Abstract
Graphene, its composites and its modified forms have attracted the attention due to its novel structure and unique properties. They are widely employed in the treatment of organic and inorganic contaminants. One of the organic contaminants class—pesticides present in the aqueous environment is the threat to human and animal biota due to their carcinogenic effects. Graphene-based materials hold great potential in decontaminating pesticide bearing effluents such as adsorbents, photo-catalyst and membranes and are the current research trend. In this chapter, we reviewed the preparation, characterization and application of graphene-based materials in water purification. From the literature, it is known that graphene-based materials are widely used as adsorbents for pesticide removal. Therefore the optimum parameters affecting the adsorption process and a comparison of graphene-based adsorbents with other adsorbents are also discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Akhtar M, Iqbal S, Bhanger MI, Moazzam M (2009) Utilization of organic by-products for the removal of organo-phosphorous pesticide from aqueous media. J Hazard Mater 162:703–707. https://doi.org/10.1016/j.jhazmat.2008.05.084
ALOthman ZA, Alam MM, Naushad M (2013) Heavy toxic metal ion exchange kinetics: validation of ion exchange process of composite cation exchanger nylon 6, Zr (IV) phosphate. J Ind Eng Chem 19:956–960
Alqadmi A, Naushad M, Ahamd T, Abdalla MA, ALOthman ZA, Al Shehri SM (2016) Synthesis and characterization of Fe3O4@TSC nanocomposite: highly efficient removal of toxic metal ions from aqueous medium. RSC Adv. 6:22679–22689
Al-Qodah Z, Shawaqfeh AT, Lafi WK (2007) Adsorption of pesticides from aqueous solutions using oil shale ash. Desalin 208:294–305. https://doi.org/10.1016/j.desal.2006.06.019
Awual MR, Hasan MM, Naushad M, Shiwaku H, Yaita T (2015) Peparation of new class composite adsorbent for enhanced palladium (II) detection and recovery. Sen Actuat B: Chem 209:790–797
Brodie BC (1859) On the atomic weight of graphite. Philos Trans R Soc London 149:249–259
Chang C, Chang C, Hsu K, Lee S, Wolfgang H (2008) Adsorptive removal of the pesticide methomyl using hyper-crosslinked polymers. J Hazard Mater 155:295–304. https://doi.org/10.1016/j.jhazmat.2007.11.057
Chatterjee S, Das SK, Chakravarty R, Chakrabarti A, Ghosh S, Guha AK (2010) Interaction of Malathion, an Organophosphorus Pesticide with Rhizopus oryzae Biomass. J Hazard Mater 174:47–53. https://doi.org/10.1016/j.jhazmat.2009.09.014
Chaudhry Q, Schroder P, Werck-Reichhart D, Grajek W, Marecik R (2002) Prospects and limitations of phytoremediation for the removal of persistent pesticides in the environment. Environ Sci Pollut Res 9:4–17. https://doi.org/10.1007/BF02987313
Chauhan RS, Singhal L (2006) Harmful effects of pesticides and their control through cowpathy. Int J Cow Sci 2:61–70
Chen J, Li C (2013) An improved hummers method for eco-friendly synthesis of graphene oxide synthesis of graphene oxide. Carbon 64:225–229. https://doi.org/10.1016/j.carbon.2013.07.055
Chen S, Sun D, Chung JS (2007) Treatment of pesticide wastewater by moving-bed biofilm reactor combined with Fenton-coagulation pretreatment. J Hazard Mater 144:577–584. https://doi.org/10.1016/j.jhazmat.2006.10.075
Chen J, Zou J, Zeng J, Song X et al (2010) Preparation and evaluation of graphene-coated solid-phase micro-extraction fiber. Anal Chim Acta 678:44–49. https://doi.org/10.1016/j.aca.2010.08.008
Cunningham SD, Shann JR, Crowley DE, Anderson TA (1997) Phytoremediation of contaminated water and soil. ACS Symp Ser 664:2–17. https://doi.org/10.1021/bk-1997-0664.ch001
Domingues VF, Priolo G, Alves AC, Cabral MF, Delerue-matos C (2007) Adsorption behavior of α-cypermethrin on cork and activated carbon. J Environ Sci Heal Part B 42:649–654. https://doi.org/10.1080/03601230701465635
Edwards CA (1977) Environmental aspects of the usage of pesticides in developing countries. In: International symposium over Fytofarmacie en Fytiatrie, Rothamshed experimental station, Harpenden (UK)
Faur C, Métivier-Pignon H, Le Cloirec P (2005) Multi component adsorption of pesticides onto activated carbon fibers. Adsorption 11:479–490. https://doi.org/10.1007/s10450-005-5607-2
Gavrilescu M (2005) Fate of pesticides in the environment. Eng Life Sci 5:497–526. https://doi.org/10.1002/elsc.200520098
Gupta VK, Ali I, Saini VK (2006) Adsorption of 2, 4-D and carbofuran pesticides using fertilizer and steel industry wastes. J Colloid Interface Sci 299:556–563. https://doi.org/10.1016/j.jcis.2006.02.017
Gupta SS, Sreeprasad TS, Maliyekkal SM, Das SK, Pradeep T (2012) Graphene from sugar and its application in water purification. ACS Appl Mater Interfaces 4:4156–4163. https://doi.org/10.1021/am300889u
Gupta VK, Eren T, Atar N, Yola ML, Parlak C, Karimi-Maleh H (2015) CoFe2O4@TiO2 decorated reduced graphene oxide nanocomposite for photocatalytic degradation of chlorpyrifos. J Mol Liq 208:122–129. https://doi.org/10.1016/j.molliq.2015.04.032
Huang X, Yin Z, Wu S, Qi X et al (2011) Graphene-based materials: synthesis, characterization, properties, and applications. Small 7:1876–1902. https://doi.org/10.1002/smll.201002009
Huc V, Bendiab N, Bouchiat V, Ebbesen T (2008) Large and flat graphene flakes produced by epoxy bonding and reverse exfoliation of highly oriented pyrolytic graphite. Nanotechnology 19:455601 (6 p). https://doi.org/10.1088/0957-4484/19/45/455601
Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339. https://doi.org/10.1021/ja01539a017
Hunter WJ (2002) Bioremediation of chlorate or perchlorate contaminated water using permeable barriers containing vegetable oil. Curr Microbiol 45:287–292. https://doi.org/10.1007/s00284-002-3751-4
Karthik V, Saravanan K, Sivarajasekar N, Suriyanarayanan N (2016a) Bioremediation of dye bearing effluents using microbial biomass. Ecol Environ Conserv 22:S423–S434
Karthik V, Saravanan K, Sivarajasekar N, Suriyanarayanan N (2016b) Utilization of biomass from Trichoderma harzianum for the adsorption of reactive red, dye. Ecol Environ Conserv 22:S435–S440
Kim KS, Zhao Y, Jang H et al (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457:706–710. https://doi.org/10.1038/nature07719
Li D, Müller MB, Gilje S, Kaner RB, Wallace GG (2008) Processable aqueous dispersions of graphene nanosheets. Nat Nanotechnol 3:101–105. https://doi.org/10.1038/nnano.2007.451
Lièvremont D, Seigle-Murandi F, Benoit-Guyod JL (1998) Removal of PCNB from aqueous solution by a fungal adsorption process. Water Res 32:3601–3606. https://doi.org/10.1016/S0043-1354(98)00132-8
Liu Q, Shi J, Zeng L, Wang T, Cai Y, Jiang G (2011) Evaluation of graphene as an advantageous adsorbent for solid-phase extraction with chlorophenols as model analytes. J Chromatogr A 1218:197–204. https://doi.org/10.1016/j.chroma.2010.11.022
Liu X, Zhang H, Ma Y, Wu X et al (2013) Graphene-coated silica as a highly efficient sorbent for residual organophosphorus pesticides in water. J Mater Chem A 1:1875–1884. https://doi.org/10.1039/C2TA00173J
Maliyekkal SM, Sreeprasad TS, Krishnan D et al (2013) Graphene: a reusable substrate for unprecedented adsorption of pesticides. Small 9:273–283. https://doi.org/10.1002/smll.201201125
Marcano DC, Kosynkin DV, Berlin JM et al (2010) Improved synthesis of graphene oxide. ACS Nano 4:4806–4814. https://doi.org/10.1021/nn1006368
McAllister MJ, Li JL, Adamson DH, Schniepp HC et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–4404. https://doi.org/10.1021/cm0630800
Naushad M, ALOthman ZA, Sharma G (2015) Inamuddin, Kinetics, isotherm and thermodynamic investigations for the adsorption of Co(II) ion onto crystal violet modified amberlite IR-120 resin. Ionics 21:1453–1459
Newcombe DA, Crowley DE (1999) Bioremediation of atrazine-contaminated soil by repeated applications of atrazine-degrading bacteria. Appl Microbiol Biotechnol 51:877–882. https://doi.org/10.1007/s002530051477
Reina A, Jia X, Ho J, Nezich D et al (2009) Layer area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett 9:3087. https://doi.org/10.1021/nl901829a
Rice PJ, Anderson TA, Coats JR (1997) Phytoremediation of herbicide-contaminated surface water with aquatic plants. ACS Symp Ser 664:133–151. https://doi.org/10.1021/bk-1997-0664.ch010
Schniepp HC, Li J, Mcallister MJ et al (2006) Functionalized single graphene sheets derived from splitting graphite. J Phys Chem B 110:8535–8539. https://doi.org/10.1021/jp060936f
Shi Z, Hu J, Li Q, Zhang S, Liang Y, Zhang H (2014) Graphene based solid phase extraction combined with ultra high performance liquid chromatography-tandem mass spectrometry for carbamate pesticides analysis in environmental water samples. J Chromatogr A 1355:219–227. https://doi.org/10.1016/j.chroma.2014.05.085
Sidorov AN, Yazdanpanah MM, Jalilian R et al (2007) Electrostatic deposition of graphene. Nanotechnology 18:135301 (4 p). https://doi.org/10.1088/0957-4484/18/13/135301
Silva M, Fernandes A, Mendes A, Manaia CM, Nunes OC (2004) Preliminary feasibility study for the use of an adsorption/bio-regeneration system for molinate removal from effluents. Water Res 38:2677–2684. https://doi.org/10.1016/j.watres.2004.03.016
Singh N (2009) Adsorption of herbicides on coal fly ash from aqueous solutions. J Hazard Mater 168:233–237. https://doi.org/10.1016/j.jhazmat.2009.02.016
Sivarajasekar N, Baskar R, Ragu T, Sarika K, Preethi N, Rathika T (2016) Biosorption studies on waste cotton seed for cationic dyes sequestration: equilibrium and thermodynamics. Appl Water Sci. https://doi.org/10.1007/s13201-016-0379-2
Sivarajasekar N, Paramasivan T, Muthusaravanan S, Muthukumaran P, Sivamani S (2017a) Defluoridation of water using adsorbents—a concise review. J Environ Biotechnol Res 6:186–198
Sivarajasekar N, Balasubramani K, Mohanraj N, Prakash Maran J, Sivamani S, Ajmal Koya P, Karthik V (2017b) Fixed-bed adsorption of atrazine onto microwave irradiated Aegle marmelos Correa fruit shell: statistical optimization, process design and breakthrough modelling. J Mol Liq 241:823–830
Sivarajasekar N, Mohanraj N, Baskar R, Sivamani S (2017c) Fixed-bed adsorption of ranitidine hydrochloride onto microwave assisted—activated Aeglemarmelos Correa fruit shell: statistical optimization and breakthrough modelling. Arab J Sci Eng. https://doi.org/10.1007/s13369-017-2565-4
Sivarajasekar N, Mohanraj N, Sivamani S, Ganesh Moorthy I (2017d) Response surface methodology approach for optimization of lead (II) adsorptive removal by Spirogyra sp. Biomass. J Environ Biotechnol 6:88–95
Sivarajasekar N, Mohanraj N, Balasubramani K, Prakash Maran J, Moorthy IG, Karthik V, Karthikeyan K (2017e) Optimization, equilibrium and kinetic studies on ibuprofen removal onto microwave assisted - activated Aegle marmelos correa fruit shell. DESALINATION AND WATER TREATMENT 84:48–58
Sivarajasekar N, Mohanraj N, Sivamani S, Moorthy IG, Kothandan R, Muthusaravanan S (2017f) Comparative modeling of fluoride biosorption onto waste Gossypium hirsutum seed microwave-bichar using response surface methodology and artificial neural networks. International Conference on Intelligent Computing, Instrumentation and Control Technologies (ICICICT), IEEE Explore 1631-1635. https://doi.org/10.1109/ICICICT1.2017.8342815
Sivarajasekar N, Paramasivan T, Subashini R, Kandasamy S (2017g) Central composite design optimization of fluoride removal by spirogyra biomass. Asian J Microbiol Biotechnol Environ Sci 19:S130–S137.
Sivarajasekar N, Mohanraj N, Sivamani S, Prakash Maran J, Moorthy IG, Balasubramani K, (2018) Statistical optimization studies on adsorption of ibuprofen onto Albizialebbeck seed pods activated carbon prepared using microwave irradiation. Materials Today: Proceedings 5(2):7264–7274
Stankovich S, Dikin DA, Piner RD et al (2007) Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon N Y 45:1558–1565. https://doi.org/10.1016/j.carbon.2007.02.034
Suciu NA, Capri E (2009) Adsorption of chlorpyrifos, penconazole and metalaxyl from aqueous solution by modified clays. J Environ Sci Heal Part B 44:525–532. https://doi.org/10.1080/03601230902997543
Sudhakar Y, Dikshit A (1999) Adsorbent selection for endosulfan removal from water environment. J Environ Sci Heal Part B 34:97–118
Sun Y, Pignatello JJ (1992) Chemical treatment of pesticide wastes. Evaluation of iron (III) chelates for catalytic hydrogen peroxide oxidation of 2,4-D at circumneutral pH. J Agric Food Chem 40:322–327. https://doi.org/10.1021/jf00014a031
Tang Y, Zhang G, Liu C, Luo S, Xu X (2013) Magnetic TiO2-graphene composite as a high-performance and recyclable platform for efficient photocatalytic removal of herbicides from water. J Hazard Mater 252–253:115–122. https://doi.org/10.1016/j.jhazmat.2013.02.053
Tsai WT, Lai CW, Hsien KJ (2003) Effect of particle size of activated clay on the adsorption of paraquat from aqueous solution. J Colloid Interface Sci 263:29–34. https://doi.org/10.1016/S0021-9797(03)00213-3
Wang C, Feng C, Gao Y, Ma X, Wu Q, Wang Z (2011) Preparation of a graphene-based magnetic nanocomposite for the removal of an organic dye from aqueous solution. Chem Eng J 173:92–97. https://doi.org/10.1016/j.cej.2011.07.041
Wang W, Li Y, Wu Q, Wang C, Zang X, Wang Z (2012) Extraction of neonicotinoid insecticides from environmental water samples with magnetic graphene nanoparticles as adsorbent followed by determination with HPLC. Anal Methods 4:766–772. https://doi.org/10.1039/c2ay05734d
Wang X, Liu B, Lu Q, Qu Q (2014a) Graphene-based materials: fabrication and application for adsorption in analytical chemistry. J Chromatogr A 1362:1–15. https://doi.org/10.1016/j.chroma.2014.08.023
Wang Y, Peng W, Liu X et al (2014b) Study of bilineage differentiation of human-bone-marrow-derived mesenchymal stem cells in oxidized sodium alginate/N-succinyl chitosan hydrogels and synergistic effects of RGD modification and low-intensity pulsed ultrasound. Acta Biomater 10:2518–2528. https://doi.org/10.1016/j.actbio.2013.12.052
Wu Q, Zhao G, Feng C, Wang C, Wang Z (2011) Preparation of a graphene-based magnetic nanocomposite for the extraction of carbamate pesticides from environmental water samples. J Chromatogr A 1218:7936–7942. https://doi.org/10.1016/j.chroma.2011.09.027
Wu Q, Feng C, Zhao G, Wang C, Wang Z (2012) Graphene-coated fiber for solid-phase microextraction of triazine herbicides in water samples. J Sep Sci 35:193–199. https://doi.org/10.1002/jssc.201100740
Xia H, Ma X (2006) Phytoremediation of ethion by water hyacinth (Eichhorni acrassipes) from water. Bioresour Technol 97:1050–1054. https://doi.org/10.1016/j.biortech.2005.04.039
Xu J, Lv H, Yang ST, Luo J (2013) Preparation of graphene adsorbents and their applications in water purification. Rev Inorg Chem 33:139–160. https://doi.org/10.1515/revic-2013-0007
Zhang C, Zhang RZ, Ma YQ et al (2015) Preparation of cellulose/graphene composite and its applications for triazine pesticides adsorption from water. ACS Sustain Chem Eng 3:396–405. https://doi.org/10.1021/sc500738k
Zhao G, Wen T, Chen C, Wang X (2012) Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas. RSC Adv 2:9286–9303. https://doi.org/10.1039/c2ra20990j
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer International Publishing AG, part of Springer Nature
About this chapter
Cite this chapter
Paramasivan, T. et al. (2019). Graphene Family Materials for the Removal of Pesticides from Water. In: Naushad, M. (eds) A New Generation Material Graphene: Applications in Water Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-75484-0_13
Download citation
DOI: https://doi.org/10.1007/978-3-319-75484-0_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-75483-3
Online ISBN: 978-3-319-75484-0
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)