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Microwave Heating-Mediated Remediation of Hydrocarbon-Polluted Soils: Theoretical Background and Techno-Economic Considerations

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Enhancing Cleanup of Environmental Pollutants

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Abstract

Massive amounts of soil and water have been contaminated with hydrocarbon compounds, including fuel and petrochemical products, because of economic and industrial activities. Several chemical-physical or biologic treatments have been studied to remediate hydrocarbon-polluted soils; however, these alternatives may be ineffective, expensive or too lengthy. Otherwise, ex situ conventional thermal desorption was successfully applied to remove organic contaminants, presenting excellent removal values in a very short time but requiring high energy and costs. Microwaves (MW) are a part of the electromagnetic spectrum occurring in the frequency range of 300 MHz–300 GHz, and recently, their application has been identified as a potential tool for hydrocarbon-polluted soil remediation. Compared to other remediation methods, MW heating has advantages including simplicity, safety, flexibility and cost-effectiveness since it offers the potential to significantly reduce treatment times, risk of contamination and costs due to the direct interaction of microwaves with the soil and its ability to overcome heat and mass transfer limitations. In conventional heating systems, the energy is transferred through conduction, convection and radiation, while in MW heating, energy is supplied directly to soil by molecular interaction with the electromagnetic field generated. Therefore, the components of the soil are heated individually and instantaneously, overcoming limits imposed by material heat transfer properties. Literature studies have shown that MW remediation has the potential to remove polar and semipolar organic pollutants from soil. The key factor of the remediation process is represented by the mechanism due to a partial dissipation of the electromagnetic field energy and its conversion into heat, avoiding the limitations of conductive heating phenomena of conventional thermal desorption treatment. This chapter discusses the theoretical background including MW heating process and the related techno-economic features for ex situ full-scale applications in remediation activities of hydrocarbon contaminants.

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References

  • Al-harahsheh M, Kingman S, Al-Makhadmah L, Hamilton IE (2014) Microwave treatment of electric arc furnace dust with PVC: Dielectric characterization and pyrolysis-leaching. J Hazard Mater 274:87–97

    Article  CAS  Google Scholar 

  • Barba AA, Acierno D, d’Amore M (2012) Use of microwaves for in-situ removal of pollutant compounds from solid matrices. J Hazard Mater 207–208:128–135

    Article  Google Scholar 

  • Benedetto A, Calvi A (2013) A pilot study on microwave heating for production and recycling of road pavement materials. Construct Build Mater 44:351–359

    Article  Google Scholar 

  • Buttress AJ, Binner E, Yi C, Palade P, Robinson JP, Kingman SW (2016) Development and evaluation of a continuous microwave processing system for hydrocarbon removal from solids. Chem Eng J 283:215–222

    Article  CAS  Google Scholar 

  • Chen F, Liu X, Falta RW, Murdoch LC (2010) Experimental demonstration of contaminant removal from fractured rock by boiling. Environ Sci Technol 44:6437–6442

    Article  CAS  Google Scholar 

  • Dauerman L, Windgasse G, He Y, Lu Y (1992) Microwave treatment of hazardous wastes: feasibility studies, The Hazardous Management Research Center. New Jersey Institute of Technology Newark, Newark

    Google Scholar 

  • Di P, Chang DPY (2001) Investigation of polychlorinated biphenyl removal from contaminated soil using microwave-generated steam. J Air Waste Manage Assoc 51:482–488

    Article  CAS  Google Scholar 

  • Do SH, Jo JH, Jo YH, Lee HK, Kong SH (2009) Application of peroxymonosulfate/cobalt (PMS/Co(II)) system to treat diesel contaminated soil. Chemosphere 77:1127–1131

    Article  CAS  Google Scholar 

  • Falciglia PP, Vagliasindi FGA (2014) Remediation of hydrocarbon-contaminated soils by ex situ microwave treatment: technical, energy and economic considerations. Environ Technol 35–18:2280–2288

    Article  Google Scholar 

  • Falciglia PP, Vagliasindi FGA (2015) Remediation of hydrocarbon polluted soils using 2.45 GHz frequency-heating: Influence of operating power and soil texture on soil temperature profiles and contaminant removal kinetics. J Geochem Explor 151:66–73

    Article  CAS  Google Scholar 

  • Falciglia PP, Vagliasindi FGA (2016) Techno-economic analysis of hydrocarbon-polluted soil treatment by using ex situ microwave heating: influence of soil texture and soil moisture on electric field penetration, operating conditions and energy costs. J Soil Sediment 16:1330–1344

    Article  CAS  Google Scholar 

  • Falciglia PP, Giustra MG, Vagliasindi FGA (2011a) Influence of soil texture on contaminant adsorption capacity and removal efficiency in ex-situ remediation of diesel polluted soil by thermal desorption. Chem Ecol 27(1):119–130

    Article  CAS  Google Scholar 

  • Falciglia PP, Giustra MG, Vagliasindi FGA (2011b) Low-temperature thermal desorption of diesel polluted soil: Influence of temperature and soil texture on contaminant removal kinetics. J Hazard Mater 185:392–400

    Article  CAS  Google Scholar 

  • Falciglia PP, Urso G, Vagliasindi FGA (2013) Microwave heating remediation of soils contaminated with diesel fuel. J Soil Sediment 13(8):1396–1407

    Article  CAS  Google Scholar 

  • Falciglia PP, Mancuso G, Scandura P, Vagliasindi FGA (2015) Effective decontamination of low dielectric hydrocarbon-polluted soils using microwave heating: Experimental investigation and modelling for in situ treatment. Sep Purif Technol 156:480–488

    Article  CAS  Google Scholar 

  • Falciglia PP, Maddalena R, Mancuso G, Messina V, Vagliasindi FGA (2016a) Lab-scale investigation on remediation of diesel-contaminated aquifer using microwave energy. J Environ Manage doi 167:196–205

    Article  CAS  Google Scholar 

  • Falciglia PP, De Guidi G, Catalfo A, Vagliasindi FGA (2016b) Remediation of soils contaminated with PAHs and nitro-PAHs using microwave irradiation. Chem Eng J 296:162–172

    Article  CAS  Google Scholar 

  • Federal Remediation Technologies Roundtable (1997) Remediation Technologies Screening Matrix and Reference Guide, Version 3.0. Chemical Extraction (Ex Situ Soil Remediation Technology)

    Google Scholar 

  • Fernández MD, Pro J, Alonso C, Aragonese P, Tarazona JV (2011) Terrestrial microcosms in a feasibility study on the remediation of diesel-contaminated soils. Ecotoxicol Environ Saf 74:2133–2140

    Article  Google Scholar 

  • George CE, Azwell DE, Adams PA, Rao GVN (1995) Evaluation of steam as a sweep gas in low temperature thermal desorption processes used for contaminated soil clean up. Waste Manag 15:407–416

    Article  CAS  Google Scholar 

  • Huang G, Zhao L, Dong Y, Zhang Q (2011) Remediation of soils contaminated with polychlorinated biphenyls by microwave-irradiated manganese dioxide. J Hazard Mater 186:128–132

    Article  CAS  Google Scholar 

  • Islam MN, Jo YT, Park JH (2012) Remediation of PAHs contaminated soil by extraction using subcritical water. J Indus Eng Chem 18:1689–1693

    Article  CAS  Google Scholar 

  • Islam MN, Jo YT, Park JH (2014) Subcritical water remediation of petroleum and aromatic hydrocarbon-contaminated soil: a semi-pilot scale study. Water Air Soil Pollut 225:2037

    Article  Google Scholar 

  • Islam MN, Park HS, Park JH (2015) Extraction of diesel from contaminated soil using subcritical water. Environ Earth Sci 74:3059–3066

    Article  CAS  Google Scholar 

  • Jagtap SS, Woo SM, Kim TS, Dhiman SS, Kim D, Lee JK (2014) Phytoremediation of diesel-contaminated soil and saccharification of the resulting biomass. Fuel 116:292–298

    Article  CAS  Google Scholar 

  • Kawala Z, Atamaczuk T (1998) Microwave-enhanced thermal decontamination of soil. Environ Sci Technol 32:2602–2607

    Article  CAS  Google Scholar 

  • Khalladi R, Benhabiles O, Bentahar F, Moulai-Mostefa N (2009) Surfactant remediation of diesel polluted soil. J Hazard Mater 164:1179–1184

    Article  CAS  Google Scholar 

  • Łebkowska M, Zborowska E, Karwowska E, Miaskiewicz-Peska E, Muszynski A, Tabernacka A, Naumczyk J, Jeczalik M (2011) Bioremediation of soil polluted with fuels by sequential multiple injection of native microorganisms: Field-scale processes in Poland. Ecol Eng 37:1895–1900

    Article  Google Scholar 

  • Lee GT, Ro HM, Lee SM (2007) Effects of triethyl phosphate and nitrate on electrokinetically enhanced biodegradation of diesel in low permeability soils. Environ Technol 28–8:853–860

    Article  Google Scholar 

  • Li H, Zhang Y, Kravchenko I, Xu H, Zhang CG (2007) Dynamic changes in microbial activity and community structure during biodegradation of petroleum compounds: a laboratory experiment. J Environ Sci 19:1003–1013

    Article  Google Scholar 

  • Li D, Zhang Y, Quan X, Zhao Y (2009) Microwave thermal remediation of crude oil contaminated soil enhanced by carbon fiber. J Environ Sci 21:1290–1295

    Article  Google Scholar 

  • Librando V, Bracchitta G, De Guidi G, Minniti Z, Perrini G, Catalfo A (2014) Photodegradation of anthracene and benzo[a]anthracene in polar and apolar media: new pathways of photodegradation. Polycycl Aromat Compd 34:264–279

    Article  Google Scholar 

  • Lin L, Yuan S, Chen J, Wang L, Wan J, Lu X (2010) Treatment of chloramphenicol-contaminated soil by microwave radiation. Chemosphere 78:66–71

    Article  CAS  Google Scholar 

  • Liu X, Zhang Q, Zhang G, Wang R (2008) Application of microwave irradiation in the removal of polychlorinated biphenyls from soil contaminated by capacitor oil. Chemosphere 72:1655–1658

    Article  CAS  Google Scholar 

  • Liu PWG, Chang TC, Chih-Hung C, Wang MZ, Hsu HW (2013) Effects of soil organic matter and bacterial community shift on bioremediation of diesel-contaminated soil. Int Biodeter Biodegr 85:661–670

    Article  Google Scholar 

  • Liu PWG, Chang TC, Chen CH, Wang MZ, Hsu HW (2014) Bioaugmentation efficiency investigation on soil organic matters and microbial community shift of diesel-contaminated soils. Int Biodeter Biodegr 95:276–284

    Article  CAS  Google Scholar 

  • Mena E, Ruiz C, Villaseñor J, Rodrigo MA, Cañizares P (2015) Biological permeable reactive barriers coupled with electrokinetic soil flushing for the treatment of diesel-polluted clay soil. J Hazard Mater 283:131–139

    Article  CAS  Google Scholar 

  • Metaxas AC, Meredith RJ (1993) Industrial microwave heating, IEE power engineering series 4. Peter Pregren LTD, London

    Google Scholar 

  • Pazos M, Plaza A, Martín M, Lobo MC (2012) The impact of electrokinetic treatment on a loamy-sand soil properties. Chem Eng J 183:231–237

    Article  CAS  Google Scholar 

  • Pereira MS, de Ávila Panisset CM, Martins AL, de Sá CHM, de Souza Barrozo MA, Ataíde CH (2014) Microwave treatment of drilled cuttings contaminated by synthetic drilling fluid. Sep Purif Technol 124:68–73

    Article  CAS  Google Scholar 

  • Qi Z, Chen T, Bai S, Yan M, Lu S, Buekens A, Yan J et al (2014) Effect of temperature and particle size on the thermal desorption of PCBs from contaminated soil. Environ Sci Pollut Res 21:4697–4704

    Article  CAS  Google Scholar 

  • Rafael A, Morel M (2013) Phototransformations of dinitropyrene isomers on models of the atmospheric particulate matter. Atmos Environ 75:171–178

    Article  Google Scholar 

  • Robinson JP, Kingman SW, Snape CE, Shang H, Barranco R, Saeid A (2009) Separation of polyaromatic hydrocarbons from contaminated soils using microwaves heating. Sep. Purif Technol 69:249–254

    Article  CAS  Google Scholar 

  • Robinson J, Binner E, Saeid A, Al-Harahsheh M, Kingman S (2014) Microwave processing of oil sands and contribution of clay minerals. Fuel 135:153–161

    Article  CAS  Google Scholar 

  • da Rosa CFC, Freire DMG, Ferraz HC (2015) Biosurfactant microfoam: application in the removal of pollutants from soil. J Environ Chem Eng 3:89–94

    Article  Google Scholar 

  • Silva-Castro GA, Rodelas B, Perucha C, Laguna J, González-López J, Calvo C (2013) Bioremediation of diesel-polluted soil using biostimulation as post-treatment after oxidation with Fenton-like reagents: Assays in a pilot plant. Sci Total Environ 445–446:347–355

    Article  Google Scholar 

  • Switzer C, Pironi P, Gerhard JI, Rein G, Torero JL (2014) Volumetric scale-up of smouldering remediation of contaminated materials. J Hazard Mater 268:51–60

    Article  CAS  Google Scholar 

  • Tatàno F, Felici F, Mangani F (2013) Lab-scale treatability tests for the thermal desorption of hydrocarbon-contaminated soils. Soil Sed Contam 22:433–456

    Google Scholar 

  • Tsai TT, Sah J, Kao CM (2010) Application of iron electrode corrosion enhanced electrokinetic-Fenton oxidation to remediate diesel contaminated soils: A laboratory feasibility study. J Hydrol 380:4–13

    Article  CAS  Google Scholar 

  • Tyagi VK, Lo SL (2013) Microwave irradiation: A sustainable way for sludge treatment and resource recovery. Renew Sustain Energy Rev 18:288–305

    Article  CAS  Google Scholar 

  • US-EPA (2004) Remediation technology cost compendium – year 2000, Solid Waste and Emergency Response, EPA-542-R-01-009

    Google Scholar 

  • Yang B, Xue N, Ding Q, Vogt RD, Zhou L, Li F, Wu G et al (2014) Polychlorinated biphenyls removal from contaminated soils using a transportable indirect thermal dryer unit: Implications for emissions. Chemosphere 114:84–92

    Article  CAS  Google Scholar 

  • Yuan S, Tian M, Lu X (2006) Microwave remediation of soil contaminated with hexachlorobenzene. J Hazard Mater B137:878–885

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Civil Engineering and Architecture, University of Catania, Viale A. Doria, 6, 95125, Catania, Italy

    Pietro P. Falciglia & Federico G. A. Vagliasindi

Authors
  1. Pietro P. Falciglia
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  2. Federico G. A. Vagliasindi
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Correspondence to Pietro P. Falciglia .

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Editors and Affiliations

  1. CESAM-Centre for Environmental and Marine Studies, Department of Chemistry, University of Aveiro, Aveiro, Portugal

    Naser A. Anjum

  2. Stress Physiology and Molecular Biology Laboratory Centre for Biotechnology, Maharshi Dayanand University, Rohtak, Haryana, India

    Sarvajeet Singh Gill

  3. Amity Institute of Microbial Technology, Amity University, Noida, India

    Narendra Tuteja

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Falciglia, P.P., Vagliasindi, F.G.A. (2017). Microwave Heating-Mediated Remediation of Hydrocarbon-Polluted Soils: Theoretical Background and Techno-Economic Considerations. In: Anjum, N., Gill, S., Tuteja, N. (eds) Enhancing Cleanup of Environmental Pollutants. Springer, Cham. https://doi.org/10.1007/978-3-319-55423-5_3

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