Abstract
Carbon nanotubes (CNTs) are promising modern nanostructured materials with extraordinary mechanical, chemical, and good thermal stability properties as well as high aspect ratio. These features make them useful materials in various applications. However, pristine CNTs tend to form aggregates and bundles making them difficult to use. Superficial modification/treatment of CNTs with organic or inorganic materials results in improvement of nanotubes’ useful properties and applicability, giving them the required magnetic, catalytic, electronic properties, etc. Therefore, characterization of CNTs is carried out to check and ascertain its features such as type, surface structure, and morphology (diameter, length), dispersion, configuration, size, etc. In this chapter, current innovative approaches widely utilized in CNTs characterization are classified and discussed with highlights on their principle as well as most of their merits and demerits.
Similar content being viewed by others
References
Akhtar K, Khan SA, Khan SB, Asiri AM (2018) Scanning electron microscopy: principle and applications in nanomaterials characterization. In: Sharma SK (ed) Handbook of materials characterization. Springer International Publishing AG, Part of Springer Nature. https://doi.org/10.1007/978-3-319-92955-2_4
Allaf RM, Rivero IV, Spearman SS, Hope-weeks LJ (2011) On the preparation of as-produced and purified single-walled carbon nanotube samples for standardized X-ray diffraction characterization. Mater Charact 62:857–864. https://doi.org/10.1016/j.matchar.2011.06.005
Alturaif HA, ALOthman ZA, Shapter JG, Wabaidur SM (2014) Use of carbon nanotubes (CNTs) with polymers in solar cells. Molecules 19(11):17329–17344
Arunkumar T, Karthikeyan R, Ram Subramani R, Viswanathan K, Anish M (2020) Synthesis and characterisation of multi-walled carbon nanotubes (MWCNTs). Int J Ambient Energy 41:452–456. (AC21 International Forum 2014)
Belin T, Epron F (2005) Characterization methods of carbon nanotubes: a review. Mater Sci Eng B 119:105–118. https://doi.org/10.1016/j.mseb.2005.02.046
Burian A, Dore JC, Kyotani T, Honkimaki V (2005) Structural studies of oriented carbon nanotubes in alumina channels using high energy X-ray diffraction. Carbon 43:2723–2729. https://doi.org/10.1016/j.carbon.2005.05.032
Caetano FR, Felippe LB, Zarbin AJ, Bergamini MF, Marcolino-Junior LH (2017) Gold nanoparticles supported on multi-walled carbon nanotubes produced by biphasic modified method and dopamine sensing application. Sensors Actuators B Chem 243:43–50
Cao A, Xu C, Liang J, Wu D, Wei B (2001) X-ray diffraction characterization on the alignment degree of carbon nanotubes. Chem Phys Lett 344:13–17
Chen M, Fan G, Tan Z, Yuan C, Xiong D, Guo Q, ... Li Z (2019) Tailoring and characterization of carbon nanotube dispersity in CNT/6061Al composites. Mater Sci Eng A 757:172–181
Chirayil CJ, Abraham J, Mishra RK, George SC, Thomas S (2017) Instrumental techniques for the characterization of nanoparticles. In: Thermal and Rheological Measurement Techniques for Nanomaterials Characterization. Elsevier Inc, pp 1–36. https://doi.org/10.1016/B978-0-323-46139-9.00001-3
Chua M, Chui C, Chng C, Lau D (2013) Carbon nanotube-based artificial tracheal prosthesis: carbon nanocomposite implants for patient-specific ENT care. IEEE Nanotechnol Mag 7(4):27–31
Colomer J-F, Van Tendeloo G (2003) Electron diffraction and microscopy of single-walled carbon nanotubes bundles. In: Wang ZL, Hui C (eds) Electron microscopy of nanotubes. Klumer Academic Publishers, Boston/London, pp 45–70. http://library1.nida.ac.th/termpaper6/sd/2554/19755.pdf
Das R, Hamid SBA, Ali ME, Ramakrishna S, Yongzhi W (2015) Carbon nanotubes characterization by X-ray powder diffraction – a review. Curr Nanosci 11:1–13. https://doi.org/10.2174/1573413710666140818210043
Davies G, El Sheikh A, Collett C, Yakub I, McGregor J (2021) Catalytic carbon materials from biomass. In: Emerging carbon materials for catalysis. Elsevier Inc., pp 161–195. https://doi.org/10.1016/b978-0-12-817561-3.00005-6
Dore J, Burian A, Tomita S (2000) Structural studies of carbon nanotubes and related materials by neutron and X-ray diffraction. In: Proceedings of the international conference on “Condensed Matter Physics,” Acta Physica Polonica A, Jaszowiec, pp 495–504
Epp J (2016) X-ray diffraction (XRD) techniques for materials characterization. In: Hubschen G, Altpeter I, Tschuncky R, Herrmann H-G (eds) Materials characterization using nondestructive evaluation methods. Elsevier Ltd. https://doi.org/10.1016/B978-0-08-100040-3.00004-3
Fredi G, Dorigato A, Fambri L, Pegoretti A (2017) Wax confinement with carbon nanotubes for phase changing epoxy blends. Polymers 9(9):405
He H, Pham-Huy LA, Dramou P, Xiao D, Zuo P, Pham-Huy C (2013) Carbon nanotubes: applications in pharmacy and medicine. BioMed Res Int 2013, 1–12. https://doi.org/10.1155/2013/578290
Herrero-Latorre C, Álvarez-Méndez J, Barciela-García J, García-Martín S, Peña- Crecente, R.M. (2015) Characterization of carbon nanotubes and analytical methods for their determination in environmental and biological samples: a review. Anal Chim Acta 853:77–94. https://doi.org/10.1016/j.aca.2014.10.008
Holbrook RD, Galyean AA, Gorham JM, Herzing A, Pettibone J (2015) Overview of nanomaterial characterization and metrology. In: Frontiers of Nanosciences. Elsevier Ltd. https://doi.org/10.1016/B978-0-08-099948-7.00002-6
Hou X, Lv S, Chen Z, Xiao F (2018) Applications of Fourier transform infrared spectroscopy technologies on asphalt materials. Measurement 121:304–316
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58
Inkson BJ (2016) Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM) for materials characterization. In: Hubschen G, Altpeter I, Tschuncky R, Herrmann H-G (eds) Materials characterization using nondestructive evaluation methods. Elsevier Ltd. https://doi.org/10.1016/B978-0-08-100040-3.00002-X
Kaliva M, Vamvakaki M (2020) Nanomaterials characterization. In: Polymer science and nanotechnology. Elsevier Inc. https://doi.org/10.1016/B978-0-12-816806-6.00017-0
Karimi M, Ghasemi A, Mirkiani S, Basri SMM, Hamblin MR (2017) Carbon Nanotubes in Drug and Gene Delivery. San Rafael, CA: Morgan & Claypool Publishers, pp 5–6
Kennedy J, Fang F, Futter J, Leveneur J, Murmu PP, Panin GN, ... Manikandan E (2017) Synthesis and enhanced field emission of zinc oxide incorporated carbon nanotubes. Diam Relat Mater 71:79–84
Koloczek J, Hawelek L, Burian A, Dore JC, Honkimaki V, Kyotani T (2005) Modelling studies of carbon nanotubes – comparison of simulations and X-ray diffraction data. J Alloys Compd 401:46–50. https://doi.org/10.1016/j.jallcom.2005.02.068
Kumar SP, Pavithra KG, Naushad M (2019) Characterization techniques for nanomaterials. In: Nanomaterials for solar cell applications, Elsevier Inc. https://doi.org/10.1016/B978-0-12-813337-8.00004-7
Laudenbach J, Schmid D, Herziger F, Hennrich F, Kappes M, Muoth M, ... Maultzsch J (2017) Diameter dependence of the defect-induced Raman modes in functionalized carbon nanotubes. Carbon 112:1–7
Leyva-Porras C, Cruz-Alcantar P, Espinosa-Solís V, Martínez-Guerra E, Piñón-Balderrama CI, Compean Martínez I, Saavedra-Leos MZ (2020) Application of differential scanning calorimetry (DSC) and modulated differential scanning calorimetry (MDSC) in food and drug industries. Polymers 12:5. (AC21 International Forum 2014)
Liao J, Tan MJ (2011) Mixing of carbon nanotubes (CNTs) and aluminum powder for powder metallurgy use. Powder Technol 208:42–48. (AC21 International Forum 2014)
Lopes CDCA, Limirio PHJO, Novais VR, Dechichi P (2018) Fourier transform infrared spectroscopy (FTIR) application chemical characterization of enamel, dentin and bone. Appl Spectrosc Rev 53(9):747–769
Ma L, Dong X, Chen M, Zhu L, Wang C, Yang F, Dong Y (2017) Fabrication and water treatment application of carbon nanotubes (CNTs)-based composite membranes: a review. Membranes 7(1):16
Mehra NK, Jain K, Jain NK (2015) Pharmaceutical and biomedical applications of surface engineered carbon nanotubes. Drug Discov Today 20(6):750–759
Mohamed MA, Jaafar J, Ismail AF, Othman MHD, Rahman MA (2017) Fourier transform infrared (FTIR) spectroscopy. In: Membrane characterization. Elsevier United Kingdom, pp 3–29. https://doi.org/10.1016/B978-0-444-63776-5.00001-2
Nicolson F, Kircher MF, Stone N, Matousek P (2021) Spatially offset Raman spectroscopy for biomedical applications. Chem Soc Rev
Omrani AN, Esmaeilzadeh E, Jafari M, Behzadmehr A (2019) Effects of multi walled carbon nanotubes shape and size on thermal conductivity and viscosity of nanofluids. Diam Relat Mater 93:96–104
Porwal D, Mukhopadhyay K, Ram K, Mathur GN (2007) Investigation of the synthesis strategy of CNTs from CCVD by thermal analysis. Thermochim Acta 463:53–59
Rahman G, Najaf Z, Mehmood A, Bilal S, Mian SA, Ali G (2019) An overview of the recent progress in the synthesis and applications of carbon nanotubes. C–J Carbon Res 5(1):3
Raju M, Kulkarni YA, Wairkar S (2019) Therapeutic potential and recent delivery systems of berberine: a wonder molecule. J Funct Foods 61:103517
Sarycheva A, Gogotsi Y (2020) Raman spectroscopy analysis of the structure and surface chemistry of Ti3C2T x MXene. Chem Mater 32(8):3480–3488
Srivastava R, Suman H, Shrivastava S, Srivastava A (2019) DFT analysis of pristine and functionalized Zigzag CNT: a case of H2S sensing. Chem Phys Lett 731:136575
Susi T, Pichler T, Ayala P (2015) X-ray photoelectron spectroscopy of graphitic carbon nanomaterials doped with heteroatoms. Beilstein J Nanotechnol 6:177–192. https://doi.org/10.3762/bjnano.6.17
Szufa S, Dzikuć M, Adrian Ł, Piersa P, Romanowska-Duda Z, Lewandowska W, ... Piwowar A (2020) Torrefaction of oat straw to use as solid biofuel, an additive to organic fertilizers for agriculture purposes and activated carbon–TGA analysis, kinetics. In: E3S web of conferences, vol 154. EDP Sciences, p 02004
Veisi H, Kazemi S, Mohammadi P, Safarimehr P, Hemmati S (2019) Catalytic reduction of 4-nitrophenol over Ag nanoparticles immobilized on Stachys lavandulifolia extract-modified multi walled carbon nanotubes. Polyhedron 157:232–240
Wang X, Mu P, Zhang C, Chen Y, Zeng J, Wang F, Jiang JX (2017) Control synthesis of tubular hyper-cross-linked polymers for highly porous carbon nanotubes. ACS Appl Mater Interfaces 9(24):20779–20786
Wang X, Dong A, Hu Y, Qian J, Huang S (2020) A review of recent work on using metal– organic frameworks to grow carbon nanotubes. Chem Commun 56(74):10809–10823
Williams DB, Carter CB (eds) (2009) Transmission electron microscopy Part 1: basics, 2nd edn. Springer, New York
Xu Q, Li W, Ding L, Yang W, Xiao H, Ong WJ (2019) Function-driven engineering of 1D carbon nanotubes and 0D carbon dots: mechanism, properties and applications. Nanoscale 11:1475–1504. (AC21 International Forum 2014)
Zhang X, Wen R, Huang Z, Tang C, Huang Y, Liu Y, ... Xu Y (2017) Enhancement of thermal conductivity by the introduction of carbon nanotubes as a filler in paraffin/expanded perlite form-stable phase-change materials. Energ Buildings 149:463–470
Zheng Q, Zhang Y, Montazerian M, Gulbiten O, Mauro JC, Zanotto ED, Yue Y (2019) Understanding glass through differential scanning calorimetry. Chem Rev 119(13):7848–7939
Zhu Y, Zhiyu B, Kalavakunda V, Hosmane NS (2017) Endofullerenes and carboranes. In: Comprehensive supramolecular chemistry II, pp 479–487
Acknowledgments
The authors appreciate the University Research Council (URC) of the University of Johannesburg for the funding support.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 Springer Nature Switzerland AG
About this entry
Cite this entry
Olaitan Ayeleru, O. et al. (2021). Innovative Approaches in Characterization of Carbon Nanotube. In: Abraham, J., Thomas, S., Kalarikkal, N. (eds) Handbook of Carbon Nanotubes. Springer, Cham. https://doi.org/10.1007/978-3-319-70614-6_55-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-70614-6_55-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-70614-6
Online ISBN: 978-3-319-70614-6
eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics