Abstract
Molecular aggregates – the assemblies of dye molecules-possess distinct optical characteristics as compared to their constituent monomeric units. Strong resonant interactions between the molecular electronic transitions of the monomers result in an intense and narrow absorption band at a frequency that depends on the relative orientation of the monomers within the aggregates. The strong absorption bands of these materials makes them attractive for a range of optoelectronic applications. We review the experimental and computational work dedicated to the determination of the optical dielectric functions of molecular aggregates, with an outlook to applications in device engineering.
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References
F. Würthner, T.E. Kaiser, C.R. Saha-Möller, Angew. Chem. Int. Ed. 50, 3376 (2011)
S.K. Saikin, A. Eisfeld, S. Valleau, A. Aspuru-Guzik, Nanophotonics 2, 21 (2013)
R.C. Benson, H.A. Kues, J. Chem. Eng. Data 22, 379 (1977)
A. Mishra, R.K. Behera, P.K. Behera, B.K. Mishra, G.B. Behera, Chem. Rev. 100, 1973 (2000)
T. Kobayashi (ed.), J-Aggregates (World Scientific, Singapore, 1996)
B.I. Shapiro, Russ. Chem. Rev. 63, 231 (1994)
Q. Wang, Z. Li, D.-D. Tao, Q. Zhang, P. Zhang, D.-P. Guo, Y.-B. Jiang, Chem. Commun. 52, 12929 (2016)
W. Liang, S. He, J. Fang, Langmuir 30, 805 (2014)
C. Curutchet, B. Mennucci, Chem. Rev. 117, 294 (2017)
T.P. Osedach, A. Iacchetti, R.R. Lunt, T.L. Andrew, P.R. Brown, G.M. Akselrod, V. Bulović, Appl. Phys. Lett. 101, 113303 (2012)
E.A. McArthur, J.M. Godbe, D.B. Tice, E.A. Weiss, J. Phys. Chem. C 116, 6136 (2012)
S. Kundu, A. Patra, Chem. Rev. 117, 712 (2017)
J.L. Banal, B. Zhang, D.J. Jones, K.P. Ghiggino, W.W.H. Wong, Acc. Chxem. Res. 50, 49 (2017)
G. Scheibe, Angew. Chem. 50, 212 (1937)
E.E. Jelley, Nature 138, 1009 (1936)
J. Frenkel, Phys. Rev. 37, 17 (1931)
V.V. Egorov, Phys. Procedia 2, 223 (2009)
M. Sukharev, A. Nitzan, Cond-Mat. Phys. (2017), arXiv:170405605
V.M. Agranovich, Excitations in Organic Solids (OUP Oxford, 2009)
T. Förster, Radiat. Res. Suppl. 2, 326 (1960)
M. Kasha, Radiat. Res. 20, 55 (1963)
W.T. Simpson, D.L. Peterson, J. Chem. Phys. 26, 588 (1957)
N.J. Hestand, F.C. Spano, Acc. Chem. Res. 50, 341 (2017)
C. Guo, M. Aydin, H.-R. Zhu, D.L. Akins, J. Phys. Chem. B 106, 5447 (2002)
H. von Berlepsch, C. Böttcher, L. Dähne, J. Phys. Chem. B 104, 8792 (2000)
H. von Berlepsch, C. Böttcher, A. Ouart, C. Burger, S. Dähne, S. Kirstein, J. Phys. Chem. B 104, 5255 (2000)
S. Sengupta, F. Würthner, Acc. Chem. Res. 46, 2498 (2013)
L.P. Vernon, G.R. Seely, The Chlorophylls (Academic Press, New York, 1966)
G.D. Scholes, G.R. Fleming, A. Olaya-Castro, R. van Grondelle, Nat. Chem. 3, 763 (2011)
W.P. Inskeep, P.R. Bloom, PLANT Physiol. 77, 483 (1985)
Q. Yan, Z. Luo, K. Cai, Y. Ma, D. Zhao, Chem. Soc. Rev. 43, 4199 (2014)
J.L. McHale, J. Phys. Chem. Lett. 3, 587 (2012)
A. Cacciola, C. Triolo, O. Di Stefano, A. Genco, M. Mazzeo, R. Saija, S. Patanè, S. Savasta, ACS Photon. 2, 971 (2015)
H. Fidder, J. Knoester, D.A. Wiersma, J. Chem. Phys. 95, 7880 (1991)
F.C. Spano, Phys. Rev. Lett. 67, 3424 (1991)
T. Wakamatsu, S. Toyoshima, K. Saito, J. Opt. Soc. Am. B 23, 1859 (2006)
T. Wakamatsu, K. Watanabe, K. Saito, Appl. Opt. 44, 906 (2005)
S. Kirstein, H. Möhwald, J. Chem. Phys. 103, 826 (1995)
V.S. Lebedev, A.S. Medvedev, D.N. Vasil’ev, D.A. Chubich, A.G. Vitukhnovsky, Q. Electron. 40, 246 (2010)
G. Wahling, Z. Für Naturforschung A 36, (1981)
S. Pirotta, M. Patrini, M. Liscidini, M. Galli, G. Dacarro, G. Canazza, G. Guizzetti, D. Comoretto, D. Bajoni, Appl. Phys. Lett. 104, 051111 (2014)
V.V. Shelkovnikov, Z.M. Ivanova, A.I. Plekhanov, E.V. Spesivtsev, S.V. Rykhlitsky, J. Appl. Spectrosc. 76, 66 (2009)
A.I. Plekhanov, V.V. Shelkovnikov, Opt. Spectrosc. 104, 545 (2008)
K. Roodenko, H.M. Nguyen, L. Caillard, A. Radja, P. Thissen, J.M. Gordon, Y.N. Gartstein, A.V. Malko, Y.J. Chabal, J. Phys. Chem. C 117, 20186 (2013)
O.P.M. Gaudin, I.D.W. Samuel, S. Amriou, P.L. Burn, Appl. Phys. Lett. 96, 053305 (2010)
H. DeVoe, J. Chem. Phys. 43, 3199 (1965)
D.A. Higgins, P.J. Reid, P.F. Barbara, J. Phys. Chem. 100, 1174 (1996)
H.V. Berlepsch, K. Ludwig, C. Böttcher, Phys. Chem. Chem. Phys. 16, 10659 (2014)
I. Pockrand, A. Brillante, D. Möbius, J. Chem. Phys. 77, 6289 (1982)
I. Pockrand, J.D. Swalen, J.G. Gordon, M.R. Philpott, J. Chem. Phys. 70, 3401 (1979)
O. Arteaga, Z. El-Hachemi, A. Canillas, Phys. Status Solidi A 205, 797 (2008)
T. Shaykhutdinov, S.D. Pop, A. Furchner, K. Hinrichs, ACS Macro Lett. 6, 598 (2017)
S. Kirstein, S. Daehne, Int. J. Photoenergy 2006, 1 (2006)
P. Alliprandini Filho, G.G. Dalkiranis, R.A.S.Z. Armond, E.M. Therézio, I.H. Bechtold, A.A. Vieira, R. Cristiano, H. Gallardo, A. Marletta, O.N. Oliveira, Phys. Chem. Chem. Phys. 16, 2892 (2014)
H. Yao, T. Isohashi, K. Kimura, J. Phys. Chem. B 111, 7176 (2007)
R.M.A. Azzam, N.M. Bashara, Ellipsometry and Polarized Light (North-Holland: Sole distributors for the USA and Canada, Elsevier Science Pub. Co., Amsterdam; New York, 1987)
J.R. Tischler, M.S. Bradley, V. Bulović, Opt. Lett. 31, 2045 (2006)
M.S. Bradley, J.R. Tischler, V. Bulović, Adv. Mater. 17, 1881 (2005)
P. Törmä, W.L. Barnes, Rep. Prog. Phys. 78, 013901 (2015)
J. Bellessa, C. Bonnand, J.C. Plenet, J. Mugnier, Phys. Rev. Lett. 93, (2004)
R. Houdré, Phys. Status Solidi B 242, 2167 (2005)
C. Bonnand, J. Bellessa, J.C. Plenet, Phys. Rev. B 73, (2006)
A. Salomon, S. Wang, J.A. Hutchison, C. Genet, T.W. Ebbesen, Chem. Phys. Chem. 14, 1882 (2013)
M.M. Dvoynenko, J.-K. Wang, Opt. Lett. 38, 760 (2013)
D. Melnikau, R. Esteban, D. Savateeva, A. Sánchez-Iglesias, M. Grzelczak, M.K. Schmidt, L.M. Liz-Marzán, J. Aizpurua, Y.P. Rakovich, J. Phys. Chem. Lett. 7, 354 (2016)
P.A. Hobson, W.L. Barnes, D.G. Lidzey, G.A. Gehring, D.M. Whittaker, M.S. Skolnick, S. Walker, Appl. Phys. Lett. 81, 3519 (2002)
A. Armitage, D. Lidzey, D.D. Bradley, T. Virgili, M. Skolnick, S. Walker, Synth. Met. 111–112, 377 (2000)
D.G. Lidzey, D.M. Coles, in Org. Hybrid Photonic Crystal, ed. by D. Comoretto (Springer International Publishing, Cham, 2015), pp. 243–273
J. Wenus, S. Ceccarelli, D.G. Lidzey, A.I. Tolmachev, J.L. Slominskii, J.L. Bricks, Org. Electron. 8, 120 (2007)
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Roodenko, K., Thissen, P. (2018). Optical Dielectric Properties of Thin Films Formed by Organic Dye Aggregates. In: Hinrichs, K., Eichhorn, KJ. (eds) Ellipsometry of Functional Organic Surfaces and Films. Springer Series in Surface Sciences, vol 52. Springer, Cham. https://doi.org/10.1007/978-3-319-75895-4_14
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