Skip to main content

Extraction of Lithium from Brine—Old and New Chemistry

  • Conference paper
  • First Online:
Extraction 2018

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

Conventionally, lithium -bearing brines are processed via solar evaporation , chemical purification , and either electrolysis to lithium hydroxide or precipitation of lithium carbonate. Lithium -ion battery technology and electric vehicles are forecast to greatly increase the demand for lithium , but not all lithium -bearing brines are amenable to the conventional extraction process and new approaches are being developed. The chemistry associated with conventional lithium extraction is outlined and two new approaches are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 249.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Garrett DE (2004) Handbook of lithium and natural calcium chloride. Their deposits, processing, uses and properties. Elsevier Academic Press. ISBN 0-12-276152-9

    Google Scholar 

  2. Hocking M, Kan J, Young P, Terry C, Begleiter D (2016) Deutsche Bank, Markets Research. Lithium 101, 9 May 2016. https://www.slideshare.net/Tehama/welcome-to-the-lithium-ion-age-lithium-101-deutsche-bank-may-9-2016

  3. Sato Y, Qin Y, Zheng Z, Kobayashi T, Yamamura T (2018) Electrowinning of metallic lithium from molten salts. www.electrochem.org/dl/ma/201/pdfs/1468.pdf. Accessed Apr 2018

  4. Boryta D (1981) Removal of boron from lithium chloride brine. US Patent 4,261,960, Apr 1981

    Google Scholar 

  5. LithiumAmericas (2017) Ni 43-101 Technical report. Reserve estimation and lithium carbonate production at the cauchari-olaroz salars, Jujuy Province, Argentina, 11 May 2017

    Google Scholar 

  6. ASX Media Release (2013) Galaxy Resources, 12 April 2013. Sal de vida definitive feasibility study supports low cost, long life lithium and potash production. https://stream1.newswire.ca/media/2013/04/11/20130411_C4655_DOC_EN_25468.pdf. Accessed Apr 1018

  7. Amouzegar et al (2000) Process for the purification of lithium carbonate. US Patent 6,048,507, 11 Apr 2000

    Google Scholar 

  8. Lithium Americas (2012) NI 43-101 Technical report. Feasibility study, reserve estimation and lithium carbonate and potash production at the cauchari-olaroz salars, Jujuy Province, Argentina, 11 July 2012

    Google Scholar 

  9. https://www.statista.com/statistics/606350/battery-grade-lithium-carbonate-price/. Accessed 19 Apr 2018

  10. Pure Energy Minerals (2017) Ni 43-101 Technical report. Clayton Valley lithium project, Esmerelda County, Nevada, 8 Aug 2017

    Google Scholar 

  11. Lee DA, Taylor WL, McDowell WJ, Drury JS (1968) Solvent extraction of lithium. J Inorg Nucl Chem 30:2807–2821 (Pergamon Press)

    Article  CAS  Google Scholar 

  12. Chen C-W, Chen P-A, Wei C-J, Huang H-L, Jou C-J, Wei Y-L, Wang PH (2017) Lithium recovery with LiTi2O4 ion-sieves. Mar Pollut Bull 124:1106–1110

    Article  CAS  Google Scholar 

  13. Tang D, Zhou D, Zhou J, Zhang P, Zhang L, Xia Y (2015) Preparation of HTiO-lithium adsorbent using low-grade titanium slag. Hydrometallurgy 157:90–96

    Article  CAS  Google Scholar 

  14. Limjuco LA, Nisola GM, Lawagon CP, Lee S-P, Seo J G, Kim H, Chung W-J (2016) H2TiO3 composite adsorbent foam for efficient and continuous recovery of Li+ from liquid resources. Colliods Surf A Physiochem Eng Asp 504:267–279

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mike Dry .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2018 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Dry, M. (2018). Extraction of Lithium from Brine—Old and New Chemistry. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-95022-8_187

Download citation

Publish with us

Policies and ethics