Abstract
The long-term durability of a coating is strongly dependent upon the coating’s resistance to crack growth, which is governed by the stress in the coating and the coating’s fracture energy. Stresses in a coating generally increase as weathering time progresses due to continued cure of the coating, physical aging, and cyclic stresses from thermal and moisture expansion mismatch between the coating and substrate. A coating’s fracture energy generally decreases as weathering progresses due to degradation of the binder network induced by both photooxidation and hydrolysis. The regular cracking patterns observed in most coatings is a result of stress relief around cracks that have already propagated.
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Nichols, M.E. (2017). Long-Term Mechanical Durability of Coatings. In: Wen, M., Dušek, K. (eds) Protective Coatings. Springer, Cham. https://doi.org/10.1007/978-3-319-51627-1_20
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DOI: https://doi.org/10.1007/978-3-319-51627-1_20
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