group at the other end. Fundamental results are shown regarding the interaction of the Orfom® D8 depressant in the bulk flotation of a Cu-Mo concentrate from an operating North American mine. Cyclic Voltammetry on pure copper and Fourier Transform Infrared Spectroscopy (FT-IR ) and X-ray Photoelectron Spectroscopy (XPS) measurements on pure chalcopyrite with Orfom® D8 depressant treatment are also reported. Through such characterization techniques a potential adsorption mechanism of Orfom® D8 on the mineral surface was identified and its depressant characteristics in the Cu-Mo flotation systems explained.
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Acknowledgements
The authors acknowledge the help of Dr. Richard LaDouceur, Ethan Baily, Skylar Dickson and Conner Windmueller in running the experiments. We are also thankful to Chevron Philips Chemical Company (CPChem) for sponsoring the research. The views and conclusions contained in this document are those of the authors and should not be interpreted as representing the official guidelines or policies, either expressed or implied of CPChem.
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Timbillah, S., Young, C., Das, A. (2018). A Fundamental Study of Disodium Carboxymethyl Trithiocarbonate (Orfom® D8) in Flotation Separation of Copper-Molybdenum Sulfides. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_247
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