Skip to main content

The Influence of Water Vapour on the Fuming Rate in a Ferromanganese System

  • Chapter
Energy Materials 2017

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

During the casting of ferromanganese alloys, a considerable amount of dark fumes, consisting primarily of manganese oxides, are generated when the Mn vapour oxidises in the atmosphere. Previous studies indicate that these fumes can be reduced by increasing the humidity above the melt. However, the reduction mechanism is not fully understood. In an attempt to understand the reduction mechanism, the influence of a humidity change on the fuming rate was studied. Laboratory scale experiments were conducted where an impinging jet blew air with a varying humidity onto the melt where dust was captured to determine relative mass fluxes. When the wet air experiments’ fume fluxes were compared to the dry air experiment, it was found that the increase in humidity resulted in a significant fume reduction (between 33 and 79%), confirming industrial observations. Dust composition from the experiments as well as dust reduction mechanisms are presented and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 79.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Turkdogan et al., Enhancement of diffusion-limited rates of vaporization of metals. J. Phys. Chem. 67(8), 1647–1654 (1963)

    Article  Google Scholar 

  2. S.E. Olsen et al., Production of Manganese Ferroalloys (Tapir Akademisk Forlag, Trondheim, Norway, 2007)

    Google Scholar 

  3. Y.E. Lee, L. Kolbeinsen, Kinetics of oxygen refining process for ferromanganese alloys. ISIJ Int. 45(9), 1282–1290 (2005)

    Article  Google Scholar 

  4. K. Yamamoto et al., Decarburization of molten ferro-manganese in combined blowing converter. Fourth Japan-Nordic countries symposium on science and technology of process metallurgy, Tokyo, 1986

    Google Scholar 

  5. I. Kero et al., Fume formation from liquid ferromanganese, in Sustainable Industrial Processing Summit, Antalya, Turkey (2015)

    Google Scholar 

  6. M.K. Næss et al., Experimental study of rate of silica formation from active oxidation of liquid silicon, in Infraxon XIII, Almaty, Kazakhstan, Infraxon XIII (2013)

    Google Scholar 

  7. S.J. Gates et al., The use of fine water sprays to suppress fume emissions when casting ferromanganese. Clean Air J. 25(2), 26–35 (2015)

    Article  Google Scholar 

  8. N. de Nevers, Air Pollution Control Engineering, 2nd edn. (McGraw-Hill International Editions, Singapore, 2010), pp. 299–307

    Google Scholar 

  9. S.J. Gates et al. Mechanisms to supress fume emissions by using water sprays when casting FeMn (Report 11048-4-06-2-06, Resonant Environmental Technologies, 2016)

    Google Scholar 

  10. L.R. Genskow et al. Psychrometry, evaporative cooling and solids drying, in Perry’s Chemical Engineers’ Handbook, ed. by W. Green (McGra-Hill Companies Inc., United States of America, 2008), pp. 3–6

    Google Scholar 

  11. J.P. Holman, Experimental Methods for Engineers, 8th edn. (McGraw-Hill/Connect Learn Succeed, New York, NY, 2012)

    Google Scholar 

Download references

Acknowledgements

The authors acknowledge the financial support of the DeMaskUs project through the Norwegian Research Council grant no 245216.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sarel J. Gates .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 The Minerals, Metals & Materials Society

About this chapter

Cite this chapter

Gates, S.J., Kornelius, G., Kero, I., Tranell, G.M. (2017). The Influence of Water Vapour on the Fuming Rate in a Ferromanganese System. In: Liu, X., et al. Energy Materials 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-52333-0_7

Download citation

Publish with us

Policies and ethics