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Rare-Earth Elements Recovery from Nd-Fe-B Hard Magnets by Hydrometallurgical Processes

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Extraction 2018

Abstract

In this study, a hydrometallurgical process was evaluated for the recovery of Nd from a Nd-Fe-B magnet. Each leaching test was performed at the solid (weight) to liquid (volume) ratio of 1:50 and was mixed at 400 rpm at ambient temperature . The effects of 3 different acids (HCl, HNO3, and H2SO4) on the extraction of Nd were investigated and H2SO4 was found to be more effective than other acid solutions. Under the optimal conditions, pregnant leach solution was produced with H2SO4 for subsequent Nd precipitation testing . Each precipitation test was carried out using 100 mL of feed solution mixed at 600 rpm at 25 °C. NaOH and H2C2O4 were used for Nd precipitation . The highest Nd was precipitated as Nd2(C2O4)3·10H2O with C2H2O4 at 20 min.

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References

  1. Humphries M (2013) Rare earth elements: the global supply chain: Congressional Research Service Washington, DC

    Google Scholar 

  2. Binnemans K, Jones PT, Blanpain B, Van Gerven T, Yang Y, Walton A, Buchert M (2013) Recycling of rare earths: a critical review. J Clean Prod 51:1–22

    Article  CAS  Google Scholar 

  3. Deloitte Sustainability BGS, Bureau de Recherches Geologiques et Minieres, Netherlands Organisation for Applied Scientific Research (2017) Study on the review of the list of critical raw materials. Brussels

    Google Scholar 

  4. Alonso E, Sherman AM, Wallington TJ, Everson MP, Field FR, Roth R, Kirchain RE (2012) Evaluating rare earth element availability: a case with revolutionary demand from clean technologies. Environ Sci Technol 46(6):3406–3414

    Article  CAS  Google Scholar 

  5. Miura K, Itoh M, Machida K-I (2008) Extraction and recovery characteristics of Fe element from Nd–Fe–B sintered magnet powder scrap by carbonylation. J Alloy Compd 466(1–2):228–232

    Article  CAS  Google Scholar 

  6. Yoon H-S, Kim C-J, Chung KW, Jeon S, Park I, Yoo K, Jha MK (2015) The effect of grinding and roasting conditions on the selective leaching of Nd and Dy from NdFeB magnet scraps. Metals 5(3):1306–1314

    Article  CAS  Google Scholar 

  7. Vander Hoogerstraete T, Blanpain B, Van Gerven T, Binnemans K (2014) From NdFeB magnets towards the rare-earth oxides: a recycling process consuming only oxalic acid. RSC Advances 4(109):64099–64111

    Article  CAS  Google Scholar 

  8. Itakura T, Sasai R, Itoh H (2006) Resource recovery from Nd–Fe–B sintered magnet by hydrothermal treatment. J Alloy Compd 408:1382–1385

    Article  Google Scholar 

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Correspondence to Murat Alkan .

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Güneş, H., Obuz, H.E., Oğur, E., Çapraz, F., Alkan, M. (2018). Rare-Earth Elements Recovery from Nd-Fe-B Hard Magnets by Hydrometallurgical Processes. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_239

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