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Electrochemically Modulated Luminescence in Nanophotonic Structures

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Luminescence in Electrochemistry

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Abstract

Electrochemistry can be applied to extract fundamental information about charge transfer processes in a large number of situations. However, at ultrasmall scales, when the system of interest contains mesoscopic collections of matter, direct electrical measurements become difficult, and there is ample reason to couple electron transfer reactions to luminescence. This chapter summarizes a new class of spectroelectrochemical experiments in which a very small numbers of redox-active molecules interact with nanophotonic structures so that the molecular luminescence is strongly coupled to the electrochemical event in zero-dimensional, 0-D, and one-dimensional, 1-D, architectures. In this chapter, we will describe various nanophotonic and nanoelectronic structures, especially the zero-mode waveguide, ZMW, that are being coupled to mesoscopic samples of redox-active molecules in order to carry out ultrasensitive measurements on the nanoscale.

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Acknowledgements

Work described in this chapter from the authors’ laboratory was supported by the US National Science Foundation and the US Department of Energy Office of Science under various grants.

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  1. Department of Chemistry and Biochemistry and Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN, 46556, USA

    W. Xu, L. P. Zaino & P. W. Bohn

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  1. Ecole Normale Superiecure de Cachan, PPSM, Cedex, France

    Fabien Miomandre

  2. Ecole Normale Superieure de Cachan, PPSM, Cachan, France

    Pierre Audebert

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Xu, W., Zaino, L.P., Bohn, P.W. (2017). Electrochemically Modulated Luminescence in Nanophotonic Structures. In: Miomandre, F., Audebert, P. (eds) Luminescence in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-49137-0_3

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