Abstract
Titanium nitride is a broad-spectrum specific functional material because of its many superior properties. Therefore, it is necessary to investigate synthesis methods of TiN and alloys containing TiN reinforcement. In the current study, with the increase of nitrogen gas pressure and the optimization of routine ball milling parameters, the conventional mechanical ball-milling method can be improved, the nanometers TiH2 -TiN composite powder can be synthesized successfully in a shorter time. Nitrogen gas filled in ball mill jar in which the pressure was 0.6 MPa. TiH2 powder was milled under nitrogen atmosphere at a spinning rate of 250 rpm. The results show that the stable TiN is formed after grinding for 2.5 h according to the X-ray diffraction pattern. DSC (differential scanning calorimetry) curves also indicate that milled compound powder adsorbs certain nitrogen gas. The gas adsorbed in TiH2-TiN composite can exist stably below 200 °C.
References
Wexler D, Calka A, Mosbah AY (2000) Ti–TiN hard metals prepared by in situ formation of TiN during reactive ball milling of Ti in ammonia. J Alloy Compd 309(1):201–207
Cao J, Li C, Qi J et al (2015) Combustion joining of carbon–carbon composites to TiAl intermetallic using a Ti–Al–C powder composite interlayer. Compos Sci Technol 115:72–79
Calka A, Williams J, Millet P (1992) Synthesis of silicon nitride by mechanical alloying. Scripta Metall Et Mater 27(12):1853–1857
Chin Z-H, Perng T-P (1997) In situ observation of combustion to form TiN during ball milling Ti in nitrogen. Appl Phys Lett 70(18):2380–2382
Yadav TP, Yadav RM, Singh DP (2012) Mechanical milling: a top down approach for the synthesis of nanomaterials and nanocomposites. Nanosci Nanotechnol 2(3):22–48
Murty B, Ranganathan S (2013) Novel materials synthesis by mechanical alloying/milling. Int Mater Rev
Koch C, Cho Y (1992) Nanocrystals by high energy ball milling. Nanostruct Mater 1(3):207–212
Gotor F, Alcala M, Real C et al (2002) Combustion synthesis of TiN induced by high-energy ball milling of Ti under nitrogen atmosphere. J Mater Res 17(07):1655–1663
Bolokang A, Phasha M (2010) Formation of titanium nitride produced from monocrystalline titanium powder under nitrogen atmosphere. Int J Refract Metal Hard Mater 28(5):610–615
Kennedy A, Lopez V (2003) The decomposition behavior of as-received and oxidized TiH2 foaming-agent powder. Mater Sci Eng A 357(1):258–263
Mcmahon BW, Yu J, Boatz JA et al (2015) Rapid aluminum nanoparticle production by milling in NH3 and CH3NH2 atmospheres: an experimental and theoretical study. ACS Appl Mater Interfaces 7(29):16101–16116
Zhu Y(1994) DSC analysis nanostructure of MoN, Mo2N, Ti, TiN. Chin Sci Bull 39(5):469–470
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant No.51374262).
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© 2017 The Minerals, Metals & Materials Society
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Wu, X., Lv, X., Liu, X., Li, C., Zhang, Y. (2017). Synthesis of TiN Nano-Composite Powder by High-Energy Ball Milling of TiH2 Under Nitrogen Atmosphere. In: Ikhmayies, S., et al. Characterization of Minerals, Metals, and Materials 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-51382-9_22
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DOI: https://doi.org/10.1007/978-3-319-51382-9_22
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