Abstract
Carbon nanotubes (CNTs) based sensors are drawn considerable attentions for gas adsorption and sensing due to their large specific surface area. In this paper, the adsorptions of three SF6 decomposed components (SO2F2, SOF2 and SO2) on Pt doped CNT are theoretically studied based on density function theory method. The density of state, frontier molecular orbital theory as well as Mulliken population analysis were considered in order to comprehensively understand the adsorbing processes. Results indicated that Pt-CNT has the best sensitivity to SOF2 owing to their strong chemisorption, followed by SO2 and the last one comes to SO2F2 due to their weak physisorption. Pt dopant that acts as an activated catalytic additive can effectively improve the adsorption ability to gas molecules through providing several active adsorption sites of CNT. Our calculation results would be meaningful not only to explain the sensing mechanism of CNT but also to suggest advanced SWCNTs based sensing materials to be applied in the field of electrical engineering.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Beyer C, Jenett H, Klockow D (2000) IEEE Trans Dielectr Electr Insulation 7(2):234–240
Zhang XX, Liu WT, Tang J, Xiao P (2010) IEEE Trans Dielectr Electr Insulation 17(3):833–838
Beyer C, Jenett H, Klockow D (2000) IEEE Trans Dielectr Electr Insulation 7(2):234–240
Piemontesi M, Niemeyer L (1996) Presented at the IEEE international symposium on electrical insulation (unpublished)
Qiu Y, Kuffel E (2000) IEEE Trans Dielectr Electr Insulation 6(6):892–895
Van Brunt RJ, Herron JT (2007) Phys Scr 1994(T53):9–29
Braun JM, Chu FY, Seethapathy R (1987) IEEE Trans Electr Insulation 22(2):187–193
Kusumoto S, Itoh S, Tsuchiya Y, Mukae H, Matsuda S, Takahashi K (1980) IEEE Trans Power Apparatus Syst PAS-99(4):1456–1465
Iijima S, Ichihashi T (1993) Nature 364(6430):603–605
Suehiro J, Zhou G, Hara M (2003) J Phys D Appl Phys 36(21):L109–L114
Kang H, Lim S, Park N, Chun KY, Baik S (2010) Sens Actuators B Chem 147(1):316–321
Zilli D, Bonelli PR, Cukierman AL (2011) Sens Actuators B Chem 157(1):169–176
Zhang X, Cui H, Gui Y, Tang J (2017) Nanoscale Res Lett 12(1):177
Popov VN (1998) Mater Sci Eng R Rep 24(3):61–102
Ruiz A, Arbiol J, Cirera A, Cornet A, Morante JR (2002) Mater Sci Eng C 19(1):105–109
Zhang X, Cui H, Dong X, Chen D, Tang J (2017) Appl Surf Sci
Zhang X, Cui H, Zhang J, Tang J (2017) Appl Surf Sci 419:802–810
Li W, Liang C, Zhou W, Qiu J, Zhou Z, Gongquan Sun A, Xin Q (2003) J Phys Chem B 107 (26):149–154
Penza M, Rossi R, Alvisi M, Cassano G, Signore MA, Serra E, Giorgi R (2008) Sens Actuators B Chem 135(1):289–297
Avramov PV, Kudin KN, Scuseria GE (2003) Chem Phys Lett 370(5–6):597–601
Monkhorst HJ, Pack JD (1976) Phys Rev B 13(12):5188–5192
Wang R, Zhang D, Zhang Y, Liu C (2006) J Phys Chem B 110(37):18267–18271
Gülseren O, Yildirim T, Ciraci S (2002) Phys Rev B 65(15)
Boys SF, Bernardi F (2002) Mol Phys 19(1):553–566
Cuong NT, Chi DH, Kim YT, Mitani T (2006) Phys Status Solidi 243(12):3472
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Cui, H., Zhang, X., Chen, D., Fang, J., Tang, J. (2018). Pt Decorating Effect on CNT Surface Towards Adsorption of SF6 Decomposed Components. In: & Materials Society, T. (eds) TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72526-0_88
Download citation
DOI: https://doi.org/10.1007/978-3-319-72526-0_88
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-72525-3
Online ISBN: 978-3-319-72526-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)