Skip to main content

Abstract

CaO-SiO2-CaF2 based flux in a continuous steel caster has to show dual viscous functions to minimize slab defects - high viscosity enough to avoid flux entrainment at mold top surface and low viscosity enough to maximize lubrication capability at oscillated mold wall region. Liquid flux could show a shear thinning behavior when its viscosity decreases with increasing shear rates. Flux viscosity was measured by a rotational type viscometer as a function of shear rates. Raman and XPS analysis were employed to understand structural changes of flux for correlating with shear thinning behavior. The present work has focused on developing an optimum mold flux system with strong shear thinning behavior. The strong shear thinning behavior appropriate for dual viscous functions could be achieved by incorporating borate or silicon nitride into the flux. The flux compositions with a strong shear thinning behavior will be presented from the viewpoint of clean slab production.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 319.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. S.H. Shin, J.W. Cho and S.H. Kim, J. Am. Cer. Soc, 2014, vol.97, pp. 3263–3269.

    Article  Google Scholar 

  2. T. Matsushita, Y. Sasaki, M. Gornerup and S. Stteharaman, ISIJ int, 2006, vol.46, pp. 1258–1253.

    Article  Google Scholar 

  3. Sorimachi, S. Sakai and T. Fujii, Tetsu-to-Hagane, 1995, vol. 81, pp. 1144–1149.

    Google Scholar 

  4. K. Tsutsumi, K. Watanabe, S Makoto, N Masayuki, H Satoru, S Takayuki and O Tomoaki, CAMP-ISIJ, 2006, vol. 19, pp. 94.

    Google Scholar 

  5. K. Watanabe, K. Tsutsumi, M. Suzuki, H. Fujita, S. Hatori, T. Suzuki and T. Omoto, ISIJ int, 2012,vol.54,pp.865–871.

    Article  Google Scholar 

  6. R. Bruckner and Y. Yuanzheng, Journal of Non-Crystalline Solids, 1994, vol 175, pp.118–128

    Article  Google Scholar 

  7. D.B. Dingwell and S.L. Webb, Physics and Chemistry of Minerals, 1989, vol 16, pp.508–516

    Article  Google Scholar 

  8. G.A. Dobreva and J. Schmelzer, Journal of Materials Science, 1993, vol 28, pp.890–900

    Article  Google Scholar 

  9. R. Bruckner and Y. Yuanzheng, Glass Science and Technology, 1994, vol 67C, pp.620–623

    Google Scholar 

  10. J. Deubener and R. Bruckner, Journal of Non-Crystalline Solids, 1997, vol 209, pp.96–111

    Article  Google Scholar 

  11. B.G. Thomas, Continuous casting The Encyclopedia of Materials and Technology, Eiservier Science Ltd., Oxford, 2001.

    Google Scholar 

  12. K.C. Mills and A.B. Fox, ISIJ int, 2003, vol.43, pp. 1479–1486.

    Article  Google Scholar 

  13. K. Okazawa, M. Yamane and Y Fukuda, Tetsu-to-Hagane, 2003, vol. 89, pp. 629.

    Google Scholar 

  14. K. Watanabe, K.Tsutsumi, M. Suzuki, M. Nakada and T. Shiomi, ISIJ Int, 2009, vol. 49, pp. 1611.

    Google Scholar 

  15. E. Chiellini, M. Giordano and D. Leporini, Structure and Transport Properties in Organized Polymeric Materials, World Scientific, Singapore, 1997.

    Google Scholar 

  16. S.G Advani and E. M. Sozer, Process Modeling in Composites Manufacturing, CRC press Oxon, 2002.

    Book  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 TMS (The Minerals, Metals & Materials Society)

About this paper

Cite this paper

Shin, SH., Cho, JW., Kim, SH. (2016). Viscoelastic Properties of Calcium Silicate Based Mold Fluxes at 1623K. In: Reddy, R.G., Chaubal, P., Pistorius, P.C., Pal, U. (eds) Advances in Molten Slags, Fluxes, and Salts: Proceedings of the 10th International Conference on Molten Slags, Fluxes and Salts 2016. Springer, Cham. https://doi.org/10.1007/978-3-319-48769-4_47

Download citation

Publish with us

Policies and ethics