Skip to main content

The Effects of the Industrial Processing on Commercial Polyhydroxyalkanoates

  • Conference paper
  • First Online:
Sustainable Design and Manufacturing 2017 (SDM 2017)

Part of the book series: Smart Innovation, Systems and Technologies ((SIST,volume 68))

Included in the following conference series:

  • 5720 Accesses

Abstract

In the last years polyhydroxyalkanoates (PHAs) gained increasing attention as potential sustainable replacement of current plastics from fossil sources. PHAs are biodegradable polymers which can be produced from bacteria exploiting waste as feedstock. In order to bring these polymers on the market, it is necessary to know their properties and assess the effects of industrial processing stages on the final material. For this reason, in this work different industrial PHAs were investigated. These materials were structurally characterized and their thermal properties were assessed. Furthermore, they were subjected to different thermal and thermo—mechanical treatments (various time, temperature and frequency of rotation in the extruder) in order to study the effect of the applied conditions on the properties of the final material.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 299.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 379.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 379.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Mooney, B.P.: The second green revolution? Production of plant-based biodegradable plastics. Biochem. J. 418, 219–232 (2009)

    Article  Google Scholar 

  2. Mazzocchetti, L., Scandola, M., Jiang, Z.: Random copolymerization with a large lactone enhances aliphatic polycarbonate crystallinity. Eur. Polym. J. 48, 1883–1891 (2012)

    Article  Google Scholar 

  3. Mazzocchetti, L., Scandola, M., Jiang, Z.: Copolymers of ethyl glycolate and ω-Pentadecalactone: enzymatic synthesis and solid-state characterization. Eur. Polym. J. 47, 942–948 (2011)

    Article  Google Scholar 

  4. Mazzocchetti, L., Tsoufis, T., Rudolf, P., Loos, K.: Enzymatic synthesis of amylose brushes revisited: details from X-ray photoelectron spectroscopy and spectroscopic ellipsometry. Macromol. Biosci. 14, 186–194 (2014)

    Article  Google Scholar 

  5. Ortega, Z., Morón, M., Monzón, D.M., Badallò, P., Paz, R.: Production of banana fiber yarns for technical textile reinforced composites. Materials 9, 370 (2016)

    Article  Google Scholar 

  6. Sisti, L., Belcari, J., Mazzocchetti, L., Totaro, G., Vannini, M., Giorgini, L., Zucchelli, A., Celli, A.: Multicomponent reinforcing system for poly(butylene succinate): composites containing poly(l-lactide) electrospun mats loaded with graphene. Polym. Testing 50, 283–291 (2016)

    Article  Google Scholar 

  7. Doi, Y.: Microbial synthesis and properties of polyhydroxy-alkanoates. MRS Bull. 17, 39–42 (1992)

    Article  Google Scholar 

  8. Mozejko-Ciesielska, J., Kiewisz, R.: Bacterial polyhydroxyalkanoates: still fabulous? Microbiol. Res. 192, 271–282 (2016)

    Article  Google Scholar 

  9. Bengtsson, S., Karlsson, A., Alexandersson, T., Quadri, L., Hjort, M., Johansson, P., Morgan-Sagastume, F., Anterrieu, S., Arcos-Hernandez, M., Karabegovic, L., Magnusson, P., Werker, A.: A process for polyhydroxyalkanoate (PHA) production from municipal wastewater treatment with biological carbon and nitrogen removal demonstrated at pilot-scale. New Biotechnol. 35, 42–53 (2017)

    Article  Google Scholar 

  10. Gazzano, M., Mazzocchetti, L., Pizzoli, M., Scandola, M.: Crystal orientation switching in spherulites grown from miscible blends of poly(3-hydroxybutyrate) with cellulose tributyrate. J. Polym. Sci. B Polym. Phys. 50, 1463–1473 (2012)

    Article  Google Scholar 

  11. Di Lorenzo, M.L., Raimo, M., Cascone, E., Martuscelli, E.: Poly(3-hydoxybutyrate)-based copolymers and blends: influence of a second component on crystallization and thermal behavior. J. Macromol. Sci. B. 40, 639–667 (2001)

    Article  Google Scholar 

  12. Chanprateep, S.: Current trends in biodegradable polyhydroxyalkanoates. J. Biosci. Bioeng. 110, 621–632 (2010)

    Article  Google Scholar 

  13. Samorì, C., Abbondanzi, F., Galletti, P., Giorgini, L., Mazzocchetti, L., Torri, C., Tagliavini, E.: Extraction of polyhydroxyalkanoates from mixed microbial cultures: impact on polymer quality and recovery. Bioresour. Technol. 189, 195–202 (2015)

    Article  Google Scholar 

  14. Samorì, C., Basaglia, M., Casella, S., Favaro, L., Galletti, P., Giorgini, L., Marchi, D., Mazzocchetti, L., Torri, C., Tagliavini, E.: Dimethyl carbonate and switchable anionic surfactants: two effective tools for the extraction of polyhydroxyalkanoates from microbial biomass. Green Chem. 17, 1047–1056 (2015)

    Article  Google Scholar 

  15. Pachekoski, W.M., Dalmolin, C., Agnelli, J.A.M.: The influence of the industrial processing on the degradation of poly(hydroxybutyrate) - PHB. Mater. Res. 16, 327–332 (2013)

    Article  Google Scholar 

  16. Angiolini, L., Benelli, T., Giorgini, L., Raymo, F.M.: Chiroptical switching based on photoinduced proton transfer between homopolymers bearing side-chain spiropyran and azopyridine moieties. Macromol. Chem. Phys. 209, 2049–2060 (2008)

    Article  Google Scholar 

  17. Bicciocchi, E., Chong, Y.K., Giorgini, L., Moad, G., Rizzardo, E., Thang, S.H.: Substituent effects on raft polymerization with benzyl aryl trithiocarbonates. Macromol. Chem. Phys. 211, 529–538 (2010)

    Article  Google Scholar 

  18. Angiolini, L., Caretti, D., Salatelli, E., Mazzocchetti, L., Willem, R., Biesemans, M.: Synthesis and characterization of new functional polystyrenes containing tributyltin carboxylate moieties linked to the aromatic ring by a trimethylene spacer. J. Inorg. Organomet. Polym Mater. 18, 236–245 (2008)

    Article  Google Scholar 

  19. Martínez-Sanz, M., Villano, M., Oliveira, C., Albuquerque, M.G.E., Majone, M., Reis, M., Lopez-Rubio, A., Lagaron, J.M.: Characterization of polyhydroxyalkanoates synthesized from microbial mixed cultures and of their nanobiocomposites with bacterial cellulose nanowhiskers. New Biotech. 31, 364–376 (2014)

    Article  Google Scholar 

  20. Samorì, C., Galletti, P., Giorgini, L., Mazzeo, R., Mazzocchetti, L., Prati, S., Sciutto, G., Volpi, F., Tagliavini, E.: The green attitude in art conservation: polyhydroxybutyrate-based gels for the cleaning of oil paintings. ChemistrySelect 1, 4502–4508 (2016)

    Article  Google Scholar 

  21. Kawalec, M., Sobota, M., Scandola, M., Kowalczuk, M., Kurcok, P.A.: Convenient route to PHB macromonomers via anionically controlled moderate-temperature degradation of PHB. J. Polym. Sci. A Polym. Chem. 48, 5490–5497 (2010)

    Article  Google Scholar 

Download references

Acknowledgements

Authors wish to acknowledge the financial support from project no. F/0264/01-02/X26 funded by MISE (mise.AOO_IAI.REGISTRO INTERNO.R.0000727.09-02-2016 on 09-02-2016).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Laura Mazzocchetti .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer International Publishing AG

About this paper

Cite this paper

Mazzocchetti, L., Benelli, T., Maccaferri, E., Giorgini, L. (2017). The Effects of the Industrial Processing on Commercial Polyhydroxyalkanoates. In: Campana, G., Howlett, R., Setchi, R., Cimatti, B. (eds) Sustainable Design and Manufacturing 2017. SDM 2017. Smart Innovation, Systems and Technologies, vol 68. Springer, Cham. https://doi.org/10.1007/978-3-319-57078-5_45

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-57078-5_45

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-57077-8

  • Online ISBN: 978-3-319-57078-5

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics