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The Electron Radiation Effect on Polyvinylchloride (PVC) Nanocomposites with Multiwalled Carbon Nanotubes

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Nanophysics, Nanomaterials, Interface Studies, and Applications (NANO 2016)

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Abstract

We demonstrated that polyene sequences in the form of faulty spots with conjugated double C=C linkages of various lengths are formed in polyvinylchloride (PVC) nanocomposite with multi-walled carbon nanotubes (MWCNTs) in the course of thermal/mechanical and chemical dehydrochlorination. Change in MWCNTs content (up to 2.0 wt.%) in such nanocomposites in combination with electron irradiation (E e = 1.8 MeV, dosage of 0.05 MGy) causes intermolecular cross-linking and destruction of the main chain and the aforesaid faulty spots, confirmed by changes in their Raman scattering spectra and photoluminescence as well as by complicated behaviour of Young’s modulus.

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Author information

Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    T. M. Pinchuk-Rugal, O. P. Dmytrenko, M. P. Kulish, Yu. I. Prylutskyy & O. S. Nychyporenko

  2. National Pedagogical Dragomanov University, Kyiv, Ukraine

    M. I. Shut

  3. Bakul Institute for Superhard Materials of NAS of Ukraine, Kyiv, Ukraine

    V. M. Tkach

  4. Pisarghevskiy Institute of Physical Chemistry of NAS of Ukraine, Kyiv, Ukraine

    V. V. Shlapatska

Authors
  1. T. M. Pinchuk-Rugal
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  2. O. P. Dmytrenko
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  3. M. P. Kulish
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  4. Yu. I. Prylutskyy
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  5. O. S. Nychyporenko
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  6. M. I. Shut
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  7. V. M. Tkach
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  8. V. V. Shlapatska
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Corresponding author

Correspondence to T. M. Pinchuk-Rugal .

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Editors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Olena Fesenko

  2. National Academy of Sciences of Ukraine, Institute of Physics, Kiev, Ukraine

    Leonid Yatsenko

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Pinchuk-Rugal, T.M. et al. (2017). The Electron Radiation Effect on Polyvinylchloride (PVC) Nanocomposites with Multiwalled Carbon Nanotubes. In: Fesenko, O., Yatsenko, L. (eds) Nanophysics, Nanomaterials, Interface Studies, and Applications . NANO 2016. Springer Proceedings in Physics, vol 195. Springer, Cham. https://doi.org/10.1007/978-3-319-56422-7_58

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